• Composites Research
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• v.36 no.6
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• pp.422-428
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• 2023

The electrical contact resistance between the bipolar plate (BP) and the carbon felt electrode (CFE), which are in contact by the stack clamping pressure, has a great impact on the stack efficiency because of the relatively low clamping pressure of the vanadium redox flow battery (VRFB) stack. In this study, a polyethylene (PE) composite-CFE hybrid bipolar plate structure is developed through a local heat welding process to reduce such contact resistance and improve cell performance. The PE matrix of the carbon fiber composite BP is locally melted to create a direct contact structure between the carbon fibers of CFE and the carbon fibers of BP, thereby reducing the electrical contact resistance. Area specific resistance (ASR) and gas permeability are measured to evaluate the performance of the PE composite-CFE hybrid bipolar plate. In addition, an acid aging test is performed to measure stack reliability. Finally, a VFRB unit cell charge/discharge test is performed to compare and analyze the performance of the developed PE composite-CFE hybrid BP and the conventional BP.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.701-706
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• 2003

A study on the electrosorption of U(VI) onto porous activated carbon fibers (ACFs) was performed to treat uranium-containing lagoon sludge. Effective U(Ⅵ) removal is accomplished when a negative potential is applied to the activated carbon fiber(ACF) electrode. For a feed concentration of 100mg/L, the concentration of U(VI) in the cell effluent is reduced to less than 1mg/L. The adsorbed uranium could be deserted from the ACF by passing a 1M NaCl solution through the cell and applying a positive potential onto the electrode. The regeneration of ACF from the cycling experiments was confirmed.

• Korean Journal of Materials Research
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• v.19 no.10
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• pp.544-549
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• 2009

Activated carbon (AC) with very large surface area has high capacitance per weight. However, such activation methods tend to suffer from low yields, below 50%, and are low in electrode density and capacitance per volume. Carbon NanoFibers (CNFs) had high surface area polarizability, high electrical conductivity and chemical stability, as well as extremely high mechanical strength and modulus, which make them an important material for electrochemical capacitors. The electrochemical properties of immobilized CNF electrodes were studied for use as in electrical double layer capacitor (EDLC) applications. Immobilized CNFs on Ni foam grown by thermal chemical vapor deposition (CVD) were successfully fabricated. CNFs had a uniform diameter range from 50 to 60 nm. Surface area was 56 m$^2$/g. CNF electrodes were compared with AC and multi wall carbon nanotube (MWNT) electrodes. The electrochemical performance of the various electrodes was examined with aqueous electrolyte of 2M KOH. Equivalent series resistance (ESR) of the CNF electrodes was lower than that of AC and MWNT electrodes. The specific capacitance of 47.5 F/g of the CNF electrodes was achieved with discharge current density of 1 mA/cm$^2$.

• Carbon letters
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• v.20
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• pp.19-25
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• 2016

Activated carbon fiber (ACF) surfaces are modified using an electron beam under different aqueous solutions to improve the NO gas sensitivity of a gas sensor based on ACFs. The oxygen functional group on the ACF surface is changed, resulting in an increase of the number of non-carbonyl (-C-O-C-) groups from 32.5% for pristine ACFs to 39.53% and 41.75% for ACFs treated with hydrogen peroxide and potassium hydroxide solutions, respectively. We discover that the NO gas sensitivity of the gas sensor fabricated using the modified ACFs as an electrode material is increased, although the specific surface area of the ACFs is decreased because of the recovery of their crystal structure. This is attributed to the static electric interaction between NO gas and the non-carbonyl groups introduced onto the ACF surfaces.

• Journal of the Korea institute for structural maintenance and inspection
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• v.28 no.3
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• pp.47-58
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• 2024

This study were conduced experimentally to analyze the heat-generating performance, flexural strength, and microstructure of conductive mortar mixed with micro steel fiber and multi-wall carbon nanotube (MWCNT). In the conductive mortar heat-generating performance and flexural strength tests, the mixing concentration of MWCNT was selected as 0.0wt%, 0.5wt%, and 1.0wt% relative to the weight of cement, and micro steel fibers were mixed at 2.0vol% relative to the volume. The performance experiments were conducted with various applied voltages (DC 10V, 30V, 60V) and different electrode spacings (40 mm, 120 mm) as parameters, and the flexural strength was measured at the curing age of 28 days and compared and analyzed with the normal mortar. Furthermore, the surface shape and microstructure of conductive mortar were analyzed using a field emission scanning electron microscope (FE-SEM). The results showed that the heat-generating performance improved as the mixing concentration of MWCNT and the applied voltage increased, and it further improved as the electrode spacing became narrower. However, even if the mixing concentration of MWCNT was added up to 1.0 wt%, the heat-generating performance was not significantly improved. As a result of the flexural strength test, the average flexural strength of all specimens except the PM specimen and the MWCNT mixed specimens was 4.5 MPa or more, showing high flexural strength due to the incorporation of micro steel fibers. Through FE-SEM image analysis, Through FE-SEM image analysis, it was confirmed that a conductive network was formed between micro steel fibers and MWCNT particles in the cement matrix.

