• Title/Summary/Keyword: Carbon dioxide(CO2)

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Reforming of Propane by Carbon Dioxide using Ni/γ-A12O3 Catalysts (Ni/γ-Al2O3 촉매상에서 이산화탄소에 의한 프로판의 개질)

  • Kim, K. H.;Kim, J. H.;Chang, S. C.;Park, D. W.
    • Applied Chemistry for Engineering
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    • v.8 no.3
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    • pp.382-388
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    • 1997
  • Reforming of propane by carbon dioxide using NiO/${\gamma}$-$A1_2O_3$ was carried out in a pulse or continuous kid bed reactor. NiO/${\gamma}$-$Al_2O_3$ showed higher dissociation ability of $CO_2$ than NiO/${\gamma}$-$Al_2O_3$, and the former exhibited higher conversion of propane than the latter. The presence of oxygen in the reaction mixture of propane and $CO_2$ increased the conversion of propane and reduced the amount of carbon deposit on the catalyst surface. Mechanical mixture catalyst of NiO/${\gamma}$-$Al_2O_3$ and $Ga_2O_3$ showed higher stability to deactivation than NiO/${\gamma}$-$Al_2O_3$ itself. The synergistic effect between NiO/${\gamma}$-$Al_2O_3$ and $Al_2O_3$ was also observed in this study.

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Evaluation of Short-Term CO2 Passive Sampler for Monitoring Atmospheric CO2 Levels

  • Yim, Bongbeen;Sim, Yoon-Ah;Kim, Sun-Tae
    • Journal of Climate Change Research
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    • v.7 no.1
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    • pp.1-8
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    • 2016
  • In this study, we investigated the applicability of a short-term carbon dioxide ($CO_2$) passive sampler using turbidity change in a solution containing barium hydroxide ($Ba(OH)_2$). The mass of $CO_2$ introduced into the $Ba(OH)_2$ aqueous solution was strongly correlated ($r^2=0.9565$) to the change in turbidity caused by its reaction with the solution. The sampling rates calculated for 1 h and 24 h were $42.4{\pm}5.4mL\;min^{-1}$ and $2.3{\pm}0.3mL\;min^{-1}$, respectively. Both unexposed (blank) and exposed samplers remained stable during the storage period of at least two weeks. The detection limits of the passive sampler for $CO_2$ were 81.5 ppm for 1 h and 61.5 ppm for 24 h. Based on the results, the passive sampler using the change of turbidity in the $Ba(OH)_2$ aqueous solution appears to be a suitable tool for measuring short-term atmospheric concentrations of $CO_2$.

Impact of CO2 Emissions, Exchange Rate Regimes, and Political Stability on Currency Crises: Evidence from South Asian Countries

  • ULLLAH, Zia;FEN, Tan Xiao;TUNIO, Fayaz Hussain;ULLAH, Imran
    • The Journal of Asian Finance, Economics and Business
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    • v.9 no.2
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    • pp.29-36
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    • 2022
  • This study uses the panel probit model to investigate and evaluate the relationship between exchange rate regimes, political stability, and carbon dioxide during currency crises. To understand currency crisis times, we study a panel dataset of seven South Asian nations that contain annual observations from 1996 to 2020. Furthermore, we created the EMPI exchange market pressure indicator to detect crises. Our results strongly suggested that fixed exchange rate is negatively associated with currency crises, with good regulatory quality and better effective governments. Simultaneously, the floating exchange rate is positively related to the currency crises in those countries where the rule of law has less adequately flowed. However, CO2, exports, and interest rates are buoyantly associated with crises. The floating exchange rate, the rule of law, exports, and interest rate are associated positively and contribute more prone to the crisis episodes. Negatively associated variables contributed less amid crises episodes: fixed exchange rate regime, government effectiveness, and regulatory quality. Meanwhile, CO2 has a positive relationship with a currency crisis and contributes more likelihood to the probability of a currency crisis. Countries that adopted the fixed exchange rates with effective governments and regulatory quality faced more minor currency crises.

