• Title/Summary/Keyword: Cathode water

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Flow and Heat Transfer Analysis of Cooling Water in a Rotating Magnetron Cathode (회전형 마그네트론 음극의 냉각수 유동 및 열전달 해석)

  • Joo, Junghoon
    • Journal of the Korean institute of surface engineering
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    • v.52 no.3
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    • pp.171-179
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    • 2019
  • We have developed a numerical model to analyze flow dynamics and heat transfer characteristics of the cooling water in a circular rotating magnetron cathode by a moving boundary grid method realized in a commercial multiphysics package, CFD-ACE+. The numerical model is composed of a target, dual mass rotating cathode and cooling water connections. When the inlet and outlet of the cooling water are offset by the same distance from the rotation axis, the temperature at the center is higher by $50^{\circ}C$ at maximum. At 5 mm away from the target surface, the temperature profile showed typical center high characteristic. At heat input of 30 kW, the maximum temperature change of the cooling water hits $6^{\circ}C$ within 0.5 sec under 60 rpm. With a cooling water configuration of center in/edge out, the temperature of the center region of the target gets lowered. Within 100 seconds of plasma operation time, the cooling water temperature keeps getting higher.

Effect of Diffusion Layer for Cell Performance in DMFC (직접메탄올 연료전지에서 전지 성능에 대한 확산층의 영향)

  • Kwon Bu-Kil;Park Kyung-Won;Choi Jong-Ho;Sung Yung-Eun
    • 한국전기화학회:학술대회논문집
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    • 2001.06a
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    • pp.179-184
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    • 2001
  • The diffusion layer within MEA(membrane electrode assembly) has been evaluated important factor for improvement of cell performance in DMFC. The diffusion layer in MEA structure leads to the reduction of catalyst loss in active catalysts layer as well as prevention of water-flooding in cathode. Cell performance is directly affected by interior properties of diffusion layer materials. Acetylene Black and $RuO_2$ with large pore size and low porosity compared to Vulcan XC-72R gave better performance caused by vigorous methanol diffusion and water removal. And $RuO_2$ as diffusion layer materials showed different behavior in anode and cathode compartment, that is, diffusion layers in anode and cathode side make methanol diffusion and water removal facilitate, respectively.

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Transient response of unit PEMFC with the visualization study of cathode flooding under different stoichiometries (당량비 조건에 따른 PEM단위 연료전지의 과도 응답 특성 및 공기극 플러딩 연구)

  • Cho, Jun-Hyun;Kim, Han-Sang;Min, Kyoung-Doug
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.539-542
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    • 2007
  • The transient response of PEMFC (proton exchange membrane fuel cell) is important criteria in the application of PEM fuel cell to real automotive system. In this work, using a transparent unit PEM fuel cell, the transient response and cathode flooding during load change are investigated. The cell voltage is acquired according to the current density change($0.3Acm^2$ to $0.6A/cm^2$) under various stoichiometry conditions and different flooding intensities, Also the cathode gas channel images are obtained by CCD imaging system simultaneously. The different level of undershoots appeared at the moment of load changes under different cathode stoichiometries and flooding intensities. The correlation of the dynamic behavior with stoichiometry and cathode flooding is induced from the results of these experiments.

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Novel Water-Soluble Polyfluorenes as an Interfacial layer leading to Cathodes-Independent High Performance of Organic Solar Cells

  • Oh, Seung-Hwan;Shim, Hee-Sang;Park, Dong-Won;Jeong, Yon-Kil;Lee, Jae-Kwang;Moon, Seung-Hyeon;Kim, Dong-Yu
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.394-394
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    • 2009
  • Water solubility of conjugated polymers may offer many applications. Potential applications of water-soluble conjugated polymers include the polymer light-emitting diode and new materials for nano and micro hollow-capsules, and bio- or chemo-sensors. We synthesized neutral polyfluorenes containing bromo-alkyl groups by the palladium catalyzed Suzuki coupling reaction. Bromo-alkyl side groups in neutral polyfluorenes were quaternized by tri-methyl amine solution. The electrochemical and optical properties of water-soluble conjugated polymers are discussed. This novel synthesized water-soluble conjugated polymers were used as a interfacial dipole layer between active layer and metal cathode in polymer solar cell for enhancement of open-circuit voltage (Voc), which is one of the most critical factors in determining device characteristics. We also investigated the device performance of polymer solar cell with different metal cathode such as Al, Ag, Au and Cu. In polymer solar cell, novel cationic water-soluble conjugated polymers were inserted between active layer and high-work function cathode (Al, Ag, Au and Cu).

