• 한국염색가공학회지
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• 제17권3호
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• pp.1-7
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• 2005

Cationic dyeable polyester(CDP) was produced through melt blending of cationic chips having $2mol\%$ of sodium salt of dimethyl ester of 5-sulfoisophthalic acid(DMS salt) and normal polyester chips in different proportions to obtain yarns having varying amount of comonomer in the fiber. The modified polyesters showed increased moisture regain, decreased viscosity, lower softening point and improved antistatic characteristics, according to the amount of modifier. In dyeing at $100^{\circ}C$ the dyeing rate of cationic dyes with CDP fiber increased slowly than that of disperse dyes. In dyeing at $120^{\circ}C$ cationic dyes reached to equilibrium at 30min and disperse dyes at 10min. Cationic dyes in dyeing of CDP fabric have a better wash fastness compared with disperse dyes, also rubbing fastness of cationic dyes is better than that of disperse dyes. The light fastness of CDP fabric for cationic and disperse dyes is not good. The fastness of 75d/36f CDP fabric is higher than 75d/72f fabric. Solvent wicking fastness of CDP with cationic dyes is better than that of disperse dyes.

• 한국염색가공학회지
• /
• 제17권3호
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• pp.8-15
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• 2005

Cationic dyeable polyester(CDP) fabric was annealed at varying temperatures range from $120^{\circ}C$ to $220^{\circ}C$ for 1, 3, and 5 min under tension. Dyeing rates of CDP fabrics were measured with cationic and disperse dyes at $100^{\circ}C$ and $120^{\circ}C$ in water system. Also X-ray diffraction pattern, DSC thermograms and dyeability of fabric with cationic and disperse dyes were investigated. The intensities of X-ray diffraction peaks of annealed fabric were increased with increasing in annealed temperature, and peak became sharp with heat setting temperature. The apparent color depth (K/S) of CDP fabric initially decreased with increase of heat-setting temperature up to $160\~180^{\circ}C$ and then increased at higher temperature. The shearing modulus(G) and surface roughness were increased with annealing temperature.