• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.313-316
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• 2012

In this study, the combustion and emission characteristics of waste cooking oil biodiesel was investigated. The fuel was injected from 5 CAD (Crank angle degree) ATDC (After top dead center) to -60 CAD ATDC by 5 CAD with 800 bar and 1600 bar injection pressure. Generally, the hydrocarbon, carbon monoxide and smoke emissions from biodiesel fuel were lower than the emission levels of diesel fuel. However, the emission characteristic of biodiesel got worse than diesel when the fuel was injected earlier than -30 CAD ATDC. $NO_x$ emission from biodeisel was higher than diesel fuel in all experimental conditions.

• 한국연소학회지
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• 제21권3호
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• pp.16-23
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• 2016

In this study, skeletal mechanisms are produced by directed relation graph with specified threshold value and sensitivity analysis based on species database from the directed relation graph. Skeletal mechanism is optimized through the elimination of unimportant reaction steps by computational singular perturbation importance index. Reduction is performed for the detailed mechanism of methyl butanoate consisting of 264 species and 1219 elementary reactions. Validation shows acceptable agreement for auto-ignition delays in wide parametric ranges of pressure, temperature and equivalence ratio. Methyl butanoate has been proposed as a simple biodiesel surrogate although the alkyl chain consists of four carbon atoms. The resulting surrogate mechanism for n-heptane and MB consists of 76 species and 226 reaction steps including those for NOx.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 2008년도 춘계학술논문발표회 논문집
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• pp.100-103
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• 2008

Autoignition suppression of hydrogen/air premixed mixtures by $CF_3CHFCF_3$(HFP) was investigated computationally. Numerical simulation was performed in isobaric and homogeneous system to evaluate the induction times. The detailed chemistry of 93 species and 817 reaction mechanism was introduced for hydrogen/air/HFP mixtures. The results shows the similar concentrations for the major reactants such as hydrogen and oxygen during autoignition while water vapor produced at the ignition temperature was decomposed later, which leaded to the shoulder on the concentration of H, OH and O radical with time. The fluorine included from HFP was converted mainly to stable HF and the carbon was formed to various species, CF2, CF2O, CO etc. More details of chemical effects of HFP addition will be investigate with sensitivity analysis in the near future.

• 대한건축학회논문집:구조계
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• 제34권3호
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• pp.37-42
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• 2018

The use of fly ash in construction materials is increasing worldwide due the various advantages of using it, such as to produce durable concrete, or to use less cement and thus lower carbon dioxide emissions. The quality of fly ash is often determined by loss on ignition value (LOI), where an upper limit of LOI is set in each country for quality control purpose. However, due to many reasons, production of high LOI fly ash is increasing that cannot be utilized in concrete, ending up in landfill. In this study, the effect of fly ash use in cementitious materials on nitrogen oxides adsorption is examined. In particular, the effect of using high LOI, and thus high carbon content fly ash on nitrogen oxides adsorption is investigated. The results suggest that the higher carbon content fly ash is related to higher nitrogen dioxide adsorption, although normal fly ash was also more effective in nitrogen dioxide adsorption than ordinary portland cement. Also, higher replacement rate of up to 40% of fly ash is beneficial for nitrogen dioxide adsorption. These results demonstrate that high carbon fly ash can be used as construction materials in an environmentally friendly way where strength requirement is low and where nitrogen oxides emissions are high.

• 에너지공학
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• 제13권2호
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• pp.161-165
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• 2004

Evaporative emissions from gasoline powered vehicles continue to be a major concern. The performance of carbon canister in evaporative emission control systems has become an important aspect of overall fuel system development and design. A vehicle's evaporative emission control system is continuously working, even when the vehicle is not running, due to generation of vapors from the fuel tank during ambient temperature variations. In this study, the effects of evaporative emissions on the engine performance were investigated. The experimental results show the effectiveness of this system for future exhaust emissions and enhanced evaporative emissions. This paper discusses the evaluation on the relationship between carbon canister condition and engine performance while engine is running.

• 한국수소및신에너지학회논문집
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• 제28권2호
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• pp.174-180
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• 2017

Recently, the world faces the environmental problem such as air pollution due to harmful gas discharged from car and abnormal climate due to the green-house gases increased by the discharge of $CO_2$. Compressed Natural Gas (CNG), one of alternative for this problem, is less harmful, compared to the existing fossil fuel, as gaseous fuel, and less carbon in fuel ingredients and carbon dioxide generation rate relatively favorable more than the existing fuel. However, CNG fuel has the weakness of slow flame propagation speed and difficult fast burn. On the other hand, hydrogen does not include carbon in fuel ingredients, and does not discharge harmful gas such as CO and HC. Moreover, it has strength of quick burning velocity and ignition is possible with small ignition energy source and it's has wide Lean Flammability Limit. If using this hydrogen with CNG fuel, the characteristics of output and discharge gas is improved by the mixer's burning velocity improved, and, at the same time, is possible to have stable lean combustion with the reduction of $CO_2$ expected. Therefore, this research tries to identify the characteristics of engine and emission gas when mixing CNG fuel and hydrogen in each portion and burning them in spark igniting engine, and grasp the lean combustion limit and emission gas characteristics according and use it as the basic data of hydrogen-CNG premixed engine.

