• Title/Summary/Keyword: Carbon mass balance

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Estimation of Landfill Stabilization using Carbon-based Mass Balance Evaluation

  • Chun, Seung-Kyu
    • Journal of Soil and Groundwater Environment
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    • v.21 no.2
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    • pp.22-28
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    • 2016
  • In order to evaluate landfill stabilization based on organic carbon, stoichiometric analysis and a biological methane potential (BMP) test based on modeling were performed at the 2nd Sudokwon Landfill Site. Mass balance analysis through a BMP test proved to be more adaptable for evaluation, and it showed that 28.9% of landfill organic carbon was expected to remain by 2046, 30 years after landfill closure. The organic carbon ratio of total landfill waste for 2046 is forecasted as 2.9% in demolition waste and 5.1% in household waste, and, if one were to consider plastic as an organic waste, the ratios would increase to 15.9% and 28.3%, respectively. Therefore, it seems that organic matter biodegradation facilitating measures such as bioreactor landfill technology and preemptive recovery of combustible waste are necessary to shorten post closure management periods and to meet the landfill stabilization guidelines more safely.

A Study on Heat and Mass Balance in a Coal Gasifier (석탄 가스화기 열 및 물질정산에 관한 연구)

  • Kim, Bong-Keun;Yoo, Jeong-Seok;Kim, You-Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.424-428
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    • 2007
  • In the current most tool using heat and mass balance in a coal gasifier is dependent on commercial code such as STANJAN, CHEMKIN. However, in order to keep the self-reliance technology, it is necessary to develop the original design tool available for comprehension and analysis on the spot. So in this study, its own heat and mass balance program is developed on the assumption that the process in a coal gasifier is adiabatic and quasi-equilibrium. The mass balance is calculated by using the chemical equilibrium principle. Also the heat and mass balance according to main operating factors such as temperature, pressure and O2/Coal ratio, was carried in this tool. This heat and mass balance was verified on the basis of the results simulated in STANJAN, commercial codes using similar logic.

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Life Cycle Assessment for the Business Activities of Green Company -2. Mass Balance and Environmental Improvement (녹색기업의 사업활동 전 과정에 대한 환경성 평가 -2. 물질수지 및 환경개선)

  • Shin, Choon-Hwan;Park, Do-Hyun
    • Journal of Environmental Science International
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    • v.22 no.4
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    • pp.425-433
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    • 2013
  • A mass balance of process was calculated by using the analysis of basic unit and environmental assessment of all the processes of Busan fashion color industry cooperative that operates a combined heat and power plant and a bio treatment plant. The mass balance for the combined heat and power plant was done, based on boiler and water treatment processes while each unit reactor was used for the bio treatment plant. From the results above, a resource recycle network, a treatment flowchart for food waste water/wastewater treatment and a carbon reduction program were established.

The Responses of a Small Lake Watershed to an Inorganic Carbon Cycle (무기탄소 순환에 대한 소규모 호수 유역의 반응)

  • Cho, Youngil
    • Journal of Korean Society on Water Environment
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    • v.29 no.5
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    • pp.610-617
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    • 2013
  • Investigating the budgets of alkalinity and dissolved inorganic carbon (DIC) in lake water systems is significant for the examination of the behavior of a lake as a sink or a source with respect to the circulation of inorganic carbon chemistry. Budgets of total alkalinity ($Alk_T$) and DIC in Onondaga Lake, which was polluted by chronic calcium (Ca) loading in spite of the closure of soda ash ($Na_2CO_3$) facility, were determined by the analyses of inorganic carbon chemistry in tributary stream channels linked to the lake. AlkT and DIC fluxes of Onondaga Creek and Ninemile Creek occupied 65% and 54%, respectively, as larger tributary streams in comparison with other tributaries as well as different input sources. Budget calculations indicate that 18% of AlkT and 11% of DIC inputs to Onondaga Lake, respectively, remained immobilized in the Lake. This suggests that Ca chronically leached had been precipitated with inorganic carbon or remineralized by secondary mineral formation during the experimental period. In this study, the assumed mass balance calculation in Onondaga Lake with tributary streams resulted in exhibiting that the lake played a role of the sink for the inorganic carbon cycle.

Characterizing Spatiotemporal Variations and Mass Balance of CO2 in a Stratified Reservoir using CE-QUAL-W2 (CE-QUAL-W2를 이용한 성층 저수지에서 CO2의 시공간적 분포 및 물질수지 분석)

  • Park, Hyungseok;Chung, Sewoong
    • Journal of Korean Society on Water Environment
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    • v.36 no.6
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    • pp.508-520
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    • 2020
  • Dam reservoirs have been reported to contribute significantly to global carbon emissions, but unlike natural lakes, there is considerable uncertainty in calculating carbon emissions due to the complex of emission pathways. In particular, the method of calculating carbon dioxide (CO2) net atmospheric flux (NAF) based on a simple gas exchange theory from sporadic data has limitations in explaining the spatiotemporal variations in the CO2 flux in stratified reservoirs. This study was aimed to analyze the spatial and temporal CO2 distribution and mass balance in Daecheong Reservoir, located in the mid-latitude monsoon climate zone, by applying a two-dimensional hydrodynamic and water quality model (CE-QUAL-W2). Simulation results showed that the Daecheong Reservoir is a heterotrophic system in which CO2 is supersaturated as a whole and releases CO2 to the atmosphere. Spatially, CO2 emissions were greater in the lacustrine zone than in the riverine and transition zones. In terms of time, CO2 emissions changed dynamically according to the temporal stratification structure of the reservoir and temporal variations of algae biomass. CO2 emissions were greater at night than during the day and were seasonally greatest in winter. The CO2 NAF calculated by the CE-QUAL-W2 model and the gas exchange theory showed a similar range, but there was a difference in the point of occurrence of the peak value. The findings provide useful information to improve the quantification of CO2 emissions from reservoirs. In order to reduce the uncertainty in the estimation of reservoir carbon emissions, more precise monitoring in time and space is required.

