• 한국재료학회지
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• 제34권5호
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• pp.254-260
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• 2024

This study is to manufacture a titanium dioxide (TiO₂) photocatalyst by recycling sludge generated using titanium tetrachloride (TiCl₄) as a coagulant. Compared to general sewage, a TiCl₄ coagulant was applied to dyeing wastewater containing a large amount of non-degradable organic compounds to evaluate its performance. Then the generated sludge was dried and fired to prepare a photocatalyst (TFS). Scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDX), X-ray diffraction (XRD), and nitrogen oxide reduction experiments were conducted to analyze the surface properties and evaluate the photoactive ability of the prepared TFS. After using titanium tetrachloride (TiCl₄) as a coagulant in the dyeing wastewater, the water quality characteristics were measured at 84 mg/L of chemical oxygen demand (COD), 10 mg/L of T-N, and 0.9 mg/L of T-P to satisfy the discharge water quality standards. The surface properties of the TFS were investigated and the anatase crystal structure was observed. It was confirmed that the ratio of Ti and O, the main components of TiO₂, accounted for more than 90 %. As a result of the nitric oxide (NO) reduction experiment, 1.56 uMol of NO was reduced to confirm a removal rate of 20.60 %. This is judged to be a photocatalytic performance similar to that of the existing P-25. Therefore, by applying TiCl₄ to the dyeing wastewater, it is possible to solve the problems of the existing coagulant and to reduce the amount of carbon dioxide generated, using an eco-friendly sludge treatment method. In addition, it is believed that environmental and economic advantages can be obtained by manufacturing TiO₂ at an eco-friendly and lower cost than before.

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 1996년도 가을 학술발표회 초록집
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• pp.39-39
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• 1996

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 2017년도 정기학술대회 발표논문집
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• pp.141-141
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• 2017

• 한국분말재료학회지
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• 제12권5호
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• pp.336-344
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• 2005

In the present study, the focus is on the effect of cobalt oxide powder in the carbothermal reduction of the titanium-cobalt-oxygen based oxide powder by solid carbon for the optimizing synthesis process of ultra fine TiC/Co composite powder. The titanium-cobalt-oxygen based oxide powder was prepared by the combination of the spray drying and desalting processes using the titanium dioxide powder and cobalt nitrate as the raw materials. The titanium-cobalt-oxygen based oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under flowing argon atmosphere. Changes in the phase structure and thermal gravity of the mixture during carbothermal reduction were analysed using XRD and TGA. Titanium-cobalt-oxygen based oxide powder desalted at $600^{\circ}C$ had a mixture of $TiO_2\;and\;Co_{3}O_4$. And the one desalted at $800^{\circ}C$ had a mixture of $TiO_2\;and\;CoTiO_3$. In the case of the former powder, the reduction of cobalt oxide powder in the titanium-cobalt-oxygen based oxide powder occurred at lower temperature than the latter one. However, the carbothermal reduction of titanium dioxide powder in the titanium-cobalt-oxygen based oxide powder with a mixture of $TiO_2\;and\;Co_{3}O_4$ occurred at higher temperature than the one with a mixture of $TiO_2\;and\;CoTiO_3$. And also, the former powder showed a lower TiC formation ability than the latter one.

• 자원환경지질
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• 제54권6호
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• pp.733-741
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• 2021

전세계적으로 2015년 파리기후협약에서 정한 목표에 따라 2050년까지 탄소중립을 위하여 각 국가는 감축목표를 수립 및 선언하고, "장기 저탄소 발전전략" (Long-term low greenhouse gas Emission Development Strategies, LEDS)을 수립, 감축 목표 설정을 위한 로드맵 등을 발표하고 있다. 국제사회의 탄소중립사회 전환 가속화에 따라 2020년말까지 128개국이 탄소중립을 선언하였으며, G20 회원국을 중심으로 지속적으로 탄소중립선언이 확대되고 있다. 우리나라도 2020년 12월 탄소중립의 능동적 대응을 통해 탄소중립과 경제성장, 국민 삶의 질 향상을 동시 달성하는 기반 마련을 위한 "2050 탄소중립 추진전략"을 발표하였고, 이를 위한 정책과제를 단계적으로 추진하고 있다. 우리나라에서 온실가스 감축을 위하여 시행되고 있는 온실가스에너지 목표관리제 및 온실가스 배출권거래제 상쇄제도 등 의무감축제도의 영역에서 벗어나 있어 종합적인 탄소관리는 미흡하며, 현재 광해방지사업으로 인한 이산화탄소배출량을 정량화한 사례는 없다. 따라서, 본 연구에서는 전세계적인 탄소중립의 관심과 정부 정책 기조에 따라 탄소 중립 실현을 위해서 한국광해광업공단의 주 업무인 광해방지사업에 대하여 국내외 탄소배출량 산정 방법으로 제시된 표준방법을 검토하고, 광해방지사업에 적합한 탄소배출량 산정 방법을 제시하고자 하였다.

