• Journal of the Korean institute of surface engineering
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• v.32 no.3
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• pp.444-446
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• 1999

The structure and composition of anodic films, formed on 6063 commercial aluminium alloy at constant current density of $1.5A/^dm2$ with various superimposed cathodic current ratio, in the range 0~33%, in the 11% $H_2SO_4$ with various concentration of $CuSO_4{\cdot}5H_2O$, in the range 0~75 g/l, without cathodic current are generally porous-type and no sign of Cu co-deposition appearance, suggesting that cathodic current is an important factor in the Cu co-deposition. Comparison with the anodic film thickness measurement results obtained from anodic film formed by direct anodic current and anodic film formed by superimposed various portion of cathodic current, the portion of cathodic current of input current increases with decrease of anodic film thickness and increases with increase of concentration of $Cu_2S{\;}and{\;}Cu_2O$ in the anodic film.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.1081-1090
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• 2003

• Restorative Dentistry and Endodontics
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• v.18 no.2
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• pp.431-445
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• 1993

The purpose of this study was to observe corrosion characteristics of six dental amalgams and was to analyse corrosion products electrochemically. After each amalgam alloy and Hg was triturated as the direction of the manufacturer by using mechanical amalgamator, the triturated mass was inserted into the cylinderical metal mold ($12{\times}10mm$) and was condensed with 160kg/$cm^2$ by using the hydrolic press. The specimen was removed from the mold and was stored at room temperature for 1 week, and was polished with amalgam polishing kit. The anodic and cathodic polarization curve was obtained by using cyclic voltammetric method with 3-electrode potentiostat in saline for each amalgam and Ag, Sn, Cu plate specimen at $37{\pm}0.5^{\circ}C$. The potential sweep range was -1.7V~0. 4V(vs SCE) in working electrode and scan rate was 50mV/s and the exposed surface area of each specimen to the electrolytic solution was $0.79cm^2$. The results were as follows. 1. In anodic-cathodic polarization curve of amalgam specimens, two anodic current rising areas and two cathodic current peaks were obtained at the low Cu amalgam(CF, CS) specimen and three anodic current rising areas and three cathodic current peaks were obtained at the high Cu amalgam (TY, DS, HV) specimen. 2. As this compared with the anodic and cathodic current peak potentials of Sn, Cu and Ag specimen, the first cathodic current peak I c was caused by the reduction of divalent tin salt, second cathodic current peak IIIc results from the reduction of quadravalent tin salt, and third cathodic current peak me results from the reduction of copper salt. 3. As reverse potential sweeping was done repeatedly, anodic current was decreased slightly in all amalgam specimens.

• Journal of Advanced Marine Engineering and Technology
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• v.28 no.6
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• pp.972-980
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• 2004

Cathodic protection is being widely used to protect steel structures in sea water environment, In order to protect steel structures completely, the flow condition of sea water surrounding with this structures and the surface condition of the structures must be considered for a desirable design of cathodic protection. In this study, the optimum protection potential and current density were investigated in terms of cathodic current density, surface condition and a flow condition of sea water. The optium protection potential of the cleaned specimen was -770 mV(SCE) and below. However in the case of the rusted specimen, its potential was -700 mV(SCE) and below, which was somewhat positive than the cleaned one irrespective of flow condition. The optimum cathodic protection current density for both the cleaned and rusted specimens was 100 mA/$\textrm{m}^2$, however, on the flow condition, 200 mA/$\textrm{m}^2$ to be supplied for cathodic protection of steel structures completely for both cleaned and rusted specimens.

• Corrosion Science and Technology
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• v.6 no.3
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• pp.90-95
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• 2007

Cathodic protection technology has been widely used on ship's outer hull and inner side of ballast water tanks as a supplementary corrosion protection measure in combination with protective organic coatings. Impressed current cathodic protection system is typically opted for the ship's hull and, sacrificial anode system, for ballast water tanks. The anticipation and interest in cathodic protection system for ships has been surprisingly low-eyed to date in comparison with protective coatings. Computational analysis for the verification of cathodic protection design has been tried sometimes for offshore marine structures, however, in commercial shipbuilding section, decades old design practice is still applied, and no systematic or analytical verification work has been done for that. In this respect, over-rotection from un-erified initial design protocol has been also concerned by several experts. Especially, it was frequently reported in sacrificial anode system that even after full design life time, anode was remaining nearly intact. Another issue for impressed current system, for example, is that the anode shield area design for ship's outer hull should be compromised with actual application situation, because the state-of-the-art design equation is quite impractical from the applicator's stand. Besides that, in this study, some other critical design issues for sacrificial anode and impressed current cathodic protection system were discussed.

• Journal of Welding and Joining
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• v.19 no.1
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• pp.65-74
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• 2001

A study on the corrosion behavior in case of As-welded and PWHT temperature 55$0^{\circ}C$ of welding part of RE36 steel for marine structure was investigated with parameters such as micro-Vickers hardness, corrosion potential measurement of weld metal(WM), base metal(BM) and heat affected zone(HAZ), both Al anode generating current and Al anode weight loss quantity under sacrificial anode cathodic protection conditions. And also we carried out slow strain rate test(SSRT) in order to research both limiting cathodic polarization potential for hydrogen embrittlement and optimum cathodic protection potential as well as mechanical properties by post-weld heat treatment(PWHT) effect. Hardness of HAZ was the highest among three parts(WM, BM and HAZ) and the highest galvanic corrosion susceptibility was HAZ. And the optimum cathodic polarization potential showing the best mechanical properties by SSRT method was from -770mV to -875mV(SCE). In analysis of SEM fractography, applied cathodic potential from -770mV to -875mV(SCE) it appeared dimple pattern with ductile fracture while it showed transgranular pattern (Q. C : quasicleavage) under -900mV(SCE). However it is suggested that limiting cathodic polarization potential indicating hydrogen embrittlement was under -900mV(SCE).

