• 헤리티지:역사와 과학
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• 제50권2호
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• pp.40-61
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• 2017

본 연구는 구리 갈매유적 회곽묘의 회곽을 대상으로 물리화학적 및 암석광물학적 분석을 통해 성분 및 재질특성을 밝혔으며 다양한 강도시험을 수행하였다. 회곽의 대부분에서는 은미정질의 방해석과 함께 석영, 장석 및 운모가 동정되었으며 주로 석회기질로 구성되어 있다. 석회질 기질은 판상의 치밀한 조직을 보이고 일부 시료에서는 침상조직의 수화물이 나타나며, 탄산화반응이 불량한 부분에서는 이차적으로 생성된 석고가 관찰된다. 회곽의 CaO 함량은 4.43~36.19wt.%의 넓은 범위에서 확인되며, 비중은 1.35~1.62의 범위에서, 흡수율은 20.1~32.6%를 보인다. 반발경도는 10.0~28.4(평균 15.7)의 범위를 나타냈으며 $-90^{\circ}$ 방향이 $0^{\circ}$ 방향에 비해 높은 값을 보여 지면과 수직한 방향으로 높은 강도를 갖는 것으로 판단된다. 방향에 따른 강도차이는 회곽의 조성에 방향성이 있기 때문이며 이는 단계별 제작과정과 관련이 있다. 초음파속도는 1,049.2~1,728.9m/s의 범위이며, 일축압축강도는 5.00MPa 이하로서 양자의 유구별 변화경향은 유사하다. 회곽의 성분과 강도를 비교한 결과, CaO 함량이 높을수록 높은 강도를 보이나 차이는 크지 않으며, 전반적인 제작기술과 숙련도는 비교적 낮았던 것으로 해석된다.

• Journal of the Korean Wood Science and Technology
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• 제30권4호
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• pp.87-95
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• 2002

3종류의 국내산 대나무의 생재 및 기건재를 3종류의 탄화로에서 탄화시키고 얻어진 죽초액에 대하여 그 특성을 검토하였다. 기계식 전용탄화로의 경우, 대부분 1단 회수 죽초액의 비중, 유기산 및 용해 타르 함량이 높았으나 2단 이상에서 감소하여 3단 이후에 일정해지는 경향을 나타내었으며 전체적으로는 기건재가 생재에 비해 이들 물성이 높게 나타났다. pH의 경우 맹종죽 기건재를 제외하고 생재가 기건재보다 높게 나타났다. 3성분합계는 비중, 유기산, 용해타르 함량과 유사한 경향을 나타내었다. 개량탄화로의 경우, 수종에 따라 전체 물성이 다양하게 나타났다. 간이탄화로에서 탄화시켜 연통온도 80℃로 얻어진 기건 죽초액의 경우 그 이상의 온도에서 얻어진 죽초액보다 비중, 용해타르 함량 및 3성분 합계가 높게 나타났다. 간이, 개량 및 기계식 전용탄화로에서 얻어진 죽초액의 비중은 온도, 수분함유 상태에 상관없이 유기산과 용해타르 함량의 합계와 0.90 정도의 높은 상관관계를 나타내어 앞으로 죽초액 품질 결정에 중요한 지표로 사용될 가능성이 시사되었다. 죽초액의 구성 유기성분의 경우 초산이 주성분이었으며, 리그닌의 열분해에 의하여 생성되는 guaiacyl 및 syringyl골격의 페놀류가 다량 검출되었다.

• Carbon letters
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• 제19권
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• pp.72-78
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• 2016

Spinnable pitches and carbon fibers were successfully prepared from petroleum or coal pyrolysis residues. After pyrolysis fuel oil (PFO), slurry oil, and coal tar were simply filtered to eliminate the solid impurities, the characteristics of the raw materials were evaluated by elemental analysis, ¹³C nuclear magnetic resonance spectrometer, matrix-assisted laser desorption/ionization time-of-flight mass spectrometer (MALDI-TOF-MS), and so on. Spinnable pitches were prepared for melt-spinning carbon fiber through a simple distillation under strong nitrogen flow, and further vacuum distillation to obtain a high softening point. Carbon fibers were produced from the above pitches by single-hole melt spinning and additional heat treatment, for oxidization and carbonization. Even though spinnable pitches and carbon fibers were processed under the same conditions, the melt-spinning and properties of the carbon fiber were different depending on the raw materials. A fine carbon fiber could not be prepared from slurry oil, and the different diameter carbon fibers were produced from the PFO and coal tar pitch. These results seem to be closely correlated with the initial characteristics of the raw materials, under this simple processing condition.

