• KSBB Journal
• /
• 제5권4호
• /
• pp.397-402
• /
• 1990

Hydrolysis of inulin was investigated employing various commercially available resin catalysts for the production of high grade fructose syrup. The particle size and porosity of the resin significantly affected the distribution of the products, indicating that the intraparticle diffusion of reactants controls thc selectivity as well as the reaction rate. To confirm the effect of the intraparticle diffusion, two different types of resin catalysts were prepared: the one having sulfonic acid group distributed uniformly throughout genular microparticles (A-type) and the other having sulfonic acid group located mainly at the exterior surface of genular microparticles (E-type). The results were found that the reaction rate and the selectivity of the E-type catalyst were higher than those of the A-type catalyst.

• 한국표면공학회지
• /
• 제24권3호
• /
• pp.162-168
• /
• 1991

Gas diffusion and electrolyte penetration in wetproofed gas diffusion electrodes were studied using layers of PTFE- bonded carbon. Minor variations in fabrication and testing procedures resulted in very large variations in catalyst layer wetting characteristics and permiability for reaction gas. By controlling the pore size of gas diffusion electrode carefully by varing the PTFE contents, baking temperature, baking time and ammonium bicarbonate as additive, the primary pore was decreased and the secondary pore was increased and so more reaction gas through the primary pore could be reacted at catalyst agglomertes in the secondary pore. And the cathode current density was increased to more than 400mA.$\textrm{cm}^2$ and Tafel slope value was decreased to lower than 110mA/decade.

• 한국수소및신에너지학회논문집
• /
• 제25권4호
• /
• pp.419-424
• /
• 2014

Direct ethanol fuel cell has been fabricated with ceramic membrane. A porous silicon carbide (SiC) membrane having approximately 30% porosity has been applied for a direct ethanol proton exchange membrane (DE-PEM) fuel cell. A horizontal type cell having Pt ($18mg/cm^2$) catalyst layer on both side of the ceramic membrane was used for the demonstration test. The ethanol oxidation based-fuel cell stack showed very high voltage (1.289V) and measurable current level (68mA) even though at room temperature.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
• /
• pp.652-655
• /
• 2009

The bimodal porous carbons were synthesized by using imprinting method with templates of SBA-15 particle and silica sphere and applied as supporting materials for the electro-catalyst of polymer electrolyte fuel cell (PEFC). The silica spheres with diameter size of 100 nm and SBA-15 particle having 200 nm -250 nm diameter and 700 nm -900 nm length were synthesized in this work. The bimodal porous carbons (S100) were prepared by using the silica spheres and SBA-15 as templates and mesophase pitch as a carbon source. The PtRu nanoparticle of ca. 1.9 nm were supported on the bimodal porous carbon support and the resulting PtRu/S100 catalysts was tested by the cyclic voltammetry. The use of bimodal porous carbon showed in comparable electro-catalytic activities with commercial catalyst. Though unclear effects of bimodal porosity of supports could be obtained in the scope of this study, morphological advantage in electrical conductivity can be considered on the electro-catalytic activity.

• 공업화학
• /
• 제31권1호
• /
• pp.61-66
• /
• 2020

본 연구에서는 압착·코팅방식 촉매 제조 공정에 첨가제로 사용되는 콜로이드 실리카의 특성이 제조된 촉매의 성능 및 열적 안정성에 미치는 영향을 연구하였다. 이를 위해 4종의 콜로이드 실리카를 대상으로 실리카 형상 및 크기, 비표면적 및 기공특성, 성분 등을 분석하였으며 해당 콜로이드 실리카를 적용하여 제조한 V₂O₅/TiO₂ 촉매의 특성 평가 및 NOx 전환율에 대한 연구를 수행하였다. 콜로이드 실리카를 이용하여 제조한 촉매의 특성은 적용한 콜로이드 실리카의 특성에 따라 달라지며, 특히 콜로이드 실리카 내 피독물질 함량은 촉매 성능에 직접적인 영향인자인 것으로 분석되었다. 또한 콜로이드 실리카 내 실리카 함량이 높을수록 촉매의 열안정성과 성능이 향상되는 것으로 나타났다.

• 분석과학
• /
• 제15권3호
• /
• pp.256-262
• /
• 2002

평균입자크기가 200 ${\mu}m$인 코디어라이트 분말을 사용하여 다공성 필터를 제조한 후, 진공함침법으로 $V_2O_5$, CuO, $LaCoO_3$ 촉매를 담지시킨 후 NO와 $SO_2$ 기체를 촉매 담지 세라믹필터에 동시 통과시키면서 NOx/SOx의 동시제거효율을 측정하였다. 제조된 다공성 필터의 기공률은 61.6%였고, 압축강도는 12.3 MPa이었으며, 면속도 5 cm/sec에서의 차압은 147 Pa이었다. NO와 $SO_2$의 동시제거효율을 분석해 본 결과, 페로브스카이트계 $LaCoO_3$ 촉매의 동시제거효율이 가장 우수함을 확인하였으며, $LaCoO_3$ 촉매의 NO에 대한 제거효율은 90% 이상, $SO_2$에 대해서는 80% 이상이었다.

