• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.1053-1056
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• 2008

콘크리트의 투수계수는 콘크리트 구조물의 내구성능 및 미세구조의 밀실성을 판단하는 핵심적인 재료 매개변수이다. 투수계수를 산정하기 위한 많은 연구들이 있었으나, 시멘트 페이스트 및 골재 각각이 콘크리트의 투수성능에 미치는 영향을 다룬 연구는 드물다. 더우기, 탄산화가 염소이온의 확산계수에 큰 영향을 미칠 수 있음에도 불구하고, 탄산화된 콘크리트에 대한 확산계수를 다룬 연구는 더욱 드문 실정이다. 본 연구의 목적은 탄산화 및 비탄산화된 콘크리트의 투수계수를 추정할 수 있는 기초적 접근방법을 개발하는 것이다. 본 연구에서는 미세구조 모델 및 시멘트의 경화특성을 기초로 투수계수를 산정할 수 있는 해석적 기법이 개발되었다. 본 연구에서는 시간단계별로 변화하는 투수계수의 해석과 중성화된 콘크리트의 투수계수이다. 탄산화된 콘크리트에서 감소된 공극량이 계산되었으며 이는 투수계수의 산정에 이용되었다. 본 연구결과는 실험적 결과를 얻어서 상호 비교하여 검증하였다.

• 한국구조물진단유지관리공학회 논문집
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• 제14권2호
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• pp.171-175
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• 2010

본 연구는 동결융해, 염해 및 중성화가 복합적으로 작용하는 콘크리트 구조물의 내구성능을 평가하기 위하여 일반강도 콘크리트를 대상으로 동결수를 달리하여 동결융해 시험을 실시함으로서 염해와 동결융해 복합작용에 의한 콘크리트의 열화를 평가하였고, 염해, 동결융해 및 중성화의 세가지 열화가 복합적으로 발생되는 복합열화에 대해서는 적절한 평가방법이 부재하여 동결수에 따른 동결융해 시험 후의 시험체에 대하여 중성화 촉진시험을 실시함으로서 복합열화에 의한 콘크리트 내구성능 저하 특성을 평가하고자 하였다. 본 연구를 통하여 동결수의 종류나 물-결합재비 수준과 무관하게 고로슬래그미분말을 사용한 배합의 경우 염해와 동결융해가 동시에 복합적으로 발생되는 환경에서도 우수한 저항성능을 보이는 결과를 나타내므로 동결융해를 포함한 복합열화 환경에서 충분한 내구성 확보를 위해서는 최소한의 설계기준강도의 확보와 고로슬래그미분말 등 적절한 시멘트 결합재의 선정이 무엇보다 중요하다는 결론을 얻었다.

• Earthquakes and Structures
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• 제27권2호
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• pp.127-142
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• 2024

The amount of wave propagation through a rubber concrete construction is the subject of the current investigation. Rubber tire waste was used to make two different types of cement mixtures. One type contains sand substitute in amounts ranging from 15% to 60% of the total volume, while the other has gravel with diameters of 3/8 and 8/15 and 15% sand in the same mixture. A wide variety of concrete forms and compositions were created, and their viscous and solid state characteristics were assessed, along with their short-, medium-, and long-term strengths. Diffusion, density, mechanical strength resistance to compressive force, and ultrasound wave propagation were also assessed. The water-to-cement ratio and plasticizer were used in this investigation. In the second part of the study, an analytical model is presented that simulates the experimental model in predicting the speed of waves and the frequencies accompanying them for this type of mixture. Higher order shear deformation beam theory for wave propagation in the rubberized concrete beam is developed, considering the bidirectional distribution, which is primarily expressed by the density, the Poisson coefficient, and Young's modulus. Hamilton's concept is used to determine the governing equations of the wave propagation in the rubberized concrete beam structure. When the analytical and experimental results for rubber concrete beams were compared, the outcomes were very comparable. The addition of rubber gravel and sandy rubber to the mixture both resulted in a discernible drop in velocities and frequencies, according to the data.

