• Title/Summary/Keyword: Cathodic protection method

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Effect of Impressed Potential on the SCC of Al-Brass (Al-황동의 응력부식균열 특성에 미치는 인가전위의 영향)

  • 정해규;임우조
    • Journal of Ocean Engineering and Technology
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    • v.18 no.1
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    • pp.69-74
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    • 2004
  • In general, the protection method of Shell and Tube Type heat exchanger for a vessel has been applied as a sacrificial anode, which is attached at the inner side of the shell. However, this is an insufficient protection method for tube. Therefore, a more suitable method, such as the impressed current cathodic protection for tube protection, is required. Al-brass is the raw material of tubes for heat exchanger of a vessel where seawater is used for cooling the water. It has a high level of heat conductivity, excellent mechanical properties, and a high level of corrosion resistance, due to a cuprous oxide (Cu$_2$O) layer against th seawater. However, in actuality, it has been reported that Al-brass tubes for heat exchanger of a vessel can produce local corrosion, such as stress corrosion cracking (SCC). This paper studied the effect of impressed potential on the stress corrosion cracking of Al-brass for impressed current cathodic protection in 3.5% NaCl +0.1% NH$_4$OH solution, under flow by a constant displacement tester. Based on the test results, the latent time of SCC, stress corrosion crack propagation, and the dezincification phase of Al-brass are investigated.

Fundamental Study on Cathodic Protection and Material Development as Erosion-Control Methods of Oceanic Centrifugal Pump(2) (해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구(2))

  • Lee, Jin Yeol;Im, U Jo;O, In Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.2
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    • pp.92-92
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    • 1996
  • Recently, with the rapid development in the oceanic systems such as the oceanic structures and vessel, there occurs much interest in the impingement erosion-corrosion. In this paper, Cu-metal was tested by using of erosion apparatus with water-jet type and was investigated under the behaviour of impingement erosion-corrosion according to various environmental conditions, and the properties of Cu-metal were evaluated through the measurement by weight loss, weight loss rate, protective efficiency. The results were compared with those obtained using Cu-metal applied to cathodic protection and Cu-alloys added to Zn or Al-metal. As a basis of those results, the best protective efficiencies could be taken as using cathodic protection method and Cu-alloy with Al & Zn material addings, and will be suggested as the fundamental data of the anti-impingement erosion-corrosion on Cu-metal of impeller material for oceanic centrifugal pump.

Fundamental Study on Cathodic Protection and Material Development as Erosion - Control Methods of Oceanic Centrifugal Pump(2) (해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구 (2))

  • 이진열;임우조;오인호
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.2
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    • pp.24-31
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    • 1996
  • Recently, with the rapid development in the oceanic systems such as the oceanic structures and vessel, there occurs much interest in the impingement erosion-corrosion. In this paper, Cu-metal was tested by using of erosion apparatus with water-jet type and was investigated under the behaviour of impingement erosion-corrosion according to various environmental conditions, and the properties of Cu-metal were evaluated through the measurement by weight loss, weight loss rate, protective efficiency. The results were compared with those obtained using Cu-metal applied to cathodic protection and Cu-alloys added to Zn or Al-metal. As a basis of those results, the best protective efficiencies could be taken as using cathodic protection method and Cu-alloy with Al & Zn material addings, and will be suggested as the fundamental data of the anti-impingement erosion-corrosion on Cu-metal of impeller material for oceanic centrifugal pump.

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Crystal Structure Control of Calcareous Deposit Films Formed by Pulse Electrodeposition Process in Seawater and Their Properties (해수 중 펄스 전착 프로세스 의해 제작한 석회질 피막의 결정구조 제어 및 특성 평가)

  • Park, Jun-Mu;Lee, Seung-Hyo
    • Journal of the Korean institute of surface engineering
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    • v.52 no.2
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    • pp.103-110
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    • 2019
  • As an anti-corrosion method in seawater, cathodic protection is widely recognized as the most effective and technically appropriate corrosion prevention methodology for marine structures against harsh corrosive environment. When applying the cathodic protection in seawater, the surface of the metal facilities the formation of compounds of $CaCO_3$ and $Mg(OH)_2$. These mixed compounds are generally called 'calcareous deposits'. This layer functions as a barrier against the corrosive environment and functions to further inhibit the corrosion process and then leading to a decrease in current demand for cathodic protection. However, calcareous deposit films are partially formed on the surface of the cathode and there are some difficulties to maintain both a corrosion resistance for a long period of time and a strong adhesion between deposits and base metal. In this study, the pulse electrodeposition process was applied to improve adhesion and corrosion resistance of the calcareous deposit films, and to solve the problem of hydrogen embrittlement at high current density. The uniform and compact calcareous deposit films were prepared by pulse electrodeposition process, and their properties were characterized using various surface analytical techniques together with electrochemical methods.

