• Title/Summary/Keyword: Carbon-fiber

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Effect of pH on the Synthesis of $LiCoO_2$ with Malonic Acid and Its Charge/Discharge Behavior for a Lithium Secondary Battery

  • Kim, Do Hun;Jeong, Yu Deok;Kim, Sang Pil;Sim, Un Bo
    • Bulletin of the Korean Chemical Society
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    • v.21 no.11
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    • pp.1125-1132
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    • 2000
  • The pH effect of the precursor solution on the preparation of $LiCoO_2$ by a solution phase reaction containing malonic acid was carried out. Layered $LiCoO_2$ powders were obtained with the precursors prepared at the different pHs (4, 7, and 9) and heat-treated at $700^{\circ}C(LiCoO_2-700)$ or $850^{\circ}C(LiCoO_2-850)$ in air. pHs of the media for precursor synthesis affects the charge/discharge and electrochemical properties of the $LiCoO_2electrodes.$ Upon irrespective of pH of the precursor media, X-ray diffraction spectra recorded for $LiCoO_2-850$ powder showed higher peak intensity ratio of I(003)/I(104) than that of $LiCoO_2-700$, since the better crystallization of the former crystallized better. However, $LiCoO_2$ synthesized at pH 4 displayed an abnormal higher intensity ratio of I(003)/I(104) than those synthesized at pH 7 and 9. The surface morphology of the $LiCoO_2-850$ powders was rougher and more irregular than that of $LiCoO_2-700$ made from the precursor synthesized at pH 7 and 9. The $LiCoO_2electrodes$ prepared with the precursors synthesized at pH 7 and 9 showed a better electrochemical and charge/discharge characteristics. From the AC impedance spectroscopic experiments for the electrode made from the precursor prepared in pH 7, the chemical diffusivity of Li ions (DLi+) in $Li0.58CoO_2determined$ was 2.7 ${\times}$10-8 $cm^2s-1$. A cell composed of the $LiCoO_2-700$ cathode prepared in pH 7 with Lithium metal anode reveals an initial discharge specific capacity of 119.8 mAhg-1 at a current density of 10.0 mAg-1 between 3.5 V and 4.3 V. The full-cell composed with $LiCoO_2-700$ cathode prepared in pH 7 and the Mesocarbon Pitch-based Carbon Fiber (MPCF) anode separated by a Cellgard 2400 membrane showed a good cycleability. In addition, it was operated over 100 charge/discharge cycles and displayed an average reversible capacity of nearly 130 mAhg-1.

Characteristics of a CFRP Cruiser's Windage Area by Stability Assessment (탄소섬유강화복합재료(CFRP) 레저선박의 횡요저항력 평가에 의한 상부구조물 풍압면적 특성)

  • Kim, Do-Yun;Lee, Chang-Woo;Lee, Dong-Kun;Oh, Dae-Kyun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.20 no.6
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    • pp.774-780
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    • 2014
  • This research aims to investigate the superstructure characteristics of the CFRP-yachts whose hulls are made of the light-weight material CFRP. CFRP-yachts, which belong to light-weight yachts, have a tendency of having very small superstructures compared to other vessels of the same length, and such a tendency is closely related to stability. In this research, a comparison of shape characteristics was made between common composite-plastic yachts and CFRP-yachts to find out the shape characteristics of CFRP-yacht. In the meantime, a case study was conducted concerning shape changes in superstructure to understand the effect of such changes on stability. For this purpose the shapes of a total of 10 GFRP-yachts and CFRP-yachts were comparatively analyzed, and the result showed the tendency of their hulls and superstructures. Whereas the case study on stability assessment involved various superstructure shapes of CFRP yachts, for assessment by superstructure size. Stability assessment was according to ISO 12217 (Small craft Stability and buoyancy assessment and categorization). A program was also developed based on stability assessment process due to rolling in beam waves and wind, and it was applied to the case study. The result of the case study showed that the windage area distribution tendency of the yachts whose hulls were made of the light-weight material CFRP was similar to that of the GFRP-yachts, but that the superstructure shapes of the CFRP-yachts were about 50% smaller than those of the GFRP-yachts. In addition, the stability assessment involving various superstructure areas of the CFRP-yachts showed that problems with stability occurred when their superstructure sizes were similar to, or larger by about 10% than, those of the GFRP-yachts.

Convergence Study on Damage and Static Fracture Characteristic of the Bonded CFRP structure with Laminate angle (적층 각도를 가진 CFRP 접착 구조물의 파손 및 정적 파괴 특성에 관한 융합 연구)

  • Lee, Jung-Ho;Kim, Eundo;Cho, Jae-Ung
    • Journal of the Korea Convergence Society
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    • v.10 no.1
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    • pp.155-161
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    • 2019
  • As composite is the light weight material whose durability and mechanical property are more superior than the existing general material. By taking notice of the composite with light weight, this study was about to investigate the static fracture characteristic of the bonded CFRP structure jointed with adhesive. Also, CFRP double cantilever beam with the variable of laminate angle was designed and the static fracture analysis was carried out. The laminate angles of CFRP double cantilever beam designed for this study were $30^{\circ}$, $45^{\circ}$ and $60^{\circ}$ individually. As the study result, the specimen with the laminate angle of $45^{\circ}$ was shown to have the durability better than those with the layer angles of $30^{\circ}$ and $45^{\circ}$. It was checked that the specimen with the laminate angle of $30^{\circ}$ had the weakest durability among all specimens. The damage data of the bonded CFRP structure by laminate angle could be secured through this study result. As the damage data of bonded interface obtained on the basis of this study result are utilized, the esthetic sense can be shown by being grafted onto the machine or structure at real life.

