• Clean Technology
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• v.2 no.1
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• pp.60-68
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• 1996

The oxidation of carbon monoxide of low concentration on the natural manganese dioxide (NMD) has been investigated in a fixed bed reactor. The experimental variables were concentration of oxygen (500ppm~99.8%) and carbon monoxide (500ppm~10000ppm) and catalyst temperature ($50{\sim}750^{\circ}C$). The NMD(Natural Manganese Dioxide) has been characterized by temperature - program reduction(TPR) using 2.4% $CO/H_2$ as a reducing agent, thermogravimetric analysis (TGA), and reduction of NMD by 2.4% $CO/H_2$. It was found that the NMD catalyst activity on the unit area was greater than the $MnO_2$ catalyst for oxidation of CO at the same temperature. The thermal stability of oxidation activity was considered to be maintained when the NMD was heated to $750^{\circ}C$. The TGA, reduction by CO, and TPR of the NMD showed that the NMD had active lattice oxygen which was easily liberated on heating in the absence and low concentration of oxygen. The reaction order in CO is 0.701 between 500~3500ppm and almost zero between 3500~10000ppm of CO.

• Asian Journal of Atmospheric Environment
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• v.4 no.1
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• pp.26-32
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• 2010

Concentrations of carbon monoxide (CO) in air were analyzed from seven urban roadside (U-RS) stations in Seoul, Korea over an 11-year period (1998-2008). As noticeable changes in CO levels coincided with the Natural Gas Vehicle Supply (NGVS) program in the year 2000, its concentration data were examined between 1998-2000 (period I) and 2001-2008 (period II). The mean values of CO from all 7 stations for the whole study period were recorded as $1.19{\pm}0.22$ ppm with large drops in its mean from $1.83{\pm}0.43$ ppm in period I to $0.94{\pm}0.21$ ppm in period II. As such, CO levels between the two periods undertook the mean reduction rate of $46.9{\pm}16.2%$ (range of 18.3 to 59.9%). According to the analysis of longterm trends of CO, its concentrations in the U-RS stations decreased very rapidly with the annual mean reduction rate of 9.5% $yr^{-1}$. A line of evidence collected in this study suggests that the implementation of the NGVS program has been quite effective to induce the alterations in CO levels in all urban roadside locations throughout the city of Seoul.

• Journal of Applied Biological Chemistry
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• v.51 no.6
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• pp.253-261
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• 2008

Isoflavone daidzein is a phytoestrogen widely distributed in Leguminosae and is especially rich in the soybean. The C6-C3 (rings B and C) unit of isoflavones is derived from the phenylpropanoid pathway and the remaining C6 (ring A) unit is from the polyketide pathway. This unique carbon skeleton is the result of isomerization of the flavone catalyzed by the isoflavone synthase, a cytochrome P450 enzyme. The isoflavones daidzein and genistein are present in the plant mostly in the glucosylated forms. However, in the human intestine, the glycosidic linkage is broken, and the free form is uptaked into blood stream. The free form is further metabolized into various reduction products to end up at the equol, which is known to have the most potent estrogenic effect among the metabolites. Several human intestinal bacteria that can convert daidzein into equol have been described, and the study into the chemistry and biochemistry of the daizein reduction would be rewarding to the improvement of the human health.

• Journal of the Korean Society of Earth Science Education
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• v.3 no.3
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• pp.228-238
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• 2010

The purpose of this study is to examine the effects which applies teaching program that search solution to prevent global warming in middle school gifted class. This program of total 10 class was theoretical and experimental class and the students presented after collecting the synthetic data about climate-change and roleplayed what they debated to firm their country's opinion about Kyoto Protocol. Finally, students as policymaker made mock Kyoto Protocol by discussion. Impression papers and images about climate-changes was made by students in last class. In discussion of making up mock Kyoto Protocol, developed and developing nations had an argument about carbon dioxide emissions because of their economic benefits. In the course of allocating mutual $CO_2$ reduction, they needed yield and negotiation among nations. Although they mainly took passive position about $CO_2$ reduction, atmosphere that all the country make greater effort for the future global environment was formed. Like this, students had more concepts over climate change by making mock Kyoto Protocol. And they could equipped global scientific literacy and responsibility by participating in social decision making process of solving global environmental issues.

• Journal of Electrochemical Science and Technology
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• v.4 no.2
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• pp.71-80
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• 2013

The study of methyl viologen ($MV^{2+}$) mediated oxygen reduction in electrolytic ethanol media possesses potential application in the electrochemical synthesis of hydrogen peroxide mainly due to the advantages of the much increased solubility of molecular oxygen ($O_2$) and high degree of reversibility of $MV^{2+/{\bullet}+}$ redox couple. The diffusion coefficients of both $MV^{2+}$ and $O_2$ were investigated via electrochemical techniques. For the first time, $MV^{2+}$ mediated $O_2$ reduction in electrolytic ethanol solution has been proved to be feasible on both boron-doped diamond and micro-carbon disc electrodes. The electrocatalytic response is demonstrated to be due to the radical cation, $MV^{{\bullet}+}$. The homogeneous electron transfer step is suggested to be the rate determining step with a rate constant of $(1{\pm}0.1){\times}10^5M^{-1}s^{-1}$. With the aid of a simulation program describing the EC' mechanism, by increasing the concentration ratio of $MV^{2+}$ to $O_2$ electrochemical catalysis can be switched from a partial to a 'total catalysis' regime.

