• 제목/요약/키워드: Carbon paste

검색결과 294건 처리시간 0.029초

Voltammetric Determination of Cobalt(Ⅱ) Using Carbon Paste Electrodes Modified with 1-(2-Pyridylazo)-2-naphthol

  • 배준웅;박유철;이상학;전우성;장혜영
    • Bulletin of the Korean Chemical Society
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    • 제17권11호
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    • pp.995-999
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    • 1996
  • A method for the determination of cobalt(Ⅱ) by differential pulse voltammetry using a carbon paste electrode constructed by incorporating 1-(2-pyridylazo)-2-naphthol(PAN) into a conventional carbon paste mixture composed of graphite powder and Nujol oil has been developed. Several influencing factors for the determination of cobalt(Ⅱ) were studied in detail and the optimum analytical conditions were found to be as follows: pH, 4.6; composition of electrode, 20%; temperature of deposition, 43 ℃; time of preconcentration, 15 min. Regeneration of the electrode surface for the continuous uses of the electrode was achieved by exposing the carbon paste electrode to an acidic solution. Response of the electrode was reproducible for the uses of five times and the relative standard deviations were 6.7 and 4.6% for 2.0×10-5 M and 4.0×10-6 M cobalt(Ⅱ), respectively. The calibration curve for cobalt(Ⅱ) obtained by differential pulse voltammetry was divided into two linear ranges of 1.7× 10-6-1.3×10-4 M and 2.0×10-7-8.0×10-7 M. The detection limit was estimated to be 1.3×10-7 M. The effects of coexisting ions were also investigated to test the applicability of the proposed method to the determination of cobalt(Ⅱ) in real samples.

금속 산화물을 포함한 탄소반죽 전극 어레이로 제작한 전자 혀 (Amperometric Electronic Tongue Based on Metal Oxide Containing Carbon Paste Electrode Array)

  • 한종호;김동선;김종식;윤인준;차근식;남학현
    • 전기화학회지
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    • 제7권4호
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    • pp.206-210
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    • 2004
  • 금속산화물 $(TiO_2,\;RuO_2,\;PbO_2,\;Ni(OH)_2)$과 Prussian blue (PB)를 각각 탄소반죽에 혼합한 후 스크린 프린팅 기법으로 6종의 탄소반죽 전극들을 제작하였다. 제작된 탄소반죽 전극들로 전자혀 시스템을 제작하여 다양한 음료수와 식품에 대한 감응을 0.1M carbonate buffer, pH 9.6완충 용액에 묽힌 후 대시간전류법의 방법으로 측정하였다 얻어진 자료를 주성분 분석법 (principal component analysis; PCA)으로 처리한 후 식음료의 맛을 평가할 수 있도록 2차원 좌표계에 표시하였으며, 그 결과 본 실험에서 제작한 시스템 및 분석법은 다양한 식음료의 종류를 뚜렷이 구분해 낼 수 있음을 확인하였다.

Formulation of Carbon Nanotube Paste and Its Optimization for Field Emission Display Applications

  • Kim, Yong-C.;Sohn, K.H.;Cho, Y.M.;Yoo, Eun-H.;Lee, Dong-Gu
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.696-699
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    • 2004
  • Of the emissive display technologies, field emission displays using pasted carbon nanotubes offer several advantages over other competing cathode materials such as low driving voltage, possible large-area and low-cost processes. In this study, formulation of carbon nanotube paste and its electron field emission properties are characterized. Also the effects of additive powders and surface morphology on electron emission are reported.

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Mechanical and electrical properties of cement paste incorporated with pitch-based carbon fiber

  • Rhee, Inkyu;Kim, Jin Hee;Park, Sang Hee;Lee, Sungho;Ryu, Bong Ryeul;Kim, Yoong Ahm
    • Carbon letters
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    • 제23권
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    • pp.22-29
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    • 2017
  • The compressive strength and electrical resistance of pitch-based carbon fiber (CF) in cementitious materials are explored to determine the feasibility of its use as a functional material in construction. The most widely used CFs are manufactured from polyacrylonitrile (PAN-based CF). Alternatively, short CFs are obtained in an economical way using pitch as a precursor in a melt-blown process (pitch-based CF), which is cheaper and more eco-friendly method because this pitch-based CF is basically recycled from petroleum residue. In the construction field, PAN-based CFs in the form of fabric are used for rehabilitation purposes to reinforce concrete slabs and piers because of their high mechanical properties. However, studies have revealed that construction materials with pitch-based CF are not popular. This study explores the compressive strength and electrical resistances of a cement paste prism using pitch-based CF.

FED용 CNT paste 제조 (Fabrication of CNT paste for FED)

  • 김태홍;김종성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.463-464
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    • 2006
  • 광산업 및 디스플레이 산업의 발전에 따라 관련 제품의 핵심 부품 및 소재 개발이 매우 중요하게 대두되고 있다. 전계방출 소자 및 back light가 되는 나노 발광체의 핵심소재중 하나인 CNT paste는 국내외에서 연구가 진행중이다. 본 연구에서는 메탄올속에서 초음파를 이용하여 분산시킨 CNT 분말, 유기 바인더, 용매, glass frit, Ag powder 등을 사용하여 paste를 만들고, TGA(Thermogravimetric Analyzer)와 SEM(Scanning Electron Microscopy) 분석에 의해 제조 공정의 최적화를 실시하였다.

