• Journal of the Korea Concrete Institute
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• v.17 no.3 s.87
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• pp.411-418
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• 2005

Polymer-modified mortar and concrete are prepared by mixing either a polymer or monomer in a dispersed, or liquid form with fresh cement mortar and concrete mixtures, and subsequently curing, and if necessary, the monomer contained in the mortar or concrete is polymerized in situ. Although polymers and monomers in any form such as latexes, water-soluble polymers, liquid resins, and monomers are used in cement composites such as mortar and concrete, it is very important that both cement hydration and polymer phase formation proceed well the yield a monolithic matrix phase with a network structure in which the hydrated cement phase and polymer phase interpenetrate. In the polymer-modified mortar and concrete structures, aggregates are bound by such a co-matrix phase, resulting in the superior properties of polymer-modified mortar and concrete compared to conventional mortar and concrete. The purpose of this study is to obtain the necessary basic data to develope appropriate latexes as cement modifiers, and to clarify the effects of the monomer ratios and amount of emulsifier on the properties of the polymer-modified mortars using methyl methacrylate-butyl acrylate(MMA/BA) and methyl methacrylate-ethyl acrylate(MMA/EA) latexes. The results of this study are as follows, the water absorption, chloride ion penetration depth and carbonation depth of MMA/BA-modified mortar are lowest. However, they are greatly affected by the polymer-cement ratio rather than the bound MMA content and type of polymer.

• Journal of the Korea Concrete Institute
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• v.26 no.1
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• pp.71-78
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• 2014

The long term integrity of concrete cask is very important for spent nuclear fuel dry storage system. However, there are serious concerns about early deterioration of concrete cask from creaking and corrosion of reinforcing steel by chloride ion because the cask is usually located in seaside, expecially by combined deterioration such as chloride ion and heat, carbonation. This study is to investigate the relation between temperature and chloride ion diffusion of concrete. Immersion tests using 3.5% NaCl solution that were controlled in four level of temperature, i.e. 20, 40, 65, and $90^{\circ}C$, were conducted for four months. The chloride ion diffusion coefficient of concrete was predicted based on the results of profiles of Cl- ion concentration with the depth direction of concrete specimens using the method of potentiometric titration by $AgNO_3$. Test results indicate that the diffusion coefficient of chloride ion increases remarkably with increasing temperature, and there was a linear relation between the natural logarithm values of the diffusion coefficients and the reciprocal of the temperature from the Arrhenius plots. Activation energy of concrete in this study was about 46.6 (W/C = 40%), 41.7 (W/C = 50%), 30.7 (W/C = 60%) kJ/mol under a temperature of up to $90^{\circ}C$, and concrete with lower water-cement ratio has a tendency towards having higher temperature dependency.

• Magazine of the Korea Concrete Institute
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• v.6 no.6
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• pp.159-172
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• 1994

The relmund hammer test and ultrasonic pulse velocity test methods are commonly used to determine the in-situ compressive strength of concrete. One of the special feature of these methods is that they cannot give consistent and reliable results for variety of structures. In particular, very old existing structures have been generally received sreious environmental affectsand thus the strength prediction will be different from normal structures. The purpose of the present study is, therefore, to propose realistic equations to predict the in-situ strengths of actual old concrete structures. The rebound hammer and ultrasonic pulse velocity tests, carbonation depth measurments and core compressive strength measurements have been carried out for very old hydraulic and seacoast concrete structures spanning from one to about seventy years in age. From these test results, the strength-rebound number relations, the strength-pluse velocity relatinns and the strength-rebound number-pluse velocity relations have been obtained through multiple regression analysis. The present study indicates that the existing equations by nondestructive tests give quite different results from the present data. The proposed equations reasonably well predict the measured data for old concrete structures, especially for low strength concrete. The prediction equations proposed here can be efficiently used in determining the in-situ strength of old concrete structures.

• Journal of the Korea Concrete Institute
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• v.18 no.6 s.96
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• pp.801-809
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• 2006

Epoxy resin has widely been used as adhesives and corrosion-resistant paints in the construction industry for many years, since it has desirable properties such as high adhesion and chemical resistance. Until now, in the production of conventional epoxy cement mortars, the use of any hardener has been considered indispensable for the hardening of the epoxy resin. However we have noticed the fact that even without any hardener, the hardening process of the epoxy resin can proceed by the action of hydroxides in cement mortars. As a result the disadvantages of the two-component mixing of the epoxy resin and hardener have been overcome. The purpose of this study is to evaluate the mechanical properties and durability of epoxy cement mortar without a hardener exposed at indoor and outdoor for one year. The epoxy cement mortars without and with a hardener were prepared with various polymer-cement ratios, and tested for weight change, flexural and compressive strengths, water absorption, carbonation depth and pore size distribution. Especially, the basic properties of the epoxy cement mortars without hardener are discussed in comparison with ones with the hardener. From the test results, it is concluded thai the epoxy cement mortars without a hardener exposed at indoor and outdoor for one year have higher strength and better durability than ones with the hardener within the polymer-cement ratios of 10 to 20%.

• Journal of the Korea Concrete Institute
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• v.19 no.2
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• pp.217-224
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• 2007

This study reports the properties of high early strength & durability of concrete using PC admixture. To apply these data to construction site, we did the lab tests. The target of this study is to accomplish early strength of concrete (5.0 Mpa/18 hr), and we did the durability tests such as length change test, chloride ion penetration test, fleeting and thawing test, adiabatic test, etc. And we tested the porperties of concrete by the different factors, such as the type of admixtures, curing temperature, the amount of binder, etc. Through the test of concrete using the different type of admixture, PC type was more excellent than PNS type admixture. As a result, we made a concrete of high early strength concrete, and excellent durable concrete. According to these tests, we concluded that we can apply this type of PC admixture to the civil & construction site, and we can reduce the term of works and finally we will accomplish the economical construction.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.4
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• pp.18-24
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• 2012

In this study, hybrid method using polyvinyl acetate (PVAc) which has a strong adhesion and flexibility in which acrylic copolymer chemical-reaction reacts with cement, and is eco-friendly, is to improve the watertightness. The hybrid method is applied applied primarily waterproof stuff comprising silicate system and secondary mortar mixed with PVAc on the concrete surface. And then, in order to evaluate the performance, the properties of bond strength and amount of water absorption were measured. Based on the above experiments, mock-up specimens for field application were fabricated, and then the properties were evaluated as laboratory experiments. As the results, specimens cast from hybrid method using PVAc showed the best results on watertightness and bond strength. And also, with respect to experiment of mock-up specimens, the properties were in agreement with laboratory results. Especially, it could know that PVAc has strengthening effect from the results of the compressive strength. Due to outstanding results of carbonation depth and resistance to chloride ion penetration, it may be applied in weak areas such as underground and marine structures.