• 제목/요약/키워드: Carbon glass

검색결과 753건 처리시간 0.041초

Carbon Nanotube Deposition using Helicon Plasma CVD at Low Temperature

  • Muroyama, Masakazu;Kazuto, Kimura;Yagi, Takao;Inoue, Kouji;Saito, Ichiro
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.201-202
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    • 2003
  • We developed a novel growth method of aligned carbon nanotubes. Aligned carbon nanotubes are grown on a metal catalyst on a glass substrate using biased Helicon plasma chemical vapor deposition (HPECVD) of $CH_4/H_2$ gases from 400 C to 500 C. The Helicon plasma source is one of the high-density plasma sources and is promising for low temperature carbon deposition. A Ni film was used as a catalyst to reduce the activation energy of the nanotubes' growth. The carbon nanotubes were deposited on the nickel catalysis layer selectively.

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활성탄과 유리섬유를 흡착제로 이용한 아조염료 함유 폐수의 처리 (Adsorption Treatment of Azo Dye Containing Wastewater using Activated Carbon and Glass Fiber as an Adsorbent)

  • 백미화;전혜인;이지애;김동수
    • 한국물환경학회지
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    • 제25권3호
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    • pp.370-374
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    • 2009
  • Adsorption characteristics of glass fibers, obtained from the spent lithium primary batteries recycling process, were investigated for the removal of Acid Red 27 dye from aqueous solution. The batch data clearly showed that increasing the initial sorptive concentration apparently enhanced the amount adsorbed and the uptake process followed the pseudo-second order rate model. The equilibrium adsorption data at different initial sorptive concentrations were fitted well to Freundlich and Langmuir adsorption isotherms. Moreover, the increase in temperature, favored the uptake of dye on this solid, indicated the process was endothermic in nature. Further, using the temperature dependence sorption data obtained at different temperatures was used to estimate various thermodynamic parameters.

Hybrid Capacitors Using Organic Electrolytes

  • Morimoto, T.;Che, Y.;Tsushima, M.
    • 전기화학회지
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    • 제6권3호
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    • pp.174-177
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    • 2003
  • Electric double-layer capacitors based on charge storage at the interface between a high surface area activated carbon electrode and an electrolyte solution are characterized by their long cycle-life and high power density in comparison with batteries. However, energy density of electric double-layer capacitors obtained at present is about 6 Wh/kg at a power density of 500W/kg which is smaller as compared with that of batteries and limits the wide spread use of the capacitors. Therefore, a new capacitor that shows larger energy density than that of electric double-layer capacitors is proposed. The new capacitor is the hybrid capacitor consisting of activated carbon cathode, carbonaceous anode and an organic electrolyte. Maximum voltage applicable to the cell is over 4.2V that is larger than that of the electric double-layer capacitor. As a result, discharged energy density on the basis of stacked volume of electrode, current collector and separator is more than 18Wh/l at a power density of 500W/l.

플라즈마 및 니트로셀롤로우스로 처리된 유리기판을 사용한 MWCNT 스프레이 박막의 수소가스 검출특성 (Sensing Properties of Hydrogen Gas for the MWCNT Thin Film Sprayed on the Glass Substrate Cured with Plasma and Nitrocellulose)

  • 장경욱
    • 한국전기전자재료학회논문지
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    • 제24권4호
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    • pp.290-296
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    • 2011
  • Carbon nanotubes (CNTs) have excellent electrical, chemical stability, mechanical and thermal properties. In this paper, networks of Multi-walled carbon nanotube (MWCNT) materials were investigated as a resistive gas sensors for the $H_2$ gas detection. Sensor films were fabricated by the air spray method using the multi-walled CNTs dispersion solution on the glass substrates cured with plasma and nitrocellulose. Sensors were characterized by the resistance measurements in the self-fabricated oven in order to find the optimum detection properties for the hydrogen gas molecular. The sensitivity and the linearity of the MWVNT sensors using the glass substrate cured with plasma for the $H_2$ gas concentration of 0.06~0.6 ppm are 0.013~0.097%/sec and 0.131~0.959%FS, respectively. The MWCNT film was excellent in the response for the hydrogen gas moleculars and its reaction speed was very fast, which could be using as hydrogen gas sensor. The resistance of the fabricated sensors decreases when the sensors are exposed to $H_2$ gas.