• 한국지하수토양환경학회지:지하수토양환경
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• 제25권1호
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• pp.95-105
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• 2020

In this study, iron nanoparticles impregnated hydrochar (FeNPs@HC) was synthesized using lignocellulosic waste and simple one-pot synthetic method. During hydrothermal carbonization (HTC) process, the mixture of lignocellulosic waste and ferric nitrate (0.1~0.5 M) as a precursor of iron nanoparticles was added and heated to 220℃ for 3 h in a teflon sealed autoclave, followed by calcination at 600℃ in N₂ atmosphere for 1 h. For the characterization of the as-prepared materials, X-ray diffraction (XRD), cation exchange capacity (CEC), fourier transform infrared spectrometer (FT-IR), Brunauer-Emmett-Teller (BET), transmission electron microscope (TEM), Energy Dispersive X-ray Spectroscopy (EDS) were used. The change of Fe(III) concentration in the feedstock influenced characteristics of produced FeNPs@HC and removal efficiency towards As(V) and Pb(II). According to the Langmuir isotherm test, maximum As(V) and Pb(II) adsorption capacity of Fe_0.25NPs@HC were found to be 11.81 and 116.28 mg/g respectively. The results of this study suggest that FeNPs@HC can be potentially used as an adsorbent or soil amendment for remediation of groundwater or soil contaminated with arsenic and cation heavy metals.

• 반도체디스플레이기술학회지
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• 제8권4호
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• pp.31-36
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• 2009

In this paper, the laser cutting characteristics of the flexible PCB using high power Nd:YAG UV laser were investigated. A specific FPCB model was selected for the experiment. Test sheets were made, which had equal materials and layer structure to those of the outline (OL) region and the contact pad (CP) region in the FPCB. The experiment is made up of two stages. In the first stage of the experiment, the laser cutting fluence was found, which is the threshold fluence to cut the test sheets completely. The laser cutting fluence of the OL sheet is $1781.26{\sim}1970.16\;J/cm^2$ and that of the CP sheet is $2109.34{\sim}2134.34\;J/cm^2$. In the second stage, cutting performance and its qualities were analyzed by the experiment. The laser cutting performance remained almost unchanged for all laser and process parameter sets. The average cutting width (top side/bottom side) of the OL sheet was $40.45\;{\mu}m/11.52\;{\mu}m$ and that of the CP sheet was $22.14\;{\mu}m/10.93\;{\mu}m$. However, the laser cutting qualities were different according to the parameters. The adjacent region of the cutting line on the OL sheet was carbonized as the beam speed was low and the overlap coefficient was high. The surface quality around the cutting line of the CP sheet was about the same. Carbonization and debris occurred on the surface of the cutting line. As a result of the experiment, the cutting qualities were better as the overlap coefficient was made low and beam speed high. Therefore, the overlap coefficient 2 or 3 is proper for the FPCB laser cutting.

• Journal of the Korean Wood Science and Technology
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• 제39권6호
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• pp.512-520
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• 2011

본 연구에서는 탄화과정 중에 탄화로에서 발생되는 폐열을 활용하기 위해서 친환경건조시스템을 개발하여 그 특성을 검토하였다. 친환경건조시스템은 화석연료를 전혀 이용하고 있지 않고, 버려지는 폐열을 이용하기 때문에 환경친화적이다. 친환경건조시스템의 열원으로 이용되는 열수는 3개의 탄화로에 서로 연결되어 폐열을 회수하고 있고, 지속적인 열원의 공급으로 건조기내의 온도와 습도변화는 크지 않았다. 친환경건조시스템 설치가 목탄의 특성에 미치는 영향을 조사하기 위하여 고정탄소, 정련도, 경도, 발열량, pH, 단위중량당 발열량, 수탄율을 분석하였다. 그 결과로부터 친환경건조시스템 설치가 목탄의 특성에 크게 영향을 주지 않는 것으로 나타났다. 따라서 버려지는 폐열을 회수하여 에너지로 이용하는 친환경건조시스템은 에너지절감과 농산물의 건조품질을 향상시켜 농가의 수익을 극대화할 수 있는 효과가 있을 것으로 생각된다.

