• Journal of the Korean Ceramic Society
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• v.54 no.5
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• pp.380-387
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• 2017

In this study, unstable CaO was converted into a stable Ca compound by using carbonation in a circulating fluidized bed boiler of fly ash to confirm material usability as cement admixture; also undertaken was carbonation test and mortar to examine chemical and physical change by measuring absorption rate and compressive strength. To investigate the chemical properties of circulating fluidized bed boiler fly ash, XRD and TG-DTA were used to determine how the properties of the reaction product change quantitatively during carbonation. In order to stabilize CaO, carbonation of CaO is considered to be the most desirable process. This is because $CaCO_3$, which is a Ca compound, was produced by carbonate reaction of unstable CaO, and decrease of the absorption rate and improvement of the compressive strength were observed when the carbonated fly ash was replaced with cement.

• Advances in concrete construction
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• v.11 no.2
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• pp.99-109
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• 2021

Slag blended concrete is widely used as a mineral admixture in the modern concrete industry. This study shows an optimization process that determines the optimal mixture of air-entrained slag blended concrete considering carbonation durability, frost durability, CO2 emission, and materials cost. First, the aim of optimization is set as total cost, which equals material cost plus CO2 emission cost. The constraints of optimization consist of strength, workability, carbonation durability with climate change, frost durability, range of components and component ratio, and absolute volume. A genetic algorithm is used to determine optimal mixtures considering aim function and various constraints. Second, mixture design examples are shown considering four different cases, namely, mixtures without considering carbonation (Case 1), mixtures considering carbonation (Case 2), mixtures considering carbonation coupled with climate change (Case 3), and mixtures of high strength concrete (Case 4). The results show that the carbonization is the controlling factor of the mixture design of the concrete with ordinary strength (the designed strength is 30MPa). To meet the challenge of climate change, stronger concrete must be used. For high-strength slag blended concrete (design strength is 55MPa), strength is the control factor of mixture design.

• Journal of the Korean Ceramic Society
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• v.51 no.2
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• pp.107-114
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• 2014

In the present work, we report a novel microstructure of scalenohedral calcite synthesized without any additives by a simple and ecofriendly carbonation process carried out in a liquid-gas system as well as the effects of experimental conditions on the crystal growth of the scalenohedral calcite phase. Various process parameters, pH, temperature, $Ca(OH)_2$ concentration, $CO_2$ flow rates, and the total volume concentration, were investigated to enhance the sensitivity of the process. The highest average length of the scalenohedral calcite was obtained at pH 6.0, temperature of $45^{\circ}C$, $Ca(OH)_2$ concentration of 0.2M, $CO_2$ flow rate of 80mL/min, and total volume of 1L. The synthesized calcite was characterized by XRD, SEM, and FTIR to identify the phases and surface morphology.

• Computers and Concrete
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• v.6 no.1
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• pp.1-18
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• 2009

Chloride diffusivity of concrete is a crucial material parameter for service life determination and durability designing of marine concrete. Many research works on this issue have been conducted, varying from empirical solutions obtained experimentally to image analysis, based on multi-scale modeling. One of the simple approaches is to express the chloride diffusivity of concrete by a multi-factor function, however, the influences of various factors on the chloride diffusivity are ambiguous. Furthermore, the majority of these research works have not dealt with the carbonation process of concrete, although this process affects the chloride diffusivity of concrete significantly. The purpose of this study is to establish a simple approach to calculate the chloride diffusivity of (non)carbonated concrete. The chloride diffusivity of concrete should be defined, based on engineering and scientific knowledge of cement and concrete materials. In this paper, a lot of parameters affecting the chloride diffusivity, such as the diffusivity in pore solution, tortuosity, micro-structural properties of hardened cement paste, volumetric portion of aggregate, are taken into consideration in the calculation of the chloride diffusivity of noncarbonated concrete. For carbonated concrete, reduced porosity due to carbonation is calculated and used for calculating the chloride diffusivity. The results are compared with experimental data and previous research works.