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Evaluation of power density in microbial fuel cells using expanded graphite/carbon nanotube (CNT) composite cathode and CNT anode (팽창흑연·소나노튜브 복합 음극과 탄소나노튜브 양극으로 이루어진 미생물 연료전지의 전력수율 평가)

  • Han, Sun-Kee;Lee, Chae-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.4
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    • pp.503-509
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    • 2013
  • Electrochemical redox capacity of a microbial fuel cell (MFC) electrode is an important factor in the power density. This study was conducted to investigate the redox capacity of surface modified anode and cathode electrodes by measuring their conductivities. An anode electrode was modified with nitric acid and a cathode electrode was modified with heat treatment. The anode electrode modified with 20 % of the nitric acid concentration showed the highest conductivity of $6.2{\mu}S/cm/g$ and the maximum power density of $306.0mW/m^2$ when used in a MFC. The cathode electrode modified at $472^{\circ}C$ for 18 min showed the highest conductivity of $5.2{\mu}S/cm/g$ and the maximum power density of $276.20mW/m^2$ when used in a MFC. On the other hand, an MFC using both the electrodes showed the highest maximum power density of $408.2mW/m^2$. Meanwhile, a control MFC without modified electrodes generated very small voltage (0.014 mV), so the power density could not be measured.

Removal of Flooding in a PEM Fuel Cell at Cathode by Flexural Wave (Flexural wave를 이용한 고분자 전해질 연료전지 공기극 내에서의 플러딩 제거)

  • Kim, Kyoung-Rock;Han, Seong-Ho;Ahn, Deuk-Kuen;Choi, Young-Don
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.1
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    • pp.35-41
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    • 2010
  • Water management is an important issue of PEM fuel cell operation. Water is the product of the electrochemical reactions inside fuel cell. If liquid water accumulation becomes excessive in a fuel cell, water columns will clog the gas flow channel. This condition is referred to as flooding. A number of researchers have examined the water removal methods in order to improve the performance. In this paper, a new water removal method that investigates the use of vibro-acoutic methods is presented. Piezo-actuators which are devices to generate the flexural wave are attached at the end of a cathode bipolar plate. Flexural wave is used to impart energy to resting droplets and thus cause movement of the droplets in the direction of the traveling wave.

Electrolyzed Water Cleaning for Semiconductor Manufacturing (전리수를 이용한 반도체 세정 공정)

  • 류근걸;김우혁;이윤배;이종권
    • Journal of the Semiconductor & Display Technology
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    • v.2 no.3
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    • pp.1-6
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    • 2003
  • In the rapid changes of the semiconductor manufacturing technologies for early 21st century, it may be safely said that a kernel of terms is the size increase of Si wafer and the size decrease of semiconductor devices. As the size of Si wafers increases and semiconductor device is miniaturized, the units of cleaning processes increase. A present cleaning technology is based upon RCA cleaning which consumes vast chemicals and ultra pure water (UPW) and is the high temperature process. Therefore, this technology gives rise to environmental issue. To resolve this matter, candidates of advanced cleaning processes have been studied. One of them is to apply the electrolyzed water. In this work, electrolyzed water cleaning was compared with various chemical cleaning, using Si wafer surfaces by changing cleaning temperature and cleaning time, and especially, concentrating upon the contact angle. It was observed that contact angle on surface treated with Electrolyzed water cleaning was $4.4^{\circ}$ without RCA cleaning. Amine series additive of high pKa (negative logarithm of the acidity constant) was used to observe the property changes of cathode water.

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Development of a Plasma Gun System for Ion Plating with Long Lifetime (이온 플레이팅용 장수명 플라즈마 건 장치의 개발)

  • Choi, Young-Wook
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.1
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    • pp.78-81
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    • 2008
  • A hollow cathode which has extremely stable discharge characteristic has been developed. This is composed of the two separated lanthanum hexaboride(LaB6) of a disk type in the tube as the electron emitters. The way of design is of great advantage to extend the surface discharge area of the LaB6, which is also useful for optimal fixing of the LaB6. The hollow cathode is capable of producing 30 kW(100 V, 300 A) of power continuously. Because the generated plasma beam with the high temperature(above $3000^{\circ}C$) from the hollow cathode passes through the center hole of the two intermediate electrodes, it is designed with the high temperature material of the tungsten and the suitable structure of the water cooling. The combinations of the hollow cathode and the two intermediate electrodes are practically useful for the ion plating plasma beam source.

Fundamental study of electrolyte cathode atomic discharge for development of on-line monitoring system (On-line monitoring system 개발에 관한 음극 액상 글로우 방전의 기초 연구)

  • Kim, Kyung-Mi;Woo, Young-A;Cho, Won-Bo;Kim, Hyo-Jin
    • Analytical Science and Technology
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    • v.15 no.6
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    • pp.496-501
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    • 2002
  • The electrolyte cathode glow discharge (ELCAD) is a new optical system for direct determination of trace heavy metals in flowing water. ELCAD has been successfully developed for on-line monitoring of heavy metals in flowing water. The application of an atmospheric glow discharge between an electrolyte solution cathode and a platinum rod anode led to the development of stable discharge. The fundamental aspects of new plasma source have been investigated. The fundamental study of ELCAD system has been measured plasma temperature using Einstein-Boltzmann equation after searching Fe atomic emission lines. The spectrum of each elements such as Cu, Pb, Fe, Ni and Cr show only major elemental line and no ionic line possibly due to low temperature plasma source. The detection limits of each elements are also investigated. These informations show that this type of plasma may apply for monitoring of heavy metals in waste water which consists of complex matrix.