• 청정기술
• /
• 제23권2호
• /
• pp.140-147
• /
• 2017

본 연구에서는 연료전지용 디젤 흡착 탈황 반응기에 사용된 촉매를 재생하는 공정을 수치해석을 통해 모사하고 분석하여 관련된 기초 공정 정보를 도출하였다. 촉매 재생에 사용되는 질소 퍼지가스의 유량, 충전된 탈황촉매의 투과율, 반응기의 크기, 반응기의 단열 성능에 따른 정상상태 해석을 통해 각각의 요소가 촉매 재생에 미치는 영향들을 살펴보았다. 온도의 영향을 거의 받지 않았던 탈황공정과 달리 촉매의 재생 공정에서는 온도 변화에 따라 영향을 크게 받았으며 이전 탈황 연구에서 중요한 공정 변수였던 충전된 촉매의 투과도, 충전층의 공극률 등은 큰 영향을 미치지 못했다. 비정상상태 해석을 수행하여 재생에 소요되는 시간을 예측하였으며 퍼지가스의 유량과 온도를 변화시키며 재생에 소요되는 시간을 분석한 결과, 퍼지가스의 유량을 높이는 것 보다 온도를 높이는 것이 재생에 더 효율적임을 확인하였다. 본 연구 결과는 선박 연료전지용 디젤의 흡착 탈황 반응기의 재생 공정 개발에 활용될 것으로 기대된다. 또한 본 결과는 연료전지뿐 아니라 일반적으로 정유사에서 생산되는 디젤유의 황 함유량을 감소시키는 저황 시스템 디자인에 활용될 수 있으며 이러한 의미에서 석유화학 산업의 청정화 기술 확보에 이바지할 것으로 기대된다.

• 한국분말재료학회지
• /
• 제22권2호
• /
• pp.100-104
• /
• 2015

The porous metals are known as relatively excellent characteristic such as large surface area, light, lower heat capacity, high toughness and permeability. The Fe-Cr-Al alloys have high corrosion resistance, heat resistance and chemical stability for high temperature applications. And then many researches are developed the Fe-Cr-Al porous metals for exhaust gas filter, hydrogen reformer catalyst support and chemical filter. In this study, the Fe-Cr-Al porous metals are developed with Fe-22Cr-6Al(wt) powder using powder compaction method. The mean size of Fe-22Cr-6Al(wt) powders is about $42.69{\mu}m$. In order to control pore size and porosity, Fe-Cr-Al powders are sintered at $1200{\sim}1450^{\circ}C$ and different sintering maintenance as 1~4 hours. The powders are pressed on disk shapes of 3 mm thickness using uniaxial press machine and sintered in high vacuum condition. The pore properties are evaluated using capillary flow porometer. As sintering temperature increased, relative density is increased from 73% to 96% and porosity, pore size are decreased from 27 to 3.3%, from 3.1 to $1.8{\mu}m$ respectively. When the sintering time is increased, the relative density is also increased from 76.5% to 84.7% and porosity, pore size are decreased from 23.5% to 15.3%, from 2.7 to $2.08{\mu}m$ respectively.

• 한국세라믹학회지
• /
• 제44권10호
• /
• pp.574-579
• /
• 2007

Porous $Al_2O_3$ ceramics were prepared by the gelcasting foams method (a slurry foaming process) with acrylamide monomer. The foaming and gelation behavior was investigated with the parameters such as the type and concentration of surfactant, solid loading of slurry, and the concentrations of initiator and catalyst. Density, porosity, microstructure, and strength of the green and sintered samples were characterized. Of the four kinds of surfactants tested, Triton X-114 showed the highest foaming ability for the solid loading of 55-30 vol%. The gelation condition giving the idle time off min was found to set the foamed structure without significant bubble enlargement and liquid lamella thinning. The green samples were fairly strong and machinable and showed maximum strength of 2.4 MPa in diametral compression. The sintered samples showed densities of 10-36% theoretical (i.e. porosity 90-64%) with a highly interconnected network of spherical pores with sizes ranging from 30 to $600{\mu}m$. The pore size and connectivity increased but the cell strut thickness decreased with decreasing the solid loading. Flexural strength of 37.8-1.7 MPa was obtained for the sintered samples.

• 한국세라믹학회지
• /
• 제43권8호
• /
• pp.472-478
• /
• 2006

The effect of compositional and processing variables on a nitriding reaction of silicon powder compact and subsequent post sintering of RBSN (Reaction-Bonded Silicon Nitride) was investigated. The addition of a nitriding agent enhanced nitridation rate substantially at low temperatures, while the formation of a liquid phase between the nitriding agent and the sintering additives at a high temperature caused a negative catalyst effect resulting in a decreased nitridation rate. A liquid phase formed by solely an additive, however, was found to have no effect on nitridation for the additive amount used in this research. The original site of a decomposing pore former was loosely filled by a reaction product ($Si_3N_4$), which provided a specimen with nitriding gas passage. For SRBSN (Sintered RBSN) specimens of high porosity, only a marginal dimensional change was measured after post sintering. Its engineering implication for near-net shaping ability is discussed.