• Computers and Concrete
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• 제12권5호
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• pp.669-680
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• 2013

This paper unveils a new computer based stabilization methodology for automated modeling analysis and its experimental verification for corrosion in reinforced concrete structures under the effect of varying oxygen concentration. Various corrosion cells with different concrete compositions under four different environmental conditions (air dry, submerged, 95% R.H and alternate wetting-drying) have been investigated under controlled laboratory conditions. The results of these laboratory tests were utilized with an automated computer-aided simulation model. This model based on mass and energy stabilization through the porous media for the corrosion process was coupled with modified stabilization methodology. By this coupling, it was possible to predict, maintain and transfer the influence of oxygen concentration on the corrosion rate of the reinforcement in concrete under various defined conditions satisfactorily. The variation in oxygen concentration available for corrosion reaction has been taken into account simulating the actual field conditions such as by varying concrete cover depth, relative humidity, water-cement ratio etc. The modeling task has been incorporated by the use of a computer based durability model as a finite element computational approach for stabilizing the effect of oxygen on corrosion of reinforced concrete structures.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 추계학술발표대회
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• pp.42.1-42.1
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• 2009

In recent years, it has been tried to develop the efficacy and bioactivity of Calcium Phosphate cements(CPC) as injectable bone substitute (IBS) by reinforcing them through varying the amount in its compositions and relative concentrations or adding other additives. In this study, the biocompatibility of are inforced Calcium Phosphate-Calcium Sulfate injectable bone substitute (IBS)containing poly ($\varepsilon$-caprolactone)PCL microspheres was evaluated which consisted of solution chitosan and Na-citrate as liquid phase and tetra calcium phosphate (TTCP), dicalciumphosphate anhydrous (DCPA) powder as the solid phase. The in vitrobiocompatibility of the IBS was done using MTT assay and Cellular adhesion and spreading studies. The in vitro experiments with simulated body fluid (SBF) confirmed the formation of apatite on sample surface after 7 and 14 days of incubation in SBF. SEM images for one cell morphologies showed that the cellular attachment was good. MG-63 cells were found to maintain their phenotype on samples and SEM micrograph confirmed that cellular attachment was well. In vitro cytotoxicity tests by an extract dilution method showed that the IBS was cytocompatible for fibroblast L-929.

• 한국재료학회지
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• 제26권10호
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• pp.521-527
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• 2016

Geopolymers have many advantages over Portland cement, including energy efficiency, reduced greenhouse gas emissions, high strength at early age and improved thermal resistance. Alkali activated geopolymers made from waste materials such as fly ash or blast furnace slag are particularly advantageous because of their environmental sustainability and low cost. However, their durability and functionality remain subjects for further study. Geopolymer materials can be used in various applications such as fire and heat resistant fiber composites, sealants, concretes, ceramics, etc., depending on the chemical composition of the source materials and the activators. In this study, we investigated the thermal properties and microstructure of fly ash and blast furnace slag based geopolymers in order to develop eco-friendly construction materials with excellent energy efficiency, sound insulation properties and good heat resistance. With different curing times, specimens of various compositions were investigated in terms of compressive strength, X-ray diffraction, thermal property and microstructure. In addition, we investigated changes in X-ray diffraction and microstructure for geopolymers exposed to $1,000^{\circ}C$ heat.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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• pp.561-564
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• 2008

콘크리트는 방사선 차폐용 구조물에 광범위하게 사용되고 있는 재료 중의 하나이다. 특히, 중량콘크리트는 중장비 또는 엘리베이터의 무게중심 등으로도 일부 사용되지만, 일반적으로 방사선 차폐 구조물에 주로 사용된다. 중량콘크리트는 일반 콘크리트 대비 높은 밀도뿐만 아니라, 콘크리트 배합적으로도 특별한 조성을 갖는다. 중량콘크리트를 구성하는 재료 중, 특히 중요한 것이 골재의 선정이다. 목표로 하는 콘크리트 밀도를 얻기 위해서는 실험 등에 의해 적절한 골재의 선정이 무엇보다도 중요하다. 그러나, 국내 실정에 적합한 중량골재원 및 이에 대한 참고자료가 많지 않은 상황으로, 지속적인 연구개발 및 관심이 필요한 상황이다. 따라서, 본 연구에서는 국내 실정에 적합한 방사선 차폐용 고밀도 중량콘크리트의 실용화를 목적으로, 골재 및 기타 재료의 적합성 시험, 콘크리트 기초 물성시험 등을 통하여 고밀도 중량콘크리트의적용 가능성을 검토하였다.

