• Title/Summary/Keyword: Carbon-monoxide

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Glycerol Carbonate Synthesis by Glycerol Oxidative Carbonylation over Copper Catalysts (구리 촉매상에서 글리세롤의 산화 카르보닐화 반응에 의한 글리세롤 카보네이트 합성)

  • Choi, Jae Hyung;Lee, Sang Deuk;Woo, Hee Chul
    • Clean Technology
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    • v.19 no.4
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    • pp.416-422
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    • 2013
  • In environmental friendly aspects, the synthesis of glycerol carbonate from glycerol using carbon monoxide and oxygen gases which were produced in petrochemical plants was studied. The oxidative carbonylation of glycerol under batch reaction system was performed on parameter conditions such as effect of various metals (Cu, Pd, Fe, Sn, Zn, Cr), oxidizing agents, mole ratio of carbon monoxide to oxygen, catalyst amount, solvent types, reaction temperature and time and dehydrating agents. In particular copper chloride catalysts showed the excellent activities, and the glycerol carbonate yields over CuCl and $CuCl_2$ catalysts were the maximum of 44% and 64%, respectively at the following reaction conditions: solvent as nitrobenzene, mole ratio of 1:3:0.15 (glycerol:carbon monoxide:catalyst), mole ratio of 2:1 (carbon monoxide:oxygen), the total pressure of 30 bar at 413 K for 4 hr. It was found that reactivity were significantly different depending on the oxidation number of Cu catalysts, and oxygen plays an important role as oxidizing agents in producing H2O during oxidation reaction after carbonylation of glycerol.

The Effect of Aerobic Exercise on Exhaled Carbon Monoxide and Cardiorespiratory Function of Female College Students who Participated in Nonsmoking (유산소운동이 금연에 참여한 여자대학생의 호기 일산화탄소 및 호흡순환기능에 미치는 영향)

  • Kim, Seung-Suk
    • Journal of Industrial Convergence
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    • v.18 no.5
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    • pp.30-35
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    • 2020
  • The purpose of this study is to find out the effect of aerobic exercise through convergence on exhaled carbon monoxide and cardiorespiratory function of female college students who participated in nonsmoking. The subjects were female college students from University D in Metropolitan City D, and those who started smoking 2 years ago and who do not engage in regular physical activities were first selected, and a total of 18 people who indicated their intention to participate in the experiment were selected to receive a pledge of nonsmoking and consent to the experiment. The selected subjects were classified into 9 people in the exercise group and 9 in the control group by wireless assignment, and individual exercise intensity was set through the maximum exercise load test to establish an accurate exercise program. Individual exercise intensity is set to 50%HRmax for 1-3 weeks, 60%HRmax for 4-6 weeks, 70%HRmax for 7-9 weeks. In order to apply the correct exercise intensity during exercise, a Polar heart rate monitor was used for control and the following results were obtained. First, the change in carbon monoxide decreased by three levels from 21.17±3.67ppm (Red 2 16-25ppm, habitual smokers) before participation in the exercise group that participated in aerobic exercise for 9 weeks to 1.36±0.76ppm (Green, 0-6ppm, non-smokers) after participation, and the control group also showed the same effect from 22.35±2.08ppm (Red 2 16-25ppm, habitual smokers) to 2.81±0.51ppm (Green, 0-6ppm, non-smokers). Second, the change in cardiorespiratory function showed a significant increase in all of the maximum oxygen intake, maximum heart rate, and maximum ventilation in the exercise group who participated in aerobic exercise for 9 weeks, but there was no significant change in the control group. Therefore, aerobic exercise showed the effect of improving the cardiorespiratory function by releasing carbon monoxide and supplying sufficient oxygen to various organs.

A Case Study of Patient with Delayed Encephalopathy after Carbon Monoxide Poisoning Improved by Korean Traditional Treatment, Especially Boshiniknoe-tang-gami (일산화탄소 중독 이후 지연성 뇌손상에 대한 보신익뇌탕가미방의 효과 1례 : case report)

