• Nuclear Engineering and Technology
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• v.54 no.3
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• pp.867-876
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• 2022

An experimental study has been conducted to investigate the heat transfer characteristics of supercritical carbon dioxide (sCO₂) uniformly heated in the horizontal circular smooth tube. The results illustrated that there was a significant difference in heat transfer between the top wall and bottom wall due to the buoyancy. Bulk flow acceleration cannot be negligible in the high heat flux region, which leads to heat transfer deterioration. A new heat transfer correlation is proposed, in which the buoyancy parameter and bulk flow acceleration have been taken into account. The new correlation and six classic correlations for sCO₂ are examined in horizontal tubes. The comparison indicates that the new correlation has a better performance for sCO₂ flowing through a horizontal heating tube under natural circulation conditions. For example, 94.9% of the calculated results using the new heat transfer correlation were within ±30% of the experimental results while only 87.9% of that using the Jackson correlation (the best of the six) were within the same error bands.

• International Journal of Highway Engineering
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• v.15 no.2
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• pp.95-103
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• 2013

PURPOSES : To investigate the fundamental characteristics of blast-furnace slag mortar that was hardened with activating chemicals to capture and sequester carbon dioxide. METHODS : Various mix proportions were considered to find an appropriate stregnth development in regards with various dosages of activating chemicals, calcium hydroxides and sodium silicates, and curing conditions, air-dried, wet and underwater conditions. Flow characteristics was investigated and setting time of the mortar was measured. At different ages of 3, 7 and 28days, strength development was investigated for all the mix variables. At each age, samples were analyzed with XRD. RESULTS : The measured flow values showed the mortar lost its flowability as the activating chemicals amount increased in the scale of mole concentration. The setting time of the mortar was relatively shorter than OPC mortar but the initial curing condition was important, such as temperature. The amount of activating chemicals was found not to be critical in the sense of setting time. The strength increased with the increased amount of chemicals. The XRD analysis results showed that portlandite peaks reduced and clacite increased as the age increased. This may mean the $Ca(OH)_2$ keeps absorbing $CO_2$ in the air during curing period. CONCLUSIONS : The carbon capturing and sequestering activated blast-furnace slag mortar showed successful strength gain to be used for road system materials and its carbon absorbing property was verified though XRD analysis.

• Journal of Electrochemical Science and Technology
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• v.8 no.2
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• pp.155-161
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• 2017

Carbon felts were prepared under various thermal conditions to improve the electrochemical properties of vanadium redox flow batteries. The number of C-O and/or C-OH functional groups on the surface of the electrodes treated under airless conditions was much larger than that of the untreated and partially oxygen-treated electrodes. The carbon felt treated under airless conditions had the lowest surface area. The overall kinetic properties of the redox reaction were greatly improved for the carbon felt treated under airless conditions; i.e., the reversibility of the anodic and cathodic reactions associated with the $VO_2{^+}/VO^{2+}$ couple became more reversible. Single-cell tests indicated that the carbon felt exhibited an excellent discharge capacity of $3.1Ah{\cdot}g^{-1}$ at $40mA{\cdot}cm^{-2}$, and the corresponding Coulombic, voltage, and energy efficiencies were 89.5%, 91.8%, and 82.2%, respectively.

• International Journal of Highway Engineering
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• v.18 no.1
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• pp.119-129
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• 2016