• Membrane Journal
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• v.1 no.1
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• pp.59-59
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• 1991

A theoretical and experimental study made in order to determine the performance of mem-brane contactors in water carbonation is presented. In particular on the basis of experimental results pre-viously obtained it has been derived an expression in which the effect of some parameters as temprera-ture water and CO₂ flow rate CO₂ pressure trans-membrane pressure on the performance of the process is taken into account. The study refers to hollow fiber membrane contactors used for the experimental tests. The main scope has been to verify if by membrane contactors it is possible to reach the same de-gree of water carbonation as by trditional methods (1-5 g/1) and to derive for the module used a cor-relation able to describe the performance of the process at several operating conditions. The high CO₂ removal observed confirms the interesting potentialties of membrane contactors also in gas streams purification.

• Korean Chemical Engineering Research
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• v.55 no.4
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• pp.443-455
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• 2017

This article provides an exclusive overview of the synthesized aragonite precipitated calcium carbonate and its applications in various fields. The last decade has seen a steady increase in the number of publications describing the synthesis, characterization and applications of calcium carbonate morphologies. Mainly, two kinds of processes have been developed for the synthesis of aragonite precipitated calcium carbonate under controlled temperature, concentrations and aging, and the final product is single-phase needle-like aragonite precipitated calcium carbonate formed. This review is mainly focused on the history of developed methods for synthesizing aragonite PCC, crystal growth mechanisms and carbonation kinetics. Carbonation is an economic, simple and ecofriendly process. Aragonite PCC is a new kind of functional filler in the paper and plastic industries, nowadays; aragonite PCC synthesis is the most exciting and important industrial application due to numerous attractive properties. This paper describes the aragonite PCC synthetic approaches and discusses some properties and applications.

• Korean Membrane Journal
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• v.1 no.1
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• pp.59-64
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• 1999

A theoretical and experimental study made in order to determine the performance of mem-brane contactors in water carbonation is presented. In particular on the basis of experimental results pre-viously obtained it has been derived an expression in which the effect of some parameters as temprera-ture water and {{{{{CO }_{2 } }}}}} flow rate {{{{{CO }_{2 } }}}}} pressure trans-membrane pressure on the performance of the process is taken into account. The study refers to hollow fiber membrane contactors used for the experimental tests. The main scope has been to verify if by membrane contactors it is possible to reach the same de-gree of water carbonation as by trditional methods (1-5 g/1) and to derive for the module used a cor-relation able to describe the performance of the process at several operating conditions. The high {{{{{CO }_{2 } } }}}} removal observed confirms the interesting potentialties of membrane contactors also in gas streams purification.

• Journal of the Korean Ceramic Society
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• v.53 no.1
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• pp.7-12
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• 2016

In this paper, we have developed a simple, new and economical carbonation method to synthesize a pure form of aragonite needles using dolomite raw materials. The obtained aragonite Precipitated Calcium Carbonate (PCC) was characterized by XRD and SEM, for the measurement of morphology, particle size, and aspect ratio (ratio of length to diameter of the particles). The synthesis of aragonite PCC involves two steps. At first, after calcinated dolomite fine powder was dissolved in water for hydration, the hydrated solution was mixed with aqueous solution of magnesium chloride at $80^{\circ}C$, and then $CO_2$ was bubbled into the suspension for 3 h to produce aragonite PCC. Finally, aragonite type precipitated calcium carbonate can be synthesized from natural dolomite via a simple carbonation process, yielding product with average particle size of $30-40{\mu}m$.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.193-196
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• 2006

A carbonation shortens the endurance life of RC structure. So, to lengthen endurance life of RC structure, we use some kinds of surface-finishes. Because surface-finishes have abilities such as restraint against penetration and diffusion of CO2. In this study, we wanted to know whether we can evaluate the restrain effect of each surface-finish against carbonation with using FEM analysis. After study, we found that it is possible and we also evaluate the restrain effect of any other surface-finishes against carbonation through this process.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.10a
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• pp.47-48
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• 2016

Mineral carbonation technology is a process whereby CO₂ is chemically reacted with calcium-and/or magnesium-containing minerals to form stable carbonate materials. Add the Materials that could fix CO₂ as mineral admixture to concrete can improve the anti-carbonation properties of concrete. This paper has carried on the literature research on the carbonated mechanism of Material that could fix carbon dioxide. Such as Brucite, 𝜞-C₂S, Mg₂SiO₄, MgO, Ca₃MgSi₂O₈. And summarizes the development of the development of this field.