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대 변형 감지용 스트레인게이지 개발 (Development of a Strain Gauge for Sensing Large Strain)

  • 이영태;조승우
    • 반도체디스플레이기술학회지
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    • 제13권4호
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    • pp.33-36
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    • 2014
  • In this paper, a carbon strain gauge for large strain was developed. The carbon strain gauge was fabricated by forming PCB and antenna pattern using Cu/Ni/Au film and carbon resistor pattern using screen printing process on plastic film substrate. It was possible to develop low-cost disposable strain gauge since the carbon paste was cheap and the fabrication process was simple. The wireless communication type carbon strain gauge was fabricated by integrating signal processing circuit, antenna and power all together on the same substrate as a strain gauge. The wireless communication type carbon strain gauge has a merit of being available immediately at the spot without any particular system.

Studies on Enhanced Oxidation of Estrone and Its Voltammetric Determination at Carbon Paste Electrode in the Presence of Cetyltrimethylammonium Bromide

  • Yang, Chunhai;Xie, Pingping
    • Bulletin of the Korean Chemical Society
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    • 제28권10호
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    • pp.1729-1734
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    • 2007
  • The electrochemical behaviors of estrone in the presence of various surfactants were examined with great details. It is found that a cationic surfactant, cetyltrimethylammonium bromide (CTAB), obviously facilitates the electro-oxidation of estrone at carbon paste electrode (CPE) from the significant peak current enhancement and the negative shift of peak potential. Additionally, chronocoulometry and electrochemical impedance spectroscopy (EIS) were also used for further investigation of the electrode process of estrone, indicating that low concentration of CTAB exhibits excellent enhancement effects on the electrochemical oxidation of estrone, greatly enhances the diffusion coefficient and the electron transfer rate. Based on this, an electrochemical method was proposed for the determination of estrone. The oxidation peak current is proportional to the concentration of estrone in the ranges over 9.0 × 10?8 - 8.0 × 10?6 mol/L, and a low detection limit of 4.0 × 10?8 mol/L was obtained for 180s accumulation at open circuit (S/N = 3). Finally, this proposed method was demonstrated using estrone tablets with good satisfaction.

스크린 프린팅 방법에 의해 게이트-에미터간 자체정렬된 3극 구조의 CNT FEA 제조 (Fabrication of CNT FEA Self-aligned between Gate and Emitter using Screen Printing Method)

  • 권상직
    • 한국전기전자재료학회논문지
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    • 제19권4호
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    • pp.367-372
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    • 2006
  • A carbon nanotube field emission display(CNT FED) panel with a 2 inch diagonal size was fabricated using a screen printing of a prepared photo-sensitive CNT paste and vacuum in-line sealing technology. After a surface treatment of the patterned CNT, only the carbon nanotube tips are uniformly exposed on the surface. The diameter of the exposed CNTs are usually about 20 nm. Using the photo-sensitive CNT paste, we have developed a triode type CNT FEA with a self-aligned gate-emitter structure. The turn on voltage was around 100 V which corresponds to according the turn on field of about $40V/{\mu}m$. By the creation of a self-aligned gate-emitter structure, it is expected that the screen printed photo-sensitive CNT paste is promising as a good candidate for the large size field emission display.

Green Synthesized Cobalt Nano Particles for using as a Good Candidate for Sensing Organic Compounds

  • Siada, S. O. Ranaei
    • Journal of Electrochemical Science and Technology
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    • 제6권4호
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    • pp.111-115
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    • 2015
  • In this work electrochemical oxidation of Ascorbic acid (AA) on the surface of Cobalt nano particle modified carbon paste electrode (CoNPsMCPE) was studied in alkaline media. CoNPs were green synthesized using Piper longum and a mixture of 5% (w/w) of it were made with carbon paste. CoNPs showed good electrocatalytic activity in alkaline media. Cyclic voltammetry (CV) and chronoamperometry (CA) were used to study the electrochemical performance of CoNPsMCPE. The number of monolayers on the surface of electrode was calculated as 1.08×109 mol cm−2 that is equal to that of metal Cobalt electrode. Diffusion coefficient of AA was determined using CA analysis which was equal to 1.5×10−6cm2 s−1.

Effect of electrical aging on emission stability of carbon nanotube paste

  • Park, J.H.;Moon, J.S.;Jeong, J.S.;Yoo, J.B.;Park, C.Y.;Moon, H.S.;Nam, J.W.;Kim, J.M.;Park, J.H.;Choe, D.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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    • pp.1466-1469
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    • 2005
  • We report effects of electrical aging on the emission stability of carbon nanotube (CNT) paste for low cost and high low-cost and large area field emission devices or displays. Photosensitive carbon nanotube paste was formulated by using of spin on glass (SOG) as an inorganic binder and investigated emission properties and stability depending on electrical aging condition.

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