  • Bae, Go-eun;Park, Hye-lim;Hong, Minna;Cho, Jae Hyun;Choi, Jin Yong;Hong, Jin woo;Kwon, Jung Nam;Kim, So Yeon;Choi, Jun Young;Han, Chang Woo;Yun, Young Ju;Park, Seong-ha;Lee, In
    • The Journal of the Society of Stroke on Korean Medicine
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    • v.17 no.1
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    • pp.29-38
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    • 2016
  • This case report is to show the effects of Traditional Korean medicine (TKM) on the patient with delayed encephalopathy after carbon monoxide poisoning. A patient with delayed encephalopathy after carbon monoxide poisoning occurs rarely and only a few cases have been reported. We treated a patient with cognitive deficit, gait disturbance was treated with herbal medicine(Boshiniknoe-tang-gami), acupuncture, moxibustion. We evaluated the improvements of symptoms by Korean Version of Mini Mental Status Examination score(K-MMSE), Modified Barthel Index(MBI) and Glasgow Coma Scale(GCS). After 3 weeks, total score of K-MMSE was increased from 12 to 17 and it was maintained to week 6. After 6 weeks, total score of MBI was increased from 30 to 86. And GCS was increased from 11 to 14. This report proved effect of Traditional Korean medicine on the improvement of delayed encephalopathy after carbon monoxide poisoning

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A Case of Delayed encephalopathy after Acute Carbon Monoxied Intoxication (일산화탄소 중독 후 발생된 지연성 뇌병증 환자의 치험 및 호전 1예)

  • 김동은;김경훈;김정석;신길조;이원철
    • The Journal of Korean Medicine
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    • v.22 no.3
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    • pp.169-178
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    • 2001
  • After initial recovery from acute carbon monoxide (CO) intoxication, some patients occasionally undergo severe neuropsychiatric deterioration, which is called postanoxic delayed encephalopathy (sequelae). This is the clinical report about one patient, a 73-year-old man, diagnosed with delayed encephalopathy after acute CO intoxication. The symptoms of the patient were mental dysfunction including memory impairment and disorientation, abnormal behavior, incontinence and mutism. He had completely recovered after an aonxic episode, but the neurological symptoms that developed were preceded by an interval of apparent normality (the 'lucid interval'). We characterized him as suffering deficiency syndrome of the heart and prescribed for him Bokreongbosim-tang and Guipi-tang, and thereafter his symptoms were remarkably improved. For the evaluation of clinical improvement, we use the Modified Barthel Index (MBI), Canadian Neurologic Scale (CNS), and the Korean version of the Mini-Mental State Examination (K-MMSE)

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Electron Transport System for Carbon Monoxide Oxidation in Acinetobacter sp.1 (Acinetobacter sp.1의 일산화탄소 산화를 위한 전자전달계)

  • 김영민;조진원
    • Korean Journal of Microbiology
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    • v.24 no.1
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    • pp.46-50
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    • 1986
  • Experiments with particulate fractions of Acinetobacter sp. 1 revealed that coeuzyme $Q_{10}$ is not the physiolohical electron acceptor, and that cytochromes of a, b, c, and o types are found in cells grown with carbon monoxide (CO) as the sole source of carbon and energy. It was found that cytochromes of b and o types, but not the a and c types, are functional in CO oxidation. Nicotinamide adenine dinucleotide (phosphate) is not involved in CO oxidation.

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Carbon monoxide poisoning-induced encephalopathy in a carbon dioxide arc welder: a case report

  • Seongwon Ma;Hoekyeong Seo;Dong Joon Park;Byeongju Choi;Shinhee Ye
    • Annals of Occupational and Environmental Medicine
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    • v.34
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    • pp.19.1-19.9
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    • 2022
  • Background: It is widely known that carbon dioxide (CO2) arc welding generates carbon monoxide (CO). However, to the best of our knowledge, no case reports have been published regarding CO poisoning in CO2 arc welders. Therefore, we aimed to report a case of CO poisoning-induced encephalopathy in a CO2 arc welder in the Republic of Korea to inform about the dangers of CO exposure among CO2arc welders. Case presentation: A 40-year-old man working as a CO2 arc welder for 15 years visited a local hospital with a tremor, involuntary urination, and speaking gibberish, on April 9, 2019. He stated that he had intermittent headache and forgetting symptoms for the last 5 years, and had been lost on the way to work several times. On April 9, 2019, he was diagnosed with CO poisoning-induced encephalopathy through brain magnetic resonance imaging. He received hyperbaric oxygen therapy, and some of his symptoms improved. According to the exposure assessment of his work environment, he was continuously exposed to high concentrations of CO for 15 years while operating CO2 arc welding machines. Conclusions: After evaluating the patient's work environment and evaluating his medical history, we concluded that his encephalopathy was caused by CO exposure during CO2 arc welding. Thus CO2 arc welders must be aware of the risk of CO poisoning and strive to avoid CO exposure.