Protection of STS304 Steel with Photo-Functional Material $TiO_2$ Coating (광기능성 재료 $TiO_2$ 피막에 의한 STS304강의 방식)

  • Nam, Ki-Woo;Lee, Sung-Yeon;Ahn, Seok-Hwan;Kim, Jong-Soon;Park, In-Duck
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.10a
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    • pp.307-311
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    • 2002
  • This study was investigated the photoelectrochemical behavior of STS304 steel with $TiO_2$ thin films coating, applied by sol-gel method, for the purpose of cathodic photoprotection of the steel corrosion. One time $TiO_2$-coated STS304 steel adopted two kinds of $TiO_2$ sol solution has the most dominant photopotential abilities, which was -200mV vs. SCE and -500mV vs. SCE under illumination with 40W fluorescent lamp, respectively. That was more negative than the corrosion potential of the bare metal(-150 mV). The bleaching of TCE was confirmed on $TiO_2$-coated STS304 under UV-illumination with 20 W Black-light. This Study was concluded that $TiO_2$-coated STS304 exhibited both a cathodic photoprotection effect against corrosion and photocatalytic self-cleaning effect.

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Effects of Weld Fume on the Corrosion Protection of Epoxy Coated on Carbon Steel

  • Shon, MinYoung
    • Corrosion Science and Technology
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    • v.10 no.3
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    • pp.80-86
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    • 2011
  • Welding was widely used in shipbuilding industries as a joining method. In present study, the effects of welding fume contaminated on steel surface on corrosion protection were examined by water ballast simulation test and condensation chamber test. Pull-off adhesion test, blistering test and cathodic disbondment test were carried out to evaluate the effects of residual welding fume. Consequently, it was clearly indicated that the residual welding fume didn't affect the corrosion protection of epoxy coated on steel when surface was treated by light sweep blasting to heavy sweep blasting which was applied in this study.

The development of On-Line Cathodic Protection Monitoring System (지중 금속구조물의 전기방식 원격감시시스템 개발)

  • 임헌호;정성우;하희천
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2001.05a
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    • pp.213-218
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    • 2001
  • These days, corrosion condition of a underground objects is measured by the electric potential between the subject and ground. But this method is implemented by means of manual work with analog voltmeter, which is uneconomic and inefficient. So, We developed real-time On-Line cathodic protection monitoring system that is able to detect corrosion potential conditions of metal objects or various steel structures in the ground continuously, display them with the graphic screen, construct a database, and analyze them simultaneously. Since the data of corrosion and corrosion protection of all underground objects is processed automatically, not manually in this system, It is possible to reduce the manipulated error, and perform precise safety management, maintenance and inspection. As as result, this system can not only guarantee long-life operation, reduction of manpower and cost, but prevent large accidents in advance.

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The TRS Terminal for Wireless Remote Corrosion Monitoring System (무선 원격 부식모니터링용 TRS 단말기)

  • Ha, Tae-Hyeon;Bae, Jeong-Hyo;Lee, Hyeon-Gu;Ha, Yun-Cheol;Kim, Dae-Gyeong
    • Proceedings of the KIEE Conference
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    • 2003.11c
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    • pp.544-547
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    • 2003
  • The owner of water pipeline has a burden of responsibility for the protection of corrosion and the prevention against leakage of water. So, they have been installed a CP(Cathodic Protection) System in odor to protect corrosion. And they also have been measured and analyzed the data about P/S(Pipe to Soil) potential of water pipeline. The P/S potential is basic data of evaluation for water pipeline corrosion. They need remote automatic corrosion monitoring system for easy maintenance. In this paper, The communication method was studied mainly. And the specifications of proposed TRS (Truncked Radio System ) terminal for corrosion monitoring are introduced briefly.

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The Development of the High-efficiency Rectifier on Marine Metallic Structures(II) (해양금속구조물의 전기방식을 위한 고효율 정류기 개발(II))

  • Ha, Tae-Hyun;Bae, Jeong-Hyo;Kim, Dae-Kyeong;Lee, Hyun-Goo;Choi, Sang-Bong;Jeong, Seong-Hwan
    • Proceedings of the KIEE Conference
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    • 2000.11d
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    • pp.727-728
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    • 2000
  • The Cathodic Protection system which is usually applied to marine metallic structures in domestic is Sacrificial Anode Method. In general. low efficiency rectifiers are using in the field of Cathodic Protection. These rectifiers are not only low efficiency but also manual type which is not able to control remotely. In this paper we describe the high efficiency rectifier used the high speed switching method for optimum corrosion control of marine metallic structures.

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A Study on the Standardization of Performance Test Method for CP Rectifier in Korea (국내 전기방식용 정류기의 성능평가 시험 방법에 대한 표준화 연구)

  • Bae, Jeong-Hyo;Ha, Tae-Hyun;Lee, Hyun-Goo;Kim, Dae-Kyeong;Lee, Ji-In
    • Proceedings of the KIEE Conference
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    • 2002.11d
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    • pp.253-256
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    • 2002
  • Generally, the owners of the facilities adopt CP(Cathodic Protection) Systems to protect the corrosion accidents previously. The developed countries have secured the standard of CP systems through the various researches and consolidation of the rules. So in the first stage. I had been studied the international standards; JSCE, NACE Standard, ASTM, DNV, Australian Standard etc. and standardized the CP systems about items performance. specifications and so on. In this thesis, I have been studying the results of standardization of performance test methods of CP rectifier to apply in Korea.

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