Convergence Study on Damage of the Bonded Part at TDCB Structure with the Laminate Angle Manufactured with CFRP (CFRP로 제작된 적층각도를 가진 TDCB 구조물에서의 접착부의 파손에 관한 융합 연구)

  • Lee, Dong-Hoon;Cho, Jae-Ung
    • Journal of the Korea Convergence Society
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    • v.9 no.12
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    • pp.175-180
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    • 2018
  • In this study, CFRP was manufactured with the laminate angle of $45^{\circ}$. The specimen of TDCB bonded with the adhesive for structure was designed by CATIA and the analysis was progressed by using the finite element analysis program of ANSYS. This study model was designed on the basis of British industry and ISO standard and the configuration factor(m) was established with variable according to the angle of model configuration. As the study result of this paper, the maximum deformations at the specimens with the tapered angles of $4^{\circ}$ and $8^{\circ}$ become most as 12.628 mm and least as 12.352mm respectively. Also, the maximum equivalent stresses at the specimens with the tapered angles of $6^{\circ}$ and $8^{\circ}$ become most as 9210.3 MPa and least as 4800.5 MPa respectively. The damage data of TDCB structure with the laminate angle which was manufactured with CFRP could be secured through this study result. As the damage data of TDCB structure bonded with CFRP obtained on the basis of this study result are utilized, the esthetic sense can be shown by being grafted onto the machine or structure at real life.

Flexural Strengthening Effects of RC Beam Reinforced with Pre-stressing Plate (긴장을 가한 보강 플레이트로 보강된 RC 보의 휨보강 효과)

  • Ha, Sang-Su
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.1
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    • pp.171-178
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    • 2019
  • Fiber-reinforced polymer (FRP) composites have proved to be reliable as strengthening materials. Most of existing studies used single types of FRP composites. Therefore, in this experimental study, carbon FRP sheet, aramid FRP sheet, and hybrid FRP plate including glass fibers were fabricated, and the effect of pre-stressed FRP composites on flexural strengthening of reinforced concrete (RC) beams was investigated. In total, eight RC beam specimens were fabricated, including one control beam (specimen N) without FRP composites and seven FRP-strengthened beams. The main parameters were type of FRP composite, the number of anchors used for pre-stressing, and thickness of FRP plates. As a result, the beam strengthened with pre-stressed FRP plate showed superior performance to the non-strengthened one in terms of initial strength, strength and stiffness at yielding, and ultimate strength. As the number of anchors and thickness of FRP plate (i.e., amount of FRP plates) increased, the strengthening effect increased as well. When hybrid FRP plates were pre-stressed, the strengthening effect was higher in comparison with pre-stressed single type FRP plate.

A Study on Design of Wind Blade with Rated Capacity of 50kW (50kW 풍력블레이드 설계에 관한 연구)

  • Kim, Sang-Man;Moon, Chae-Joo;Jung, Gweon-Sung
    • The Journal of the Korea institute of electronic communication sciences
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    • v.16 no.3
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    • pp.485-492
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    • 2021
  • The wind turbines with a rated capacity of 50kW or less are generally considered as small class. Small wind turbines are an attractive alternative for off-grid power system and electric home appliances, both as stand-alone application and in combination with other energy technologies such as energy storage system, photovoltaic, small hydro or diesel engines. The research objective is to develop the 50kW scale wind turbine blades in ways that resemble as closely as possible with the construction and methods of utility scale turbine blade manufacturing. The mold process based on wooden form is employed to create a hollow, multi-piece, lightweight design using carbon fiber and fiberglass with an epoxy based resin. A hand layup prototyping method is developed using high density foam molds that allows short cycle time between design iterations of aerodynamic platforms. A production process of five blades is manufactured and key components of the blade are tested by IEC 61400-23 to verify the appropriateness of the design. Also, wind system with developed blades is tested by IEC 61400-12 to verify the performance characteristics. The results of blade and turbine system test showed the available design conditions for commercial operation.

