• 한국응용과학기술학회지
• /
• 제7권1호
• /
• pp.71-76
• /
• 1990

Transesterification reactions (methyl methacrylate with monoethanolamine, methyl methacrylate with n-butyl alcohol, dimethylphthalate with ethylene glycol, dimethyl phthalate with monoethanolamine) were kinetically investigated in the presense of various metal acetate catalysts at $110^{\circ}C$. The amount of reactants was measured by gas and liquid chromatography, and the reaction rates also measured from the amount of reaction products and reactants upon each catalyst. The transesterification reactions were carried out under the first order conditions respect to the concentration of reactants, respectively. The overall reaction order was 2nd, Maximum reaction rates were appeared at the range of 1.4 to 1.6 in electronegativity of metal ions and maximum catalytic activities were obserbed at the range of 1.5 to 1,8 in instability constant of metal acetates.

• 한국전기전자재료학회논문지
• /
• 제37권4호
• /
• pp.358-373
• /
• 2024

Oxygen evolution reaction is a critical bottleneck for the development of efficient electrochemical hydrogen production because of its sluggish reaction. Among various catalysts, transition metal-based layered double hydroxide has drawn significant attention due to their excellent catalytic properties and cost-effectiveness. This paper begins with basic crystal structures, and then conventional adsorbate evolution mechanism of layered double hydroxide. Strategies for enhancing catalytic properties based on adsorbate evolution mechanism and lattice oxygen mechanism that could surpass theoretical limit of adsorbate evolution mechanism are discussed. This paper ends with a brief discussion on the challenges and future directions of layered double hydroxide-based oxygen evolution reaction catalysts.

• 한국환경과학회지
• /
• 제16권9호
• /
• pp.1077-1083
• /
• 2007

[ $V_2O_5/TiO_2$ ] catalyst impregnated ceramic candle filters are in principle, capable of performing shallow-bed dust filtration plus a catalytic reaction, promoted by a catalytic deposited in their inner structure. Pilot-scale $V_2O_5/TiO_2$ catalyst impregnated ceramic candle filters were prepared, characterized and tested for their activity towards the SCR reaction. The effect on NO conversion of operating temperature, gas hourly space velocity, amount of deposited catalyst, pressure drops and long-term experiment (life of catalytic filter) was determined. The following effects of $V_2O_5/TiO_2$ catalyst impregnated ceramic candle filters in SCR reaction are observed: (1) It increases the activity and widens the temperature window for SCR. (2) When the content of $V_2O_5$ catalyst increases further from 3 to 9wt.%, activity of NO increases. (3) NO conversion at first increases with temperature and then decreases at high temperatures (above $400^{\circ} over), possibly due to the occurrence of the ammonia oxidation reaction.

• 공업화학
• /
• 제25권2호
• /
• pp.198-203
• /
• 2014

본 연구에서는 Ni metal foam 플레이트의 수증기 개질반응 및 표면 특성을 조사하였다. 전처리를 통하여 Ni의 산화상태를 변화시킬 수 있었으며, 활성 site로서 표면에 노출된 metallic Ni 종은 수증기 개질 반응활성에 중요한 역할을 한다. 또한 Ni metal foam 플레이트의 기공제어 및 촉매 기능을 부여하기 위하여 Ni metal foam 플레이트와 Ni-YSZ 촉매를 혼합하여 다공성 촉매 분리막을 제조하였다. SEM 분석 결과 metal foam 플레이트의 기공을 제어할 수 있었으며, 표면에 Ni-YSZ 촉매는 고르게 잘 분포되어 있었다. Ni 기반 다공성 촉매 분리막은 공간속도에 상관없이 상용촉매와 유사한 수증기 개질 활성을 가진다.

• Corrosion Science and Technology
• /
• 제21권5호
• /
• pp.412-417
• /
• 2022

Proton exchange membrane fuel cells (PEMFCs) provide zero emission power sources for electric vehicles and portable electronic devices. Although significant progresses for the widespread application of electrochemical energy technology have been achieved, some drawbacks such as catalytic activity, durability, and high cost of catalysts still remain. Pt-based catalysts are regarded as the most efficient catalysts for sluggish kinetics of oxygen reduction reaction (ORR). However, their prohibitive cost limits the commercialization of PEMFCs. Therefore, we proposed a NiCo@Au core shell structure as Pt-free ORR electrocatalyst in PEMFCs. NiCo alloy was synthesized as core to introduce ionization tendency and autoxidation reaction. Au as a shell was synthesized to prevent oxidation of core NiCo and increase catalytic activity for ORR. Herein, we report the synthesis, characterization, electrochemical properties, and PEMFCs performance of the novel NiCo@Au core-shell as a catalyst for ORR in PEMFCs application. Based on results of this study, possible mechanism for catalytic of autoxidation core@anti-oxidation shell in PEMFCs is suggested.

