• Title/Summary/Keyword: Carbon-coated

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Effect of Diffusion on the Interfacial Adhesion of Poly(hydroxy ether) Coated Caron Fibers (계면확산에 의한 Poly(hydroxy ether) 코팅된 탄소섬유의 계면접착력 변화 연구)

  • 강현민;윤태호
    • Composites Research
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    • v.12 no.6
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    • pp.15-21
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    • 1999
  • Carbon fibers were coated with carboxy modified poly(hydroxy ether)(C-PHE, water dispersed), water soluble polymers poly(hydroxy ether ethanol amine)(PHEA) or water insoluble poly(hydroxy ether)(PHE). Interfacial shear strength of polymer coated carbon fibers was measured by micro-droplet tests with vinyl ester resin, and approximately 30 samples were tested. The interfacial adhesion of poly-mers to carbon fibers was also evaluated, and diffusion behavior of polymer films in vinyl ester resin was investigated. The carbon fibers after testing and diffusion samples were analysed by SEM in order to understand adhesion mechanism. Interfacial shear strength of carbon fibers was enhanced by the coating of PHE and C-PHE which have good or marginal solubility in vinyl ester resin, respectively, but not by the coating of PHEA possibly due to the poor solubility in vinyl ester resin.

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Improvement in Cycle Characteristics using PVP Based Direct Carbon Coating During High-Rate Charge and Discharge of Li[Ni0.93Co0.07]O2 Nanofibers: Application for Lithium Secondary Batteries

  • Hae In Kim;Hyun Ju Jang;Thuy Thi Bich Tran;Jong-Tae Son;Eui Jeong Park
    • Journal of Electrochemical Science and Technology
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    • v.14 no.2
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    • pp.139-144
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    • 2023
  • In this study, carbon-coated porous nanofibers were prepared via electrospinning and the performance of Li[Ni0.93Co0.07]O2 (NC) synthesized by electrospinning (E-NC) and co-precipitation (C-NC) was compared. E-NC had a discharge capacity of 206 mAh g-1 at 0.1C (17 mA/g), which is 10% higher than that of C-NC (189.2 mAh g-1). E-NC shows a high-rate performance of 118.32 mAh g-1 (61.7%) at 5C (850 mA/g), which is 50% higher than that of C-NC (78.22 mAh g-1 = 45.7%). Charge transfer of the carbon-coated porous nanofiber E-NC decreased by 35% compared to C-NC after 20 cycles as observed using electrochemical impedance spectroscopy. The results of this study show that the nanofiber structure with carbon coating shortens the Li-ion diffusion path, improves electrical conductivity, resulting in excellent rate performance.

Synthesis of Multi-walled Carbon Nanotubes and Nanofibers on a Catalytic Metal Substrate Using an Ethylene Inverse Diffusion Flame as a Heat Source (에틸렌 역확산화염을 열원으로 사용하여 촉매금속 기판 상에 합성한 탄소나노튜브와 탄소나노섬유)

  • Lee, Gyo-Woo;Jurng, Jong-Soo;Kang, Kyung-Tae;Hwang, Jung-Ho
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1304-1309
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    • 2004
  • Synthesis of carbon nanotubes and nanofibers on a catalytic metal substrate, using an ethylene fueled inverse diffusion flame, was investigated. Multi-walled carbon nanotubes, with diameters of 20 - 60nm, were formed on the substrate coated with nickel-nitrate in the region of 5 - 6mm from the flame center along the radial direction. The gas temperature for this region was ranging from about 1400 to 900K. Nickel particles originated from the coated nickel-nitrate on the substrate were the major catalyst for the formation of the nanomaterials. HR-TEM and Raman spectrum revealed that synthesized carbon nanotubes had multi-walled structures with some defective graphite layers at walls.

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Carbon nanotube-coated $ZnGa_2O_4:Mn^{2+}$ phosphor for field emission display

  • Park, Je-Hong;Park, Boo-Won;Choi, Nam-Sik;Kim, Jong-Su
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1543-1544
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    • 2007
  • Carbon nanotubes (CNTs) are coated on green $ZnGa_2O_4:Mn^{2+}$ phosphor for filed emission display. The cathodoluminescent intensity of CNTs-phosphor is improved compared with uncoated phosphors. Also the effects of phosphors-coated CNTs on electrical and degradation characteristics are investigated to reveal the reason of the enhanced emission intensity.

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Field Emission Characteristic of Titanium-Coated Carbon Nanotube (티타늄이 코팅된 탄소나노튜브의 전계방출특성)

  • Lee, Seung-Yeon;Uh, Hyung-Soo;Park, Sang-Sik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.149-149
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    • 2010
  • The effect of titanium (Ti) coating over the surface of carbon nanotubes (CNTs) on field emission characteristics was investigated. Since the work function of CNTs emitter is about 5.0 eV, field emission would be observed at lower voltage if this work function gets lower. Work function of Ti is approximately 4.09eV. Field emission characteristics of as-grown and Ti-coated CNTs were measured in a diode-type configuration. The resultant emission characteristics revealed that thin($50{\AA}$-thick) Ti-coated CNTs could be a better electron emitter with lower emission voltage and higher emission efficiency.