PURPOSES : The purpose of this study is to develop a methodology for estimating additional carbon emissions due to freeway incidents. METHODS : As our country grows, our highway policy has mainly neglected the environmental and social sectors. However, with the formation of a national green growth keynote and an increase in the number of people interested in environmental and social issues, problems related to social issues, such as traffic accidents and congestion, and environmental issues, such as the impact of air pollution caused by exhaust gases that are emitted from highway vehicles, are beginning to be discussed. Accordingly, studies have been conducted on a variety of environmental aspects in the field of road transport, and for the quantitative calculation of greenhouse gas emissions, using various methods. However, in order to observe the effects of carbon emissions, microscopic simulations must use many difficult variables such as cost, analysis time, and ease of analysis process. In this study, additional greenhouse gas emissions that occur because of highway traffic accidents were classified by type (incident handling time, number of lanes blocked, freeway level of service), and the annual additional emissions based on incidents were calculated. According to the results, congestion length and emissions tend to increase with an increase in incident clearance time, number of occupied lanes, and worsening level of service. Using this data, we analyzed accident data on the Gyeong-bu Expressway (Yang-Jae IC - Osan IC) for a year. RESULTS : Additional greenhouse gas emissions that occur because of highway traffic accidents were classified by type (incident handling time, number of lanes blocked, freeway level of service) and annual additional emissions caused by accidents were calculated. CONCLUSIONS : In this study, a methodology for estimating carbon emissions due to freeway incidents was developed that incorporates macroscopic flow models. The results of the study are organized in the form of a look-Up table that calculates carbon emissions rather easily.

• Composites Research
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• v.36 no.6
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• pp.422-428
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• 2023

The electrical contact resistance between the bipolar plate (BP) and the carbon felt electrode (CFE), which are in contact by the stack clamping pressure, has a great impact on the stack efficiency because of the relatively low clamping pressure of the vanadium redox flow battery (VRFB) stack. In this study, a polyethylene (PE) composite-CFE hybrid bipolar plate structure is developed through a local heat welding process to reduce such contact resistance and improve cell performance. The PE matrix of the carbon fiber composite BP is locally melted to create a direct contact structure between the carbon fibers of CFE and the carbon fibers of BP, thereby reducing the electrical contact resistance. Area specific resistance (ASR) and gas permeability are measured to evaluate the performance of the PE composite-CFE hybrid bipolar plate. In addition, an acid aging test is performed to measure stack reliability. Finally, a VFRB unit cell charge/discharge test is performed to compare and analyze the performance of the developed PE composite-CFE hybrid BP and the conventional BP.

• Carbon letters
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• v.2 no.3_4
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• pp.192-201
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• 2001

The Carbon/Carbon composite was prepared from 3D carbon fiber preform and coal tar pitch as matrix precursor. In order to evaluate of ablative characteristics of the composite, liquid rocket system was employed Kerosene and liquid oxygen was used as propellants, operating at a nominal chamber pressure of 330 psi and a nominal mixture ratio (O/F) of 2.0. The results of an experimental evaluation were that high density composite exhibited high, while low density composites showed low erosion resistance. The erosion rate against heat flux was highly depended on the density of the materials. The morphology of eroded fiber showed differently according to collision angle with heat flux on the composite. The granular matrix which derived from carbonization pressure of 900 bar was more resistance to heat flux than well-developed flow type matrix.

• Ocean and Polar Research
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• v.26 no.2
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• pp.273-286
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• 2004