Growth and Characterization of Vertically well Aligned Crbon Nanotubes on Glass Substrate by Plasma Enhanced Hot Filament Chemical Vapor deposition

  • Park, Chong-Yun;Yoo, Ji-Beom
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2000년도 제18회 학술발표회 논문개요집
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    • pp.210-210
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    • 2000
  • Vertically well aligned multi-wall carbon nanotubes (CNT) were grown on nickel coated glass substrates by plasma enhanced hot filament chemical vapor deposition at low temperatures below 600$^{\circ}C$. Acetylene and ammonia gas were used as the carbon source and a catalyst. Effects of growth parameters such as pre-treatment of substrate, plasma intensity, filament current, imput gas flow rate, gas composition, substrate temperature and different substrates on the growth characteristics of CNT were systematically investigated. Figure 1 shows SEM image of CNT grown on Ni coated glass substrate. Diameter of nanotube was 30 to 100nm depending on the growth condition. The diameter of CNT decreased and density of CNT increased as NH3 etching time etching time increased. Plasma intensity was found to be the most critical parameter to determine the growth of CNT. CNT was not grown at the plasma intensity lower than 500V. Growth of CNT without filament current was observed. Raman spectroscopy showed the C-C tangential stretching mode at 1592 cm1 as well as D line at 1366 cm-1. From the microanalysis using HRTEM, nickel cap was observed on the top of the grown CNT and very thin carbon amorphous layer of 5nm was found on the nickel cap. Current-voltage characteristics using STM showed about 34nA of current at the applied voltage of 1 volt. Electron emission from the vertically well aligned CNT was obtained using phosphor anode with onset electric field of 1.5C/um.

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유리탄소섬유 하이브리드 복합재의 절삭 조건에 따른 가공 결함 비교 (Comparison of Machining Defects by Cutting Condition in Hybird FRP Drilling)

  • 백종현;김수진
    • 한국기계가공학회지
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    • 제21권9호
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    • pp.12-20
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    • 2022
  • Delamination and burr defects are important problems in drilling fiber reinforced plastics. A method for measuring FRP drilling defects has been studied. Delamination and burr factors were defined as the relative length or area. Using these factors, the effects of tool shape and drilling conditions on delamination and burr were studied. In this study, the defects that occur when drilling a glass-carbon fiber hybrid composite were compared in terms of three factors. In the glass-carbon fiber hybrid composite, the effects of the feed rate and tool point angle on the delamination and burr factors were similar to those in previous studies. The diameter of the tool did not affect the defect factor. A circular burr was generated in a drill tool with a point angle of 184°, and a relatively small deburring factor was observed compared with a tool with a point angle of 140°.

Zr 기지 비정질 합금 스크랩의 비정질 형성능 및 기계적 성질에 미치는 재용해 횟수와 탄소 함량의 영향 (The Effect of Remelting Cycles and Its Carbon Content on the Glass Forming Ability and Mechanical Properties of the Zr-based Amorphous Alloy Return Scrap)

  • 이병철;김성규;박봉규;박흥일;박화순
    • 한국주조공학회지
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    • 제34권3호
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    • pp.94-99
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    • 2014
  • A commercially used Zr-based amorphous alloy was recycled and the effects of introducing carbon during recycling on the glass forming ability and mechanical properties of the alloy were investigated. The initial carbon content used in this study was 229ppm. The carbon content was gradually increased as the number of recycling iterations was increased and after the $4^{th}$ recycling it rapidly increased. As return scrap was recycled, polygonal particles precipitated, and they were identified as ZrC. The amount of the precipitates also increased with recycling. Tg, Tx and ${\Delta}T$ of the base alloy were 615 K, 696 K and 81 Kr respectively and they changed to 634 K, 706 K and 72 K after the $10^{th}$ recycling. The decrease of the ${\Delta}T$ value indicates deterioration of the glass forming ability. Hardness was not changed during three iterations of recycling but after the $4^{th}$ recycling it significantly increased. This is ascribed to an increase of amount of the hard particles, namely ZrC.