• Journal of Advanced Marine Engineering and Technology
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• v.24 no.4
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• pp.460-469
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• 2000

A study on the corrosion behavior of RE36 steel for marine structure was investigated with parameters such as micro-Vickers hardness, corrosion potential and corrosion current density measurement of weld metal(WM), base metal (BM) and heat affected zone(HAZ), Al anode generating current and Al anode weight loss quantity in case of cathodic protection. And we carried out slow strain rate test(SSRT) in order to research mechanical properties such as stress at maximum load, percent strain, time to fracture and strain to failure ratio etc and to find out limiting cathodic polarization potential for hydrogen embrittlement with applied cathodic polarization potential. Hardness of HAZ part was the highest among those three parts and also galvanic corrosion susceptibility was the highest in HAZ part among those three parts due to the lowest corrosion potential than other parts. However corrosion current density was the highest in WM part among those three parts. And the optimum cathodic polarization potential showing the best mechanical properties obtained by SSRT method with applied constant cathodic potential was from - 770mV to - 875mV(SCE). However it is suggested that limiting cathodic polarization potential indicating hydrogen embrittlement on the mechanical properties was under - 900mV(SCE).

• Journal of the Korean institute of surface engineering
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• v.44 no.3
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• pp.105-116
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• 2011

Ships and offshore structures are exposed to harsh marine environments, and maintenance and repair are becoming increasingly important to the industry and the economy. The major corrosion phenomenons of metals and alloys in marine environment are pitting corrosion, stress corrosion cracking, crevice corrosion, fatigue corrosion, cavitation-erosion and etc. due to the effect of chloride ions and is quite serious. Methods of protection against corrosion can generally be divided into two groups: anodic protection and cathodic protection. Anodic protection is limited to the passivity characteristics of a material in its environment, while cathodic protection can apply methods such as sacrificial anode cathodic protection and impressed current cathodic protection. Sacrificial anode methods using Al and Zn alloys are widely used for marine structures and vessels intended for use in seawater. Impressed current cathodic protection methods are also widely used in marine environments, but tend to generate problems related to hydrogen embrittlement caused by hydrogen gas generation. Therefore, it is important to the proper maintenance and operation of the various corrosion protection systems for ship in the harsh marine environment.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.37 no.2
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• pp.147-152
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• 2001

Corrosion damage of boiler, factory equipment and so forth occur quickly due to using of the polluted water, resulting in increasing leak accident. Especially, working life of hot water boiler using the polluted water becomes more short, and energy loss increases. The cathodic protection method is the most economical and reliable one to prevent corrosion damage of steel structures. Mg-base alloys galvanic anode protection of cathodic protection methode is suitable for the application of hot water boiler using water with high specific resistance such as tap water. This paper is studied on the cathodic protection characteristics of hot water boiler. In tap water solution, the measurement of cathodic protection potential according to the time elapsed is carried out, and behavior of cathodic polarization with current change is investigated. The main results obtained are as follows. In hot water boiler shell, the open circuit potential of base metal become less noble than that of weld Bone, and the current density of base metal becomes low than that of weld zone. The further distance from Mg-alloy galvanic anode, the higher cathodic protection potential of hot water boiler appears. And protective potential becomes high according to pass cathodic protection time and after 6∼10 days become stable.

• Journal of Advanced Research in Ocean Engineering
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• v.2 no.4
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• pp.158-168
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• 2016

During the installation of crude oil or gas pipelines, which pass through onshore buried pipelines or onshore pipeline from subsea pipeline to onshore plant, countermeasures need to be implemented so as to ensure a sufficient design life by protecting the steel pipes against corrosion. This can be achieved through impressed current cathodic protection method for onshore pipelines and through galvanic sacrificial anode corrosion protection method for offshore pipelines. In particular, in the case of impressed current cathodic protection, isolation joint flanges should be used. However, this makes maintenance control difficult with its installation having a negative impact on price. Therefore, in this study, the most suitable methodology for onshore pipeline protection between galvanic sacrificial anode corrosion protection and impressed current cathodic protection method will be introduced. In oil and gas transportation facilities, the media can be carried to the end users via onshore buried and/or offshore pipeline. It is imperative for the field operators, pipeline engineers, and designers to be corrosion conscious as the pipelines would undergo material degradations due to corrosion. The mitigation can be achieved with the introduction of an impressed current cathodic protection method for onshore buried pipelines and a galvanic sacrificial anode corrosion protection method for offshore pipelines. In the case of impressed current cathodic protection, isolation joint flanges should be used to discontinuity. However, this makes maintenance control to be difficult when its installation has a negative impact on the price. In this study, the most suitable corrosion protection technique between galvanic sacrificial anode corrosion protection and impressed current cathodic protection is introduced for (economic life of) onshore buried pipeline.