• KIEAE Journal
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• v.14 no.1
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• pp.101-111
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• 2014

The Product Carbon Footprint Labeling has been run for more than four years by the Ministry of Environment and there are number of products labeled by KEITI(Korea Environmental Industry & Technology Institute), as for declaring products with their carbon emission during life cycle stages. There are several categories for certifying products by the characteristics of usage. Building products which are applied to a building as combined components or elements, are classified as production goods which means that the products are chosen by a business, not by a final consumer. In this paper, current status of PCF labeling has been reviewed focused on building products and the characteristics of carbon emission by a kind of product such as interior products, window products, structural products, system products and others. Until Dec. 2013, 82 products has been labeled and it covers about 53% among labeled product goods by the certification. Among the labeled building products, interior products are main products. From the results of comparison, variations of emission amounts by products have been found and the cause of variation could be explained by the purpose and material properties of products. However, the exact reason for variations cannot be acquired because of lack of information and the short operation period of the certification program. Further studies and more products are needed to be studied and analyzed focused on the emission characteristic by each product and to suggest reduction technologies for sustainable building products.

• Journal of the Korea Institute of Military Science and Technology
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• v.9 no.3
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• pp.88-94
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• 2006

In order to substitute current aluminum sabot and to increase the penetration performance of the kinetic energy projectiles, the research and development program for composites sabot has been conducted. For carbon/epoxy composites sabot, unidirectional carbon fiber reinforced epoxy prepreg was chosen and thick sectioned composites preforms with the different fiber angles along the circumferential direction of sabot were prepared by compression molding under the careful processing conditions at $150^{\circ}C$ for 1hour with $70kgf/cm^2$ curing pressure. The composites sabot demonstrated a weight reduction by approximately 30% than that of current aluminum sabot. The muzzle velocity of a kinetic energy projectile with composites sabot was measured to be about 63m/s higher than that with aluminum sabot. These results imply that the penetration performance is expected to be considerably increased when the composite sabot is applied to the kinetic energy projectiles.

• Clean Technology
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• v.30 no.2
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• pp.94-104
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• 2024

Remanufacturing re-commercializes a used product to achieve an equal or higher performance level than the original product by disassembling, cleaning, inspecting, repairing, reconditioning, and reassembling the used product. The remanufacturing industry is a key industry necessary to realize carbon neutrality by 2050. This study uses life cycle assessment to analyze the resource reduction and greenhouse gas reduction effects with and without considering the avoided effect for an injector, which is an automobile part that is actively being remanufactured. The results of this study showed that the resource reduction effect and greenhouse gas reduction effect induced by injector remanufacturing were reduced by 95.30% and 93.88%, respectively, based on one unit without considering the avoided effect. However, when considering the avoided effect, which in this case is the environmental impact of not disposing of the used injector and not having to use natural resources to manufacture a new injector because the used injector was reused during remanufacturing, the resource reduction effect and greenhouse gas reduction effect were 190.91% and 188.33%, respectively. The results of this study are expected to be used in the future to evaluate the amount of environmental impact reduction while considering the avoided effect during remanufacturing and to help develop research methodology for remanufacturing.

• Journal of Korean Society of Forest Science
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• v.110 no.3
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• pp.440-452
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• 2021

This study identified and evaluated conditions for continued participation of private forest owners in forest carbon offset programs. The probability of continuing forest carbon offset projects, which delays greenhouse gas emissions by extending harvesting periods, increases with increasing price of carbon offset credits, public recognition of forest value, and education level. Willingness to Accept (WTA) was estimated using a Multiple Bounded Dichotomous Choice Question, which was 17,039 KRW/tCO₂ for extending age to 60 years, and 23,070 KRW/tCO₂ for 100 years. The following findings aim to promote participation and supply of carbon offset programs in private forests according to the study outcomes. First, introducing policies supporting private forest owners bearing opportunity costs for avoiding greenhouse gas emissions by postponing timber harvest is needed. Second, educational programs for private forest owners whose awareness of and interests in the public value of forest is necessary. Third, although having participated from the beginning of the offset program, finding ways to lead continuous participation of forest owners who are less likely to accept WTA is also necessary.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.20 no.4
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• pp.29-42
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• 2017

As the "Guidelines for GHG Environmental Assessment" was revised, it pointed out that the developers should evaluate GHG sequestration and storage of the developing site. However, the current guidelines only taking into account the quantitative reduction lost within the development site, and did not consider the qualitative decrease in the carbon sequestration capacity of forest edge produced by developments. In order to assess the quantitative and qualitative effects of vegetation carbon uptake, the CASA-NPP model and satellite image spatial-temporal fusion were used to estimate the annual net primary production in 2005 and 2015. The development projects between 2006 and 2014 were examined for evaluate quantitative changes in development site and qualitative changes in surroundings by development types. The RMSE value of the satellite image fusion results is less than 0.1 and approaches 0, and the correlation coefficient is more than 0.6, which shows relatively high prediction accuracy. The NPP estimation results range from 0 to $1335.53g\;C/m^2$ year before development and from 0 to $1333.77g\;C/m^2$ year after development. As a result of analyzing NPP reduction amount within the development area by type of forest development, the difference is not significant by type of development but it shows the lowest change in the sports facilities development. It was also found that the vegetation was most affected by the edge vegetation of industrial development. This suggests that the industrial development causes additional development in the surrounding area and indirectly influences the carbon sequestration function of edge vegetaion due to the increase of the edge and influx of disturbed species. The NPP calculation method and results presented in this study can be applied to quantitative and qualitative impact assessment of before and after development, and it can be applied to policies related to greenhouse gas in environmental impact assessment.