FEA for RC Beams Partially Flexural Reinforced with CFRP Sheets (CFRP 시트로 부분 휨 보강된 철근콘크리트 보의 유한요소해석)

  • Kim, Kun-Soo;Park, Ki-Tae;Kim, Byeong Cheol;Kim, Jaehwan;Jung, Kyu-San
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.5
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    • pp.9-16
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    • 2020
  • A CFRP sheet has been applied as a structural reinforcement in the field, and various studies are conducted to evaluate the effect of CFRP sheets on reinforced concrete. Although many experiments were performed from previous studies, there are still limitations to analyze structural behaviors with various parameters in experiments directly. This study shows the FEA on structural behaviors of RC beams reinforced with CFRP sheets using ABAQUS software. To simulate debonding failure of CFRP sheets which is a major failure mode of RC beam with CFRP sheets, a cohesive element was applied between the bottom surface of RC beam and CFRP sheets. Both quasi-static method and 2-D symmetric FE model technique were performed to solve nonlinear problems. Results obtained from the FE models show good agreements with experimental results. It was found that reinforcement level of CFRP sheets is closely related to structural behavior of reinforced concrete including maximum strength, initial stiffness and deflection at failure. Also, as over-reinforcement of CFRP sheets could give rise to the brittle failure of RCstructure using CFRP sheets, an appropriate measure should be required when installing CFRP sheets in the structure.

Mechanical Characteristics of 3-dimensional Woven Composite Stiffened Panel (3차원으로 직조된 복합재 보강 패널의 기계적 특성 연구)

  • Jeong, Jae-Hyeong;Hong, So-Mang;Byun, Joon-Hyung;Nam, Young-Woo;Kweon, Jin-Hwe
    • Composites Research
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    • v.35 no.4
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    • pp.269-276
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    • 2022
  • In this paper, a composite stiffened panel was fabricated using a three-dimensional weaving method that can reduce the risk of delamination, and mechanical properties such as buckling load and natural frequency were investigated. The preform of the stringer and skin of the stiffened panel were fabricated in one piece using T800 grade carbon fiber and then, resin (EP2400) was injected into the preform. The compression test and natural frequency measurement were performed for the stiffened panel, and the results were compared with the finite element analyses. In order to compare the performance of 3D weaving structures, the stiffened panels with the same configuration were fabricated using UD and 2D plain weave (fabric) prepregs. Compared to the tested buckling load of the 3D woven panel, the buckling loads of the stiffened panels of UD prepreg and 2D plain weave exhibited +20% and -3% differences, respectively. From this study, it was confirmed that the buckling load of the stiffened panel manufactured by 3D weaving method was lower than that of the UD prepreg panel, but showed a slightly higher value than that of the 2D plain weave panel.

Flexural Reinforcement of Timber Beams Using Carbon Fiber Plates (탄소섬유판을 사용한 목재 보의 휨보강)

  • Choi, Jin-Chul;Kim, Seung-Hun;Lee, Yong-Taeg
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.238-246
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    • 2022
  • This paper summarizes the development and evaluation of the reinforcement details of CFRP plates to improve the bending performance of wooden beams. In this study, the reinforcing technology using high-strength bolts for the end of beam were developed as reinforcement details for reinforcing wooden beams with CFRP plates by EBM method. In order to evaluate the bending performance, a bending test was conducted for the specimens with details of reinforcement such as the EBM method and the NSM method. From the experimental results, the EBM specimens without end restraints had both the CFRP plate attachment failure and the splitting failure of the wood. In the load-displacement curve, the non-reinforced specimens exhibited linear elastic behavior and then brittle fracture after the maximum load. The maximum load of the specimens reinforced by the EBM method increased by 31.5~63.0% compared to the non-reinforced specimens, and the maximum load according to the end restraints of the high-strength bolts increased by 24.0%. Based on the reinforcement amount of the same CFRP plate, EBM reinforcement was 2.67 times larger in maximum load increase rate than NSM reinforcement.

The Growth and Properties of Green Sprouts in Soil Culture (지면재배를 이용한 푸른콩나물의 생육 및 성분특성)

  • Chang, Kwang Jin;Lee, Jang Ho;Kim, Yong Tae;Ahn, Chung Woong
    • Journal of Practical Agriculture & Fisheries Research
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    • v.6 no.1
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    • pp.63-72
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    • 2004
  • This study was conducted to determine the growth and properties of green soybean sprouts(Vigna umbellata Thunb.) in soil culture. Patkong which is a small grain variety was sawn on electric heated hot bed in the greenhouse. Temperature of the culture bed were respectively 17, 20, 25, and 30℃ and water temperature were respectively 14, 17, 20 and 25℃. The kinds of soil used for this study were upland soil, sand, peatmoss and Pearlite, loess, loess and activated carbon. BA was treated in the concentrations of 240 times, 80 times, 40 times besides control. High temperature of 25 and 30℃ increased sprout yield compared to lower temperature but caused to decay from 7 days after sawing. Thus, the most optimum temperature for soil culture was 20℃. The best soil was sand of which increased fresh weight of 850g during same period. Addition of BA was most effective to promote sprout growth in the concentration of 80 times. Compared to general soybean sprouts, green soybean sprouts were 50% higher in fiber but 72% lower in glucide. Vitamin B was 200% higher in green soybean sprouts but vitamin C was higher in general soybean sprouts.