The effects of environmental forcing on autotrophic picoplankton distributional patterns were investigated for convergence ($5^{\circ}N$), divergence ($9^{\circ}N-10^{\circ}30'N$) and oligotrophic ($17^{\circ}N$) sites in the tropical eastern Pacific during 2001 and 2003 KODOS (Korea Deep Ocean Study) cruises. The distributions of picoplankton populations - Prochlorococcus, Synechococcus and picoeukaryotes algae - were determined by flow cytometric analyses. Latitudinal variations in abundance maxima, vertical profiles, integrated abundance (0-150 m), and estimated carbon biomass were contrasted for each site according to three hydrological conditions. Prochlorococcus showed consistently high abundance in the surface mixed layers of all sites at $1\;{\times}\;10^5{\sim}3\;{\times}\;10^5\;cells\;ml^{-1}$ and showed declining abundance below these layers. However, these decreasing rates were not particularly sharp showing considerably high abundance at $1\;{\times}\;10^4\;cells\;ml^{-1}$ or higher even at 100 m depth. Vertical profiles of Synechococcus and picoeukaryotes were generally parallel to each other in all sites. A clear abundance maximum was observed at divergence site at or slightly above the pycnocline depth. Higher abundance was observed at the surface mixed layer for convergence site but a sharp decrease was observed below the pycnocline. However, there was no significant abundance fluctuation with depth at more oligotrophic site ($17^{\circ}N$). Integrated cell abundance of Prochlorococcus was high in the oligotrophic site at $2.17\;{\times}\;10^{13}\;m^{-2}$, and low in the convergence site at $0.88\;{\times}\;10^{13}\;m^{-2}$. However, opposite pattern was observed for Synechococcus and picoeukaryotes where relatively high integrated cell abundance was shown in the convergence site. Estimated carbon biomass of Prochlorococcus contributed 30.4-80.3% of total autotrophic picoplankton carbon showing the highest contribution in the oligotrophic site and the lowest contribution in the convergence site. Synechococcus contribution of total autotrophic picoplantkon carbon biomass was lower than 5.8% for most of sites except the convergence site where Synechococcus contributed 23.2% of picoplankton carbon biomass. Carbon biomass of picoeukaryotes was 18.8-46.4% showing the highest carbon biomass at the convergence site. Overall, Prochlorococcus showed higher cell abundance and carbon biomass and exhibited different reaction to hydrological conditions when compare with the other two major autotrophic picoplankton groups.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.1-6
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• 2004

Lots of researches were gone already about grooving corrosion mechanism of ERW carbon steel pipe. But there is seldom study for water hammer happened by fluid and acceleration of corrosion rate by incresed flow velocity. Therefore, in this study carried out the analysis based on hydrodynamic and fracture mechanics. Analyzed stress that act on a pipe using ANSYS as a program, and also FLUENT and STAR-CD were used for flow phenomenon confirmation. As the result, fatigue failure is happened by water hammer and corrosion rate was increased because of turbulent flow.

• Journal of ILASS-Korea
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• v.13 no.4
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• pp.173-179
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• 2008

The current machinery and tools of secondary channel of the nuclear power plants were produced in the carbon-steel and low-alloy steel. What produced with the carbon-steel occurs wall thinning effect from flow accelerated corrosion by the fluid flow at high temperature, high pressure. Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle-installed. Wall thinning by flow accelerated corrosion occurs piping system, the heat exchanger, steam condenser and feedwater heaters etc,. Feedwater heaters of many nuclear power plants have recently experienced sever wall thinning damage, which will increase as operating time progress. This study describes the comparisons between the numerical results using the FLUENT code and experimental data of down scale model.

• Transactions of the Korean hydrogen and new energy society
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• v.26 no.4
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• pp.324-330
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• 2015

The electrolyte flow rates of vanadium redox flow battery play very important role in terms of ion transfer to electrolyte, kinetics and pump efficiency in system. In this paper a vanadium redox flow battery single cell was tested to suggest the optimization criteria of electrolyte flow rates on the efficiencies. The compared electrolyte circulation flow rates in this experimental work were 15, 30 and 45 mL/min. The charge/discharge characteristics of the flow rate of 30 mL/min was the best out of all flow rates in terms of charging and discharging time. The current efficiencies, voltage efficiencies and energy efficiencies at the flow rate of 30 mL/min were the best. The IR losses obtained at thd current density of $40mA/cm^2$, at the flow rates of 15, 30 and 45 mL/min were 0.085 V, 0.042 V and 0.115 V, respectively. The charge efficiencies at the current density of $40mA/cm^2$ were 96.42%, 96.45% and 96.29% for the electrolyte flow rates of 15, 30 and 45 mL/min, respectively. The voltge efficiencies at the current density of $40mA/cm^2$ were 77.34%, 80.62% and 76.10% for the electrolyte flow rates of 15, 30 and 45 mL/min, respectively. Finally, the energy efficiencies at the current density of $40mA/cm^2$ were 74.57%, 77.76% and 73.27% for the electrolyte flow rates of 15, 30 and 45 mL/min, respectively. The optimum flow rates of electrolytes were 20 mL/min in most of operating variables of vanadium redox flow battery.