• 한국안전학회지
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• 제30권6호
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• pp.40-47
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• 2015

In this study, temperature characteristics and fire damage form were analyzed to investigate flame spreading form and fire probability from ignition sources subject to drivit component materials which is finishing material in architecture. Ignition sources were limited to a gas torch and exterior panel board fire, and the size of the sample was manufacture in 30 cm length ${\times}$ 50 cm height ${\times}$ 5cm thickness size. Marble (inner wall) + 3 mm drivit (outer wall), marble (inner wall) + 4 mm plaster stone (outer wall), sandwich panel + 3 mm driver bit (outer wall), sandwich panel + 3 mm driver bit + insulation (outer wall), and gypsum board (inner wall) + 3 mm drivit (outer wall) were prepared for the sample. As result of the research for temperature characteristics, large temperature difference by each material was shown in $218^{\circ}C{\sim}995^{\circ}C$ at 30 seconds and $501^{\circ}C{\sim}1078^{\circ}C$ at 300 seconds. Especially when the inner wall was a plaster board, lowest temperature of $501^{\circ}C$ was shown at 300 seconds and marble inner wall showed the following lowest temperature of $900^{\circ}C$. Temperature rising over $1000^{\circ}C$ was shown in other materials. Regarding fire damage form, drivit or gypsum board outer wall parts exposed to fire showed combustion and carbonization to show calcination(breaking phenomenon) and influence of heat exposure was higher as calcination became more severe.

• Korean Chemical Engineering Research
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• 제54권4호
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• pp.459-464
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• 2016

본 연구에서는 리튬이온 전지용 실리콘 음극소재의 사이클 안정성 및 율속 특성 향상을 위해 다공성 실리콘/탄소 복합소재의 전기화학적 특성을 조사하였다. 나노 실리카 제조는 스토버 방법을 사용하고 교반 속도, 교반 온도 및 $NH_3$/TEOS 비율을 조절 하여 100~500 nm 크기의 구형 실리카를 합성하였다. 구형 나노 실리카의 마그네슘 열환원과 산처리 과정을 통해 다공성 실리콘을 얻고, 제조된 다공성 실리콘에 Phenolic resin을 탄소전구체로 사용하여 최종적으로 다공성 실리콘/탄소 활물질을 합성하였다. 또한 $LiPF_6$ (EC:DMC:EMC=1:1:1 vol%) 전해액에서 다공성 실리콘/탄소 음극소재의 충 방전, 순환전압 전류, 임피던스 테스트 등의 전기화학적 특성을 조사 하였다. 다공성 실리콘/탄소 복합소재의 음극활물질로서 코인 전지의 성능을 조사한 결과 초기용량 및 40사이클 용량 보존율은 각각 2,006 mAh/g, 55.4%를 나타내었다.

• Environmental Engineering Research
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• 제25권4호
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• pp.536-544
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• 2020

To address organic dye wastewater, economic and effective adsorbents are required. Here, magnetic biochar from alkali-activated rice straw (AMBC) was successfully synthesized using one-step magnetization and carbonization method. The alkaline activation caused the large specific surface area, high pore volume and abundant oxygen-containing groups of the AMBC, and the magnetization gave the AMBC a certain degree of electropositivity and fast equilibrium characteristics. These characteristics collectively contributed to a relative high adsorption capacity of 53.66 mg g^-1 for this adsorbent towards rhodamine B (RhB). In brief, RhB can spontaneously adsorb onto the heterogeneous surface of the AMBC and reach the equilibrium in 60 min. Although the initial pH, ionic strength and other substances of the solution affected the adsorption performance of the AMBC, it could be easily regenerated and reused with considerable adsorption content. Based on the results, H-bonds, π-π stacking and electrostatic interactions were speculated as the primary mechanisms for RhB adsorption onto the AMBC, which was also demonstrated by the FTIR analysis. With the advantageous features of low cost, easy separation, considerable adsorption capacity and favorable stability and reusability, the AMBC would be a potential adsorbent for removing organic dyes from wastewater.

• 한국안전학회지
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• 제28권3호
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• pp.69-73
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• 2013

The purpose of this paper is to analyze the carbonization pattern and operation characteristics of an MCCB. The MCCB is consisted of the actuator lever, actuator mechanism, bimetallic strip, contacts, up and down operator, arc divider or extinguisher, metal operation pin, terminal part, etc. When the actuator lever of the MCCB is at the top or the internal metal operation pin is in contact with the front part, the MCCB is turned on or off. It means trip state if the actuator lever or the internal metal operation pin moves to back side. In the UL 94 vertical combustion test, white smoke occurred from the MCCB when an average of 17~24 seconds elapsed after the MCCB was ignited and black smoke occurred when an average of 45~50 seconds elapsed. It took 5~6 minutes for the MCCB surface to be half burnt and took an average of 8~9 minutes for the MCCB surface to be entirely burnt. In the UL 94 test, the MCCB trip device operated when an average 7~8 minutes elapsed. If the MCCB trip has occurred, it may have been caused by an electrical problem such as a short-circuit, overcurrent, etc., as well as fire heat. From the entire part combustion test according to KS C 3004, it was found that the metal operation pin could be moved to the MCCB trip position without any electrical problems.