• 제목/요약/키워드: Cathode process

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Li(Ni1-x-yCoxMny)O2계 이차전지 공정 스크랩으로부터 회수한 전이금속을 활용한 리튬이차전지 양극재 제조 (Preparation of Cathode Materials for Lithium Rechargeable Batteries using Transition Metals Recycled from Li(Ni1-x-yCoxMny)O2 Secondary Battery Scraps)

  • 이재원;김대원;장성태
    • 한국분말재료학회지
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    • 제21권2호
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    • pp.131-136
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    • 2014
  • Cathode materials and their precursors are prepared with transition metal solutions recycled from the the waste lithium-ion batteries containing NCM (nickel-cobalt-manganese) cathodes by a $H_2$ and C-reduction process. The recycled transition metal sulfate solutions are used in a co-precipitation process in a CSTR reactor to obtain the transition metal hydroxide. The NCM cathode materials (Ni:Mn:Co=5:3:2) are prepared from the transition metal hydroxide by calcining with lithium carbonate. X-ray diffraction and scanning electron microscopy analyses show that the cathode material has a layered structure and particle size of about 10 ${\mu}m$. The cathode materials also exhibited a capacity of about 160 mAh/g with a retention rate of 93~96% after 100 cycles.

시트르산의 양과 소결온도에 따른 (La,Sr)$MnO_3/Gd_{0.2}Ce_{0.8}O_{1.9}$ 계면특성 (Characterization of (La,Sr))$MnO_3/Gd_{0.2}Ce_{0.8}O_{1.9}$ Interface with Citric Acid Contents and Sintering Temperature)

  • 윤일영;윤희성;김병호
    • 한국전기전자재료학회논문지
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    • 제11권1호
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    • pp.18-25
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    • 1998
  • G $d_{0.2}$C $e_{0.8}$ $O_{1.9}$(CGO) for electrolyte and L $a_{0.5}$S $r_{0.5}$Mn $O_3$(LSM50) for cathode in Solid Oxide Fuel Cells(SOFC) were synthesized by citrate process. Specimens were prepared with sintering temperatures at 110$0^{\circ}C$, 120$0^{\circ}C$ and 130$0^{\circ}C$, which were fabricated by slurry coating with citric acid contents. Interfacial resistance was measured between cathode and electrolyte using AC-impedance analyzer. With various citric acid content, the degree of agglomeration for the initial particles changed. Also sintering temperature changed the particle size and the degree of densification of cathode. Factors affecting the interfacial resistance were adherent degree of the electrolyte and cathode, distribution of TPB(three phase boundaries, TPB i.e., electrolyte/electrode/gas phase area) and porosity of cathode. By increasing the sintering temperature, particle size and densification of the cathode were increased. And then, TPB area which occurs catalytic reaction was reduced and so interfacial resistance was increased.sed.sed.d.

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Simplified Process for Passive Matrix OLEDs

  • 이승준;신윤수;임대우;유재훈;최경희
    • 한국광학회:학술대회논문집
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    • 한국광학회 2008년도 동계학술발표회 논문집
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    • pp.397-398
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    • 2008
  • We have developed simplified processes for the formation of insulators, cathode separators and bus electrodes in PMOLEDs. The insulators and cathode separators are patterned simultaneously by a single layer of image reversal photoresist. And, the bus electrodes of low resistance are formed by the cathode separator and cathode metal. Using these simplified processes, we fabricated 1.17" $96{\times}RGB{\times}96$ panels and analyzed their performance and reliability.

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Characteristics of directly sputtered AI cathode film using twin target sputtering system for OLEDs

  • Moon, Jong-Min;Lee, Sang-Hyeon;Kim, Han-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.655-658
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    • 2007
  • Characteristics of Al cathode films deposited by using specially designed twin target sputter (TTS) system were investigated. It was found that Al cathode films prepared by TTS were amorphous structure with nanocrystallines due to low substrate temperature and OLEDs fabricated using TTS system have low leakage current density at reverse bias because of effective confinement of energetic particles during sputtering process.

