• Title/Summary/Keyword: Ce 희생양극

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Effect of Additional Elements on Efficiency of Al and Zn Sacrificial Anode for Naval Vessels (함정용 Al 및 Zn 희생양극의 효율에 미치는 첨가원소 영향)

  • Choi, Woo-Suk;Park, Kyung-Chul;Kim, Byeong-Ho
    • Journal of Navigation and Port Research
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    • v.39 no.4
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    • pp.277-283
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    • 2015
  • MS(Mild Steel), HTS(High Tensile Steel), HYS(High Yield Steel), AL(Aluminum Alloy) and Composite Materials are used for vessels. Steel Materials are mostly used for vessels because body of a ship have to perform the basic functions such as watertight, preserving the strength and supporting the equipments. The vessels primarily carry out a mission at ocean, so that body of a ship is necessarily rusted. There are several methods to protect the corrosion of vessels such as painting, SACP(sacrificial anode cathodic protection) and ICCP(impressed current cathodic protection). For the sacrificial anode cathodic protection, Al and Zn alloys are normally used. Heavy metals are added to the Al and Zn Alloys for improving the corrosion properties but they are so harmful to the human and environment. Therefore, the use of these heavy metals is strictly regulated in the world. In this paper, Al and Zn Alloys are made by adding the trace elements(Ma, Ca, Ce and Sn) which is not harmful to the human and environment. SEM, XRD, Potentiodynamic Polarization test and Current Efficiency test are conducted for evaluation of Al and Zn Alloys. As a result of the experiment, Al-3Zn-0.6Sn and Zn-3Sn Alloys are more efficient than other Alloys.

Effect of Rare Earth Elements on Uranium Electrodeposition in LiCl-KCl Eutectic Salt (LiCl-KCl 공융염에서 우라늄 전착거동에 대한 희토류 원소들의 영향)

  • Park, Sungbin;Kang, Young-Ho;Hwang, Sung Chan;Lee, Hansoo;Paek, Seungwoo;Ahn, Do-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.4
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    • pp.263-269
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    • 2015
  • It is necessary to investigate the electrodeposition behavior of uranium and other elements on the cathode in the electrorefining process to recover the uranium selectively from the reduced metals of the electrolytic reduction process since transuranic elements and rare earth elements is dissolved in the LiCl-KCl eutectic salt. Study on separation factors of U, Ce, Y and Nd based on U and Ce was performed to investigate the deposition behavior of the cathode with respect to the concentration of rare earth elements in LiCl-KCl eutectic salt. After electrorefining with constant current mode by using Ce metal as a sacrifice anode, the contents of U, Ce, Y and Nd in the salt phase and the deposit phase of the cathode were analyzed, and separation factors of the elements were obtained from the analyses. Securing conditions of pure uranium recovery in the elctrorefining process was investigated by considering the separation factors with respect to $UCl_3$ and $CeCl_3/UCl_3$ ratio.