Estimation of Transport and Mass balance of Tributyltin in Masan Bay (마산만의 Tributyltin 거동 및 물질수지 산정)

  • Kim Dong-Myung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.5 no.4
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    • pp.48-56
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    • 2002
  • It was peformed to estimate the sensitivity analyses and mass balance for tributyltin in Masan Bay, using the model builded by stella program. The results of the sensitivity analysis for dissolved tributyltin and tributyltin in the particulate organic carbon showed that not only organic carbon partition coefficient but also settling rate is important. In the case of tributyltin in phytoplankton, bioconcentration factor of phytoplankton is most important. The results of the mass balance showed that standing stocks of tributyltin in water, in phytoplankton and in particulate organic carbon are 3.29×10⁴g, 1.16×10²g and 3.17×10³g, respectively. In the case of flux, partition to particulate organic carbon showed most high value, 1.64×10³g/4ay, and next were deposition to sediment, 1.64×10³g/day and transportation to open sea by tide, 1.64×10³g/day.

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Removal Characteristics of Volatile Organic Compounds in Biofilters and Stoichiometric Analysis of Biological Reaction by Carbon Mass Balance (바이오필터의 휘발성유기화합물 제거특성 및 탄소물질수지를 이용한 생물반응의 양론적 해석)

  • Kim, Dae-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.8
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    • pp.747-753
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    • 2010
  • This study was performed to investigate the removal characteristics of volatile organic compounds (VOCs) in the gasphase biofilters, and to propose a stoichiometric analysis approach to characterize biological reaction through carbon mass balance. The VOCs studied were toluene, styrene, methyl ethyl ketone (MEK), and methyl isobutyl ketone (MIBK) as a single substrate for each biofilter. The critical loading rate was determined to be $46.9\;g/m^3{\cdot}hr$, $25.8\;g/m^3{\cdot}hr$, $96.3\;g/m^3{\cdot}hr$, and $66.5\;g/m^3{\cdot}hr$ for toluene, styrene, MEK, and MIBK, respectively. The obtained results indicated that the critical loading rate was well correlated the octanol-water partition coefficient. In the analysis of carbon mass balance, carbon recovery to $CO_2$ became relatively lower as substrate loadings increased, but higher for carbon recovery to biomass. Stoichiometric analysis revealed that biomass yield increased as substrate loadings increased, and its coefficient (g biomass/g substrate) varied from 0.31 to 0.57 for toluene, 0.29 to 0.57 for styrene, 0.08 to 0.56 for MEK, and 0.14 to 0.53 for MIBK.

Mass Balance of Finfish Cage Farm in South Korea (어류가두리 양식장의 물질수지 산정)

  • Bo-Ram Sim;Hyung Chul Kim;Sang-Pil Yoon;SokJin Hong;Woosung Jung;Sungchan Kang
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.56 no.4
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    • pp.473-483
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    • 2023
  • This study was conducted to better understand the impact of marine fish farming by estimating mass balances of carbon and nitrogen. According to the results, 94.55% of carbon and 95.66% of nitrogen inputs were from the feed supplied in the farm. Of the total carbon emissions in the farm, 47.28% was due to fish respiration, which was subsequently released into seawater. Advection and diffusion in the farm contributed to 30.29% of the carbon released. In the case of nitrogen, 50.70% of the nitrogen released into the seawater was produced by fish excreta, and 31.37% was advected and diffused into the system. The sedimentary environment received 3.82% and 3.10% of the carbon and nitrogen released from the farm, respectively. The fish feed used for healthy growth contained 11.64% carbon and 9.17% nitrogen. Since the feed type was floating pellets, the load released into the sedimentary environment was relatively lower than that released into the marine environment. These findings suggest that the identification of an optimal fish feed that respects fish physiology and preserves a healthy ecology is critical for the future of aquaculture. Furthermore, ecosystem-based aquaculture systems that decrease environmental burden, while endeavoring to improve environmental health, are required.

Application of Computer-coupled Mass Spectrometer for Continuous On-line Monitoring of Cell Growth and Growth Rate (세포증식과 증식속도의 On-line Monitoring을 위한 Computer- coupled Mass Spectrometer의 응용)

  • 남수완;최춘순;김정회
    • Microbiology and Biotechnology Letters
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    • v.17 no.3
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    • pp.241-246
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    • 1989
  • Continuous on-line monitoring of cell concentration and growth rate in aerobic batch fermentation process was carried out by analyzing the exhaust gas composition of tormentor with a quadrupole mass spectrometer. From the mass spectrometric analyses of major gaseous components, i.e. $N_2$, $O_2$, $CO_2$ and $H_2O$, and the material balance equations for oxygen and carbon dioxide, oxygen uptake rate (OUR) rind carbon dioxide evolution rate (CER) were instantaneously calculated using a computer (16-bit IBM PC-AT) interfaced to a quadrupole mass spectrometer. The calculated OUR and CER data were used for the estimation of cell concentration and growth rate of Candida utilis during batch culture. It was found that the cell concentration could be satisfactorily estimated from the data of OUR arid CER during the culture and this method could be successfully und for the continuous monitoring of cell growth and growth rate.

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