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원통형 고체산화물 연료전지 기술개발 (Development of Tubular Solid Oxide Fuel Cell)

  • 송락현
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 2001년도 유체기계 연구개발 발표회 논문집
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    • pp.373-380
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    • 2001
  • Solid Oxide Fuel Cells (SOFCs) have received considerable attention because of the advantages of high effiiciency, low pollution, cogeneration application and excellent integration with simplified reformer In this paper, we reported development of anode-tubular SOFC by wet process. For making tubular cell, Ni-cermet YSZ anode tube was fabricated using extrusion process, and YSZ electrolyte layer and LSM-YSZ composite, LSM, LSCF cathode layer were coated onto the anode supported tube using slurry dipping process and sintered by co-firing process. By using this tubular cell, we fabricated single cell consisted of the various cathode layers and 4 cell stack with an effective area of $75 cm^2$ per single cell, and evaluated their performance characteristics.

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평면 음극선관의 재생률 향상을 위한 유리재료의 열적 특성에 관한 연구 (A Study on the Thermal Properties of Glass for Effective Salvage Process of Flat Cathode-ray Tube)

  • 박상후;이부윤;김원진;허보석
    • 대한기계학회논문집A
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    • 제25권12호
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    • pp.1988-1994
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    • 2001
  • The CRT(Cathode-ray Tube) of salvage is a process of separating the panel and funnel to recycle a cathode-ray tube. In this paper, the thermal properties of glass for CRT were studied to improve its recycling ratio. In the salvage process, several patterns of breakage, as called 'comer pull', were easily generated on the sealing surface of panel or funnel glass due to the residual tensile stress, which had correlations with some parameters of the manufacturing process of CRT and the initial material properties of glass. Finite element analyses and experimental approaches on the flit sealing process were carried out to obtain the major characteristic of glass related to the residual stress. From this study, it was identified that the thermal expansion coefficient of glass had much influence on the residual stress of panel glass after frit sealing process. Therefore, the optimal conditions of thermal properties for CRT glass were proposed to achieve an effective salvage process. By using these optimal conditions, the size of comer pull on the panel and funnel glass was reduced to 10% level compared with the original size, and the recycling ratio of CRT was increased in the salvage process.

고체 산화물 연료전지의 공기극 유로내 크롬 피독에 관한 전산해석 (Numerical analysis of chromium deposition through the SOFC cathode channel)

  • 박준근;배중면;이신구
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.372-375
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    • 2006
  • SOFC is a high temperature fuelcell with many advantages, but it also have several demerits. One of the Issues is cathode poisoning of Cr coming from stainless steel interconnects. Diffusion process of Cr evaporated from the surface of interconnect steel was calculated by using CFD technique to understand factors for Cr deposition. It has been cleared that factors concerned in Cr deposition and how they affect Cr deposition. Major variables for Cr deposit ion are diffusion coefficient, air velocity and temperature If diffusion coefficient decreases, Cr concentration increases in the air but decreases on the cathode surface. Increasing in air velocity, Cr concentration decreases in the air and on the cathode surface. Increase in temperature leads to rising Cr concentration on the cathode surface because of diffusion coefficient increment.

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연료전지용 캐소드 공기블로어의 비정상 내부유동장 연구 (Unsteady Internal Flow Analysis of a Cathode Air Blower Used for Fuel Cell System)

  • 장춘만;이종성
    • 신재생에너지
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    • 제8권3호
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    • pp.6-13
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    • 2012
  • This paper describes unsteady internal flow characteristics of a cathode air blower, used for the 1 kW fuel cell system. The cathode air blower considered in the present study is a diaphragm type blower. To analyze the flow field inside the diaphragm cavity, compressible unsteady numerical simulation is performed. Moving mesh system is applied to the numerical analysis for describing the volume change of the diaphragm cavity in time. Throughout a numerical simulation by modeling the inlet and outlet valves in a diaphragm cavity, unsteady nature of an internal flow is successfully analyzed. Variations of mass flow rate, force and pressure on the lower moving plate of a diaphragm cavity are evaluated in time. The computed mass flow rate at the same pressure and rotating frequency of a motor has a maximum of 5 percent error with the experimental data. It is found that flow pattern at the suction process is more complex compared to that at the discharge process. Unsteady nature of internal flow in the cathode air blower is analyzed in detail.