• Asian Journal of Atmospheric Environment
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• 제10권2호
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• pp.99-113
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• 2016

In order to improve the portability of basic absorbents monoethanolamine (MEA) and glycine (Gly), both were supported on microporous activated carbon (AC). Chemical modification by alkali-metal ion exchange (of Li, Na, K) was carried out on Gly-based absorbents. All supported absorbents were subjected to $CO_2$ absorption capacity (pure $CO_2$) and selectivity (indoor level) tests. Textural and chemical characterizations were carried out on test sorbents. All impregnation brought about significant reduction of specific surface area and microporosity of the adsorbent Depreciation in the textural properties was found to result to reduction in pure $CO_2$ sorption. Contrarily, low-level $CO_2$ removal capacity was enhanced as the absorbent dosage increases, resulting in supported 5 molar MEA in methanol solution. Adsorption capacities were improved from 0.016 and 0.8 in raw ACs to 1.065 mmol/g for MEA's. Surface chemistry via X-ray photoelectron spectroscopy (XPS) of the supported sorbents showed the presence of amine, pyrrole and quaternary-N. In reducing sequence of potency, pyridine, amine and pyrrolic-N were noticed to contribute significantly to $CO_2$ selective adsorption. Furthermore, the adsorption isotherm study confirms the presence of various SNGs heterogeneously distributed on AC. The adsorption mechanism of the present AC adsorbents favored Freundlich and Langmuir isotherm at lower and higher $CO_2$ concentrations respectively.

• 플랜트 저널
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• 제9권2호
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• pp.42-45
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• 2013

이산화탄소로 대표되는 온실가스 저감이 세계적인 이슈가 됨에 따라, 이산화탄소 포집 및 저장(CCS: Carbon Capture & Storage)에 대한 연구도 활발히 이루어지고 있다. 본 연구에서는 연간 1만 톤급 이산화탄소의 지중저장용 파일럿 주입플랜트를 개발하였다. 주입플랜트의 핵심 구성품은 액상 이산화탄소를 주입조건으로 가압하는 가압펌프, 가압펌프 입구조건 확보를 위한 부스터 펌프, 초임계 상태로 이산화탄소를 승온시키는 인라인 히터 등이 있다. 개발된 구성품들을 바탕으로 전체 주입시스템을 설계, 제작하였다. 제작된 시스템의 시운전을 통하여, 인버터 조절에 따른 압력상승, 펌프 모터 회전수와 주입밸브 제어를 통한 주입압력 유지, PID 제어를 통한 온도확보가 적절히 이루어짐을 확인하였다. 전체 소비전력은 2,000 ~ 2,500 W로, 가압펌프의 소비전력이 75% 이상을 차지하였다. 본 이산화탄소 주입용 파일럿 플랜트는 향후 온실가스 저감 사업에 유일한 국산화 기기로서 다양하게 활용될 것으로 예상된다.

• 한국환경보건학회지
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• 제21권2호
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• pp.68-74
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• 1995

The optimum conditions was synthesized for the formation of Magnetite ($Fe_3O_4$) by air bubbling with the suspensions obtained by mixing Ferrous sulfate ($FeSO_4\cdot 7H_2O$) and Sodium Hydroxide (NaOH) solution in various values equivalent ratio($R=2NaOH/FeSO_4$) were studied. The changes of the structure were measured with XRD, $EM and BET. Equivalent ratio R: 0.65 was synthesized Goethite ($\alpha$-FeOOH), which becomes Maghemite ($\gamma=Fe_2O_3$) by dehydration, reduction and oxidation process. At the equivalent ratio over 1 (R>1), Magnetite ($Fe_3O_4$) was synthesized directly. The oxygen-deficient Magnetite ($Fe_3O_{4-\delta}$), which is obtained by flowing $H_2$ gas(100 ml/min) through the synthesis Magnetite at 350$\circ$C for 4 hr. By using it, was researched the decomposition reaction of $CO_2$. $CO_2$ was decomposed nearly 100% in 45 minutes by the oxygen-deficient Magnetite.

• 한국환경과학회지
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• 제13권9호
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• pp.845-853
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• 2004

Recently many countries agreed to reduce emissions of greenhouse gases into the atmosphere or at least to keep them at the current level at the Kyoto Protocol. Carbon dioxide has been proven to be 80% of greenhouse gases, contributing to the increase of the earth's surface temperature. It is reported that half of the $CO_2$ emissions are produced by industry and power plants using fossil fuels. In this article, we review and analysis domestic and abroad R & D policy trends relating to UN framework convention on climate change(UNFCCC).

• 한국농공학회:학술대회논문집
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• 한국농공학회 2005년도 학술발표논문집
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• pp.598-603
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• 2005

Biogas produced from anaerobic digestion processes has about 60% of methane and about 40% of carbon dioxide. Raw biogas can be used in internal combustion engines either spark ignition or diesel engines. Since the gas has relatively low calorific values, engine power also is lower than rated power values. Modified engines or biogas-specific engines have been utilized in order to increase efficiency. Another option is gas cleansing for increasing its calorific values. A couple of European countries adopted this approach in using biogas for one of transportation fuels, such as $CO_2$ scrubbing with water or special solutions. This study reports the results of water scrubbing for reducing $CO_2$ concentration. In 2.5m-high PVC pipe accepting water, $CO_2$ reduction rates were investigated. When flow rate of $CO_2$ and air mixture was about 5 LPM, $CO_2$ concentration was decreased up to 70%. Higher calorific biogas through water scrubbing is expected to be applied to various commercial engines without costly modification.