• Korean Chemical Engineering Research
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• 제55권3호
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• pp.279-286
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• 2017

This review paper evaluates different kinds of synthesis methods for calcite precipitated calcium carbonates by using different materials. The various processing routes of calcite with different compositions are reported and the possible optimum conditions required to synthesize a desired particle sizes of calcite are predicted. This paper mainly focuses on that the calcite morphology and size of the particles by carbonation process using loop reactors. In this regard, we have investigated various parameters such as $CO_2$ flow rate, Ca $(OH)_2$ concentration, temperature, pH effect, reaction time and loop reactor mechanism with orifice diameter. The research results illustrate the formation of well-defined and pure calcite crystals with controlled crystal growth and particle size, without additives or organic solvents. The crystal growth and particle size can be controlled, and smaller sizes are obtained by decreasing the Ca $(OH)_2$ concentration and increasing the $CO_2$ flow rate at lower temperatures with suitable pH. The crystal structure of obtained calcite was characterized by using X-ray diffraction method and the morphology by scanning electron microscope (SEM). The result of x-ray diffraction recognized that the calcite phase of calcium carbonate was the dominating crystalline structure.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.9-18
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• 2001

1. EAF Dust in Japan - Generation and Characteristics. The quantity of dust generated from EAF shops in Japan was estimated to be 520,000 tons/year in 1999. Extremely fine dust (or fume) is formed in the EAF by metal vaporization. Its characteristics such as chemical compositions, phases, particle size, leaching of heavy metal are mentioned. 2. EAF Dust Treatment Methods in Japan. In 1999, 61% of EAF dust was treated by regional zinc recovery processing routes, 25% went to landfill disposal, 4% was reused as cement material, and 10% was treated by on-site processing routes. The problems of EAF dust treatment methods in Japan are: (1) very high treatment cost, and (2) heavy environmental load (leaching of heavy metal, emission of dioxins, depletion of disposal sites, etc). It has been much hoped for that new dust management technology would be developed. 3. New technology of EAF dust treatment in Japan. In Japan, some new technologies of EAF dust treatment have been developed, and some others are in the developing stages. Following five processes are mentioned:. (1) Smelting reduction process by Kawasaki Steel, (2) DSM process by Daido Steel, (3) VHR process by Aichi Steel, (4) On-site dust direct recycling technology, and (5) Process technology of direct separation and recovery of iron and zinc metals contained in high temperature EAF off gas by the Japan Research and Development Center fur Metals.

• Advances in concrete construction
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• 제11권3호
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• pp.231-238
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• 2021

The present work aims at investigating the effects of using various fine mineral additions as partial replacement to Portland cement on the tribological properties of concrete. To achieve this goal, concrete mixtures were prepared with different percentages (10, 20 and 30%) of limestone fillers (LF) and natural pozzolana (NP), and (20, 40 and 60%) of blast furnace slag (BFS). The interface yield stress (τ0) and viscous constants (η) that allow characterizing friction at the concrete-pipe wall interface were determined using a rotational tribometer. In addition, the compositions of the boundary layers that formed in the pumping pipes of the different concretes under study were also identified and analyzed. The experimental results obtained showed that the concretes studied have a linear tribological behavior that can be described by the Bingham model. Furthermore, the use of different mineral additions, especially limestone fillers and blast furnace slags, even at high rates, had a beneficial effect on the optimization of the volume of paste present in the boundary layer, which made it possible to significantly reduce the viscous constant of concrete. However, a maximum rate of 10% of natural pozzolana was recommended to achieve tribological properties that are favorable to the pumpability of concrete.