• Korean Chemical Engineering Research
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• v.60 no.1
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• pp.1-6
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• 2022

As the demand for wearable devices increases, many studies have been studied on the development of flexible electrode materials recently. In particular, the development of high-performance flexible electrode materials is very important for wearable sensors for healthcare because it is necessary to continuously monitor and accurately detect body information such as body temperature, heart rate, blood glucose, and oxygen concentration in real time. In this study, we fabricated the nonenzymatic glucose sensor based on polyaniline/carbon nanotube fiber (PANI/CNT fiber) electrode. PANI layer was synthesized on the flexible CNT fiber electrode through electrochemical polymerization process in order to improve the performance of a flexible CNT fiber based electrode material. Surface morphology of the PANI/CNT fiber electrode was observed by scanning electron microscopy. And its electrochemical characteristics were investigated by chronoamperometry, cyclic voltammetry, electrochemical impedance spectroscopy. Compared to bare CNT fiber electrode, this PANI/CNT fiber electrode exhibited small electron transfer resistance, low peak separation potential and large surface area, resulting in enhanced sensing properties for glucose such as wide linear range (0.024~0.39 and 1.56~50 mM), high sensitivity (52.91 and 2.24 ㎂/mM·cm²), low detection limit (2 μM) and good selectivity. Therefore, it is expected that it will be possible to develop high performance CNT fiber based flexible electrode materials using various nanomaterials.

• Journal of the Korean Electrochemical Society
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• v.5 no.3
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• pp.117-124
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• 2002

Poly(acrylonitrile)(PAN) solutions in dimethylformamide(DMF) were electrospun to prepare webs consisting of 400nm ultra-fine fibers. The webs were oxidatively stabilized, activated by steam and resulted to be activated carbon fibers(ACFs). The specific surface area was $800\~1230 m^2/g$, which showed a trend of a decrease of the surface area with an increase in activation temperature, showing opposite behavior to the other ACFs. The activation energy of the stabilized fibers for the steam activation was determined as 29.2 kJ/mol to be relatively low indicating the easier activation than that of other carbonized fibers. The ACF webs were characterized by pore size and specific surface uea which would be related to the specific capacitance of the electrical double layer capacitor (EDLC). The specific capacitances measured were 27 F/g, 25 F/g, 22 F/g at the respective activation temperature of $700^{circ}C,\;750^{\circ}C\;800^{\circ}C$, showing similar trend with the specific surface area i.e., the higher activation temperature was, the lower specific capacitance resulted.

• Journal of the Korean Society for Nondestructive Testing
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• v.34 no.5
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• pp.377-383
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• 2014

An addressable conducting network (ACN) makes it possible to monitor the condition of a structure using the electrical resistance between electrodes on the surface of a carbon fiber reinforced plastics (CFRP) structure. To improve the damage detection reliability of the ACN, the contact resistances between the electrodes and CFRP laminates needs to be minimized. In this study, silver nanoparticle electrodes were fabricated via printed electronics techniques on a CFRP composite. The contact resistance between the silver electrodes and CFRP were measured with respect to various fabrication conditions such as the sintering temperature of the silver nano-ink and the surface roughness of the CFRP laminates. The interfaces between the silver electrode and carbon fibers were observed using a scanning electron microscope (SEM). Based on this study, it was found that the lowest contact resistance of $0.3664{\Omega}$ could be achieved when the sintering temperature of the silver nano-ink and surface roughness were $120^{\circ}C$ and 0.230 a, respectively.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.1
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• pp.66-73
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• 2022

The purpose of this study was to develop self-heating concrete by utilizing the conduction resistance of concrete in order to reduce the risk of occurrence of black ice in the concrete pavement in winter and to prevent damage caused by freez-thawing effect. For this purpose, it was attempted to evaluate the strength and temperature exothermic characteristics using powder and liquid waste CNTs and a waste cathode agent as a conduction promotion. It was analyzed that liquid waste CNT had an effective dispersion degree in the mortar and a small decrease in strength occurred. In addition, DC 24 V was supplied by applying steel mesh, copper foil and copper wire to the mortar as electrodes, and the temperature change characteristics according to the mixing ratio of spent CNTs, anodes and carbon fibers were evaluated. In addition, by evaluating the temperature characteristics according to the electrode spacing from the selected optimal mixture, it was confirmed that it had sufficient heating characteristics up to an electrode spacing of 100 mm up to AC 50 V.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.3
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• pp.298-305
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• 2016

In this study, we treated pitch-based activated carbon fibers (ACFs) in hydrogen peroxide using electron beam (E-beam) irradiation to improve nitrogen monoxide (NO) sensing ability as an electrode material of gas sensor. The specific surface area of ACFs treated by E-beam irradiation with 400 kGy increased from $885m^2/g$ (pristine) to $1160m^2/g$ without any changes in structural property and functional group. The increase in specific surface area of the E-beam irradiated ACFs enhanced NO gas sensing properties such as response time and sensitivity. When the ACFs irradiated with 400 kGy, response time was remarkably reduced from 360 s to 210 s and sensitivity was increased by 4.5%, compared to the pristine ACFs. These results demonstrate convincingly that surface modification of ACFs using E-beam in hydrogen peroxide solution can enhance textural properties of ACFs and NO gas sensing ability of gas sensor at room temperature.