유리성형용 카본금형의 표면조도에 미치는 고출력 스퍼터링 조건의 영향 (The Effect of High Power Sputtering Conditions on Surface Roughness of Carbon Mold for Glass Forming )

  • 주성후;양재웅
    • 한국응용과학기술학회지
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    • 제41권1호
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    • pp.46-57
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    • 2024
  • In this study, the various process conditions for high-power DC Magnetron Sputtering (DCMS) on the surface roughness of carbon thin films were investigated. The optimal conditions for Si/C coating were 40min for deposition time, which does not deviate from normal plasma, to obtain the maximum deposition rate, and the conditions for the best surface roughness were -16volt bias voltage and 400watt DC power with 1.3x10-3torr chamber pressure. Under these optimal conditions, an excellent carbon thin film with a surface roughness of 1.62nm and a thickness of 724nm was obtained. As a result of XPS analysis, it was confirmed that the GLC structure (sp2 bonding) was more dominant than the DLC structure (sp3 bonding) in the thin film structure of the carbon composite layer formed by DC sputtering. Except in infrequent cases of relatively plasma instability, the lower bias voltage and applied power induces smaller surface roughness value due to the cooling effect and particle densification. For the optimal conditions for Graphite/C composite layer coating, a roughness of 36.3 nm and a thickness of 711 nm was obtained under the same conditions of the optimal process conditions for Si/C coating. This layer showed a immensely low roughness value compared to the roughness of bare graphite of 242 nm which verifies that carbon coating using DC sputtering is highly effective in modifying the surface of graphite molds for glass forming.

정적 하중을 고려한 풍력 터빈 복합재 블레이드의 구조해석과 안전도 설계 (Structural analysis and safety design of composite wind turbine blades considering static loads)

  • 최재혁;이재환;신상준
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.57.1-57.1
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    • 2011
  • 본 논문에서는 소음을 저감하고 구조적 안전도를 향상시키기 위하여 10kW급 소형 복합재 풍력터빈 블레이드를 해석, 설계하였다. 풍력터빈 블레이드 설계의 기본 사항에 맞추어 블레이드의 스팬 길이는 약 4m, 중량은 30kg 내외가 되도록 설정하였다. 풍력발전기용 블레이드는 경량화가 중요하므로 유리섬유복합재 (glass fiber reinforce pastics), 탄소섬유복합재 (carbon fiber reinforced plastics)가 사용되었다. 본 설계에서는 Carbon prepreg (WSN3KY), Carbon UD(UIN150c), E-glass 등을 사용하였다. 상용 유한요소 프로그램인 NASTRAN을 이용해 Carbon prepreg (WSN3KY), Carbon UD (UIN150c)의 탄소섬유복합재만으로 구성된 블레이드 구조해석을 수행한 결과 중량 조건 및 강도의 안전도는 충족되었으나, 높은 가격을 감안하여 E-glass와 조합하여 블레이드를 재설계할 예정이다. 이번 설계는 소형 풍력발전용 블레이드 설계이므로 좌굴은 고려하지 않았으며, 향후 필요에 따라서 좌굴 및 피로해석도 수행하여 검증할 예정이다. 그리고 블레이드가 복합재로 구성되면 감쇠력이 감소할 가능성이 있다. 탄소섬유복합재로만 구성된 블레이드 구조해석에서도 최대 40cm의 변형이 예측되었으며, 감쇠값 저하 문제도 고려하여야 될 것 같아 BEMT (Blade Element Momentum Theory) 공력모델을 이용해 구조-유체 연성 결합 해석을 수행할 계획이다.

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