• 한국수소및신에너지학회논문집
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• 제27권4호
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• pp.357-364
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• 2016

Recently, the world faces the environmental problem such as air pollution due to harmful gas discharged from car and abnormal climate due to the green-house gases increased by the discharge of $CO_2$. Compressed Natural Gas (CNG), one of alternative for this problem, is less harmful, compared to the existing fossil fuel, as gaseous fuel, and less carbon in fuel ingredients and carbon dioxide generation rate relatively favorable more than the existing fuel. However, CNG fuel has the weakness of slow flame propagation speed and difficult fast burn. On the other hand, hydrogen does not include carbon in fuel ingredients, and does not discharge harmful gas such as CO and HC. Moreover, it has strength of quick burning velocity and ignition is possible with small ignition energy source and it's has wide Lean Flammability Limit. If using this hydrogen with CNG fuel, the characteristics of output and discharge gas is improved by the mixer's burning velocity improved, and, at the same time, is possible to have stable lean combustion with the reduction of $CO_2$ expected. Therefore, this research tries to identify the characteristics of engine and emission gas when mixing CNG fuel and hydrogen in each portion and burning them in spark igniting engine, and grasp the combustion stability and emission gas characteristics according and use it as the basic data of hydrogen-CNG premixed engine.

• 한국추진공학회지
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• 제11권6호
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• pp.1-8
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• 2007

본 연구에서는 로켓 모타의 추진제 점화 특성을 살펴보기 위하여 혼합형, 복기 및 니트라민 추진제를 대상으로 압력 변화에 따른 점화지연시간을 아크 이미지를 이용하여 측정하였다. 추진제 표면의 반사에너지를 측정하기 위하여 광섬유 표면반사계를 사용하였다. 추진제 점화성은 복기 추진제 > 혼합형 추진제 > 니트라민 추진제 순으로 나타났으며, 니트라민 추진제 점화에 가장 큰 점화 에너지가 필요했으나 압력이 $75{\sim}400$ psia 범위로 상승함에 따라 니트라민 추진제의 점화 지연 시간은 급격히 감소하였다. 카본 블랙, ZrC 및 WC 등의 소량의 오페시화이어를 첨가함으로써 추진제 표면의 흡수도를 증가시킬 수 있었다.

• 한국산림과학회지
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• 제98권3호
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• pp.290-296
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• 2009

본 연구에서는 영동지역에서 자생하는 초본류 가운데 김의털, 방아풀, 주름조개풀, 칡, 엉겅퀴를 대상으로 발화점시험기, 콘칼로리미터, 연기밀도시험기 등을 이용하여 연소특성을 고찰하였다. 발화온도 범위는 $400{\sim}455^{\circ}C$로 확인되었으며 착화는 일어나지 않았다. 방아풀은 가장 많은 열량을 방출하였고, 김의털은 가장 많은 연기를 방출하였으며, 칡과 엉겅퀴는 가장 많은 CO와 $CO_2$를 방출하였다. 따라서 산불발생 시 방아풀은 열방출량이 많아 산불강도가 클 것으로 생각되며 김의털, 칡, 엉겅퀴는 다량의 연기와 CO, $CO_2$가 방출됨에 따라 피난이 어려울 것으로 사료된다.

• 한국자동차공학회논문집
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• 제15권3호
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• pp.54-62
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• 2007

The knock characteristics in an engine were investigated under homogeneous charge compression ignition (HCCI) operation. Liquefied petroleum gas (LPG)and gasoline were used as fuels and injected at the intake port using port fuel injection equipment. Di-methyl ether (DME) was used as an ignition promoter and was injected directly into the cylinder near compression top dead center (TDC). A commercial variable valve timing device was used to control the volumetric efficiency and the amount of internal residual gas. Different intake valve timingsand fuel injection amounts were tested to verify the knock characteristics of the HCCI engine. The ringing intensity (RI) was used to define the intensity of knock according to the operating conditions. The RI of the LPG HCCI engine was lower than that of the gasoline HCCI engine at every experimental condition. The indicated mean effective pressure (IMEP) dropped when the RI was over 0.5 MW/m2and the maximum combustion pressure was over 6.5MPa. There was no significant relationship between RI and fuel type. The RI can be predicted by the crank angle degree (CAD) at 50 CA. Carbon monoxide (CO) and hydrocarbon (HC) emissions were minimized at high RI conditions. The shortest burn duration under low RI was effective in achieving low HC and CO emissions.