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New Functional Conductive Polymer Composites Containing Nickel Coated Carbon Black Reinforced Phenolic Resin

  • Farid El-Tantawy;Nadia Abdel Aal;Yong Kiel Sung
    • Macromolecular Research
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    • v.13 no.3
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    • pp.194-205
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    • 2005
  • The network structure of Ni-coated carbon black (NCB) composites filled with phenolic resin was investigated by means of using scanning electron microscopy, viscosity, interfacial tension, shrinkability, Flory-Huggins interaction parameters, and swelling index. The electrical properties of the composites have been characterized by measurement of the specific conductivity as a function of temperature. Additionally, the variation of conductivity with temperature for the composites has been reported and analyzed in terms of the dilution volume fraction, relative volume expansion, and barrier heights energy. The thermal stability of phenolic-NCB composites has been also studied by means of the voltage cycle processes. The experimental data of EMI wave shielding were analyzed and compared with theoretical calculations. The mechanical properties such as tensile strength, tensile modulus, hardness and elongation at break (EB) of NCB-phenolic resin composites were also investigated.

Spray-coated single-wall carbon nanotube film strain sensor (스프레이코팅 방식으로 제작된 단일벽 탄소나노튜브막 스트레인센서)

  • Park, Chan-Won
    • Journal of Industrial Technology
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    • v.32 no.A
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    • pp.29-33
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    • 2012
  • We demonstrated the viability of fully microfabricating SWCNT(single-wall carbon nanotube) film strain sensors for force and weight sensing. Our spray-deposited SWCNT film strain sensors showed good linearity over a range from 0 to 400 microstrain, and much higher sensitivity compared to commercial metal foil-type gauges. The number of grids and the thickness of the SWCNT film were found to have a significant effect on the strain sensing properties of the SWCNT film gauges. A strain sensing methode for the CNT-based strain gauges was also investigated using a binocular type beam load cells. Preliminary results indicate that the microfabrication method shown here is promising for developing a commercial strain gauge using a spray-coated SWCNT thin film. In the near future, various studies will be performed to further enhance the properties of the spray-coated SWCNT film strain sensors.

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Enhanced Dispersion of Multi-Walled Carbon Nanotubes by Polydimethylsiloxane Coating and Its Application

  • Yoon, Hye Soo;Jeong, Myung-Geun;Kim, Kwang-Dae;Kim, Dae Han;Park, Eun Ji;Kim, Young Dok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.279-279
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    • 2013
  • We report on the preparation of polydimethylsiloxane (PDMS) coated multi-walled carbon nanotubes (MWNTs) followed by their dispersion in various solvents. To disperse MWNTs without acids of surfactants, which are the commonly used methods, hydrophobic PDMS coating was selected. It was determined that the PDMS coated MWNTs are more dispersed in diverse solvents such as dimethyl formamide (DMF) and acetone than bare MWNTs. In case of DMF solvent, dispersion of MWNT was improved by 40 % upon PDMS-coating of MWNT, which was confirmed by UV/Vis absorption spectroscopy. In this work, the PDMS coated MWNTs dispersed solution was also used for the fabrication of film, which is conductive, transparent and superhydrophobic because of the reduced aggregation and increased water repellency of MWNTs.

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Preparation of Electrode Coated with Activated Carbon for Dust Removal (분진제거를 위한 활성탄 전극판의 제조)

  • Kim, Kwang Soo;Park, Jung O;Jun, Tae Hwan;Kim, Ilho
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.11
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    • pp.815-820
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    • 2013
  • The purpose of this research is to prepare the aluminum electrode coated with activated carbon for removing air pollution dust. The experiments were studied on the selection of optimal polymer for binding aluminum plate with powdered activated carbon, preventing the pore blocking of activated carbon from polymer binder, and the dust treatability for the prepared activated carbon electrode. The optimal adhesive for coating activated carbon on an electric aluminum plate was polyvinyl acetate (PVA) with vinyl functional group. For the opening of the blocked pore with polymer, it was very effective to embed polymer solvent in pore of activated catbon firstly before mixing activated carbon with PVA, and then to devolatilize the embedded solvent of carbon pore at high temperature. The mass of trapped dust on aluminum electrode coated with activated carbon was about double of the trapped one on just aluminum electrode.

Erosion Behavior of SiC Coated C/C Composites with Condition of Combustion Test

  • Joo, Hyeok-Jong;Min, Kyung-Dae;Lee, Jae-Won
    • Carbon letters
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    • v.4 no.3
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    • pp.133-139
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    • 2003
  • Carbon/carbon composites are ideal candidates for a number of aerospace applications including structural materials for advanced vehicles, leading edges, structures of re-entry and hypersonic vehicles and propulsion systems. One serious defect for such application of the carbon/carbon composites is their poor oxidation resistance in high temperature oxidizing environments. SiC coating was employed to protect the composites from oxidation. It is mechanically and chemically stable under extreme thermal and oxidative environments, provides good adhesion to the substrate, and offers good thermal shock resistance. The SiC layer on the nozzle machined from the carbon/carbon composites was formed by pack-cementation method. Then, erosion characteristic of SiC coated carbon/carbon nozzle was examined by combustion test using a liquid rocket motor. The erosion rates were measured as function of combustion pressure, ratio of oxygen to fuel, combustion time, density of the composites and geometry of reinforced carbon fibre in the composites. The morphology change of the composites after combustion test was investigated using SEM and erosion mechanism also was discussed.

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