• 신재생에너지
• /
• 제19권4호
• /
• pp.11-19
• /
• 2023

Levulinic acid (LA) derived from cellulosic biomass, serves a crucial intermediate that can be used in various chemical conversions. This study focused on optimizing the production of LA using two types of pretreated rice husk (de-ashed and delignificated cellulosic biomass) in a batch reaction system through catalytic conversion with sulfuric acid. To determine the optimal conditions, the conversions of glucose and α-cellulose were examined to compare the effects of pretreatment on the rice husk. The experimental parameters covered a broad spectrum, including temperatures ranging from 140℃ to 200℃, a reaction time was up to 600 minutes, and a substrate to catalyst (acid solution) ratio of 100 g/L. The highest LA yield was 44.8%, achieved from de-ashed rice husk with 3.0 wt.% of sulfuric acid at 180℃ and with a reaction time of 180 minutes. In the case of the delignificated rice husk, a LA yield of 43.6% was obtained with 3.0 wt.% of sulfuric acid at 200℃ and with reaction time of 30 minutes.

• 한국환경과학회지
• /
• 제11권6호
• /
• pp.577-582
• /
• 2002

Selective catalytic reduction and selective non-catalytic reduction processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. Especially, the selective non-catalytic reduction process can be operated more economical and designed more simply than the selective catalytic reduction. For this reason, many researchers carried out to increase the removal efficiency of nitrogen oxidants in the condition of low oxygen concentration by using the selective non-catalytic reduction process. However, this study was flue gas contained high oxygen concentration of 20(v/v%) with ammonia as a reducing agent. Moreover, it carried out experiment with many factors that are reaction temperature, retention time, initial NO concentration, NSR(normalized stoichiometric ratio). It was determined optimal operating conditions to improve NO removal efficiency with SNCR process. The De-NOx efficiency was increased with NSR, initial NO concentration and retention time increasement. This study has NO removal efficiency over 80% in the high oxygen concentration as well as low oxygen concentration. The injection of reducing agent may be considered for SNCR process and facility operation in 850$\^{C}$ of optimal condition.

• Composites Research
• /
• 제32권2호
• /
• pp.85-89
• /
• 2019

나노입자에 기반한 화학 촉매 반응 효율성에는 크기, 형태 및 조성이 중요한 영향을 미치는 것으로 알려져 있다. 이에 대한 체계적인 비교를 위해 갈바닉 치환 반응을 통해 100 nm 직경의 요철형 표면 구조를 갖는 금, 백금, 팔라듐 나노플레이트에 대한 정량적인 분석 조건 형성이 가능하였으며, 4-나이트로페놀과 4-나이트로아닐린을 대상으로한 촉매 반응 진행을 분광분석법을 통해 확인할 수 있었다. 이로부터 동일 형태 및 형태에서 구성 원소에 따라 확연히 다른 Pd > Au > Pt의 촉매성 환원 반응 효율을 보임을 관찰할 수 있었으며, 기질의 형태에 따라 추가적인 영향을 받음을 관찰 가능하였다.

• Bulletin of the Korean Chemical Society
• /
• 제29권11호
• /
• pp.2270-2272
• /
• 2008

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2002년도 제25회 KOSCI SYMPOSIUM 논문집
• /
• pp.65-69
• /
• 2002

Catalytic combustion known as one of the traditional oxidation methods of VOC gas is restricted to its applicable fields because of its reaction characteristics. But recently innovative improvement of catalytic endurance makes its applicable range broader from MEMs to industrial power generation. Therefore, control technologies based on the catalytic combustion characteristics are researched and developed dynamically. Especially, the stable control of catalytic combustion is an essential factor in a view of maximizing its efficiency. In this research, the fuel equivalence ratio and the preheating temperature of mixture gas is controlled by catalytic combustion system enhanced in heat transfer with high temperature heat exchanger. As a result, the combustion characteristics of system was investigated, and both passive and active control type were compared and analyzed.