Effect of Weathering of Bottom Ash on Mitigation of Green House Gases Emission from Upland Soil (밭토양에서 저회의 풍화가 온실가스 배출 저감에 미치는 영향)

  • Heo, Do Young;Hong, Chang Oh
    • Korean Journal of Environmental Agriculture
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    • v.38 no.4
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    • pp.245-253
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    • 2019
  • BACKGROUND: Weathering of bottom ash (BA) might induce change of its surface texture and pH and affect physical and chemical properties of soil associated with greenhouse gas emission, when it is applied to the arable soil. This study was conducted to determine effect of weathering of BA in mitigating emission of greenhouse gases from upland soil. METHODS AND RESULTS: In a field experiment, methane (CH4), carbon dioxide (CO2), and nitrous oxide (N2O) emitted from the soil was periodically monitored using closed chamber. Three month-weathered BA and non-weathered BA were applied to an upland soil at the rates of 0, 200 Mg ha-1. Maize (Zea mays L.) was grown from July 1st to Oct 8th in 2018. Both BAs did not affect cumulative CH4 emission. Cumulative CO2 emission were 23.1, 19.8, and 18.8 Mg/ha/100days and cumulative N2O emission were 35.8, 20.9, and 17.7 kg/ha/100days for the control, non-weathered BA, and weathered BA, respectively. Weathering of BA did not decrease emission of greenhouse gases significantly, compared to the weathered BA in this study. In addition, both BAs did not decrease biomass yields of maize. CONCLUSION: BA might be a good soil amendment to mitigate emissions of CO2 and N2O from arable soil without adverse effect on crop productivity.

Study on CO2 Decomposition using Ar/CO2 Inductively Coupled Plasma (아르곤/이산화탄소 혼합가스의 유도 결합 플라즈마를 이용한 이산화탄소 분해 연구)

  • Kim, Kyung-Hyun;Kim, Kwan-Yong;Lee, Hyo-Chang;Chung, Chin-Wook
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.135-140
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    • 2015
  • Decomposition of carbon dioxide is studied using $Ar/CO_2$ mixture inductively coupled plasmas (ICP). Argon gas was added to generate plasma which has high electron density. To measure decomposition rate of $CO_2$, optical emission actinometry is used. Changing input power, pressure and mixture ratio, the plasma parameters and the spectrum intensity were measured using single Langmuir probe and spectroscope. The source characteristic of Carbon dioxide ICP observed from the obtained plasma parameters. The decomposition rate is evolved depending on the reaction and discharge mode. This result is analyzed with both the measurement of the plasma parameters and the dissociation mechanism of $CO_2$.

Applicability of CO2 Extinguishing System for Ships (질식사고 방지용 CO2 소화설비의 선박 적용성)

  • Ha, Yeon Chul;Seo, Jung Kwan
    • Journal of the Society of Naval Architects of Korea
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    • v.54 no.4
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    • pp.294-300
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    • 2017
  • The offshore installations and ships are the structures most likely to be exposed to hazards such as hydrocarbon fire and/or explosion. Developing proactive measures to prevent the escalation of such events thus requires detailed knowledge of the related phenomena and their consequences. $CO_2$ extinguishing systems are extensively used for fire accidents of on-and offshore installations because of outstanding performance and low cost. There is, however, the risk of carbon dioxide system which enumerates many of the fatalities by suffocation associated with industrial fire protection requirements. Therefore, the aim of this study is to perform the prediction of fire suppression characteristics of the carbon dioxide system in realistic enclosed compartment area of ships and propose $CO_2$ extinguish fire fighting system for preventing suffocation accidents during fire fighting. According to CFD calculations, it can be observed and assessed that various fire profiles with $CO_2$ and $O_2$ mole fraction in the target enclosed compartment area are applicable within the proposed system. Additionally, the design of fire safety system of ships and offshore installations can utilize ventilation system and/or layout arrangement through the proposed system.

Analysis of Spatial and Vertical Variability of Environmental Parameters in a Greenhouse and Comparison of Carbon Dioxide Concentration in Two Different Types of Greenhouses (온실 환경요인의 공간적 및 수직적 특성 분석과 온실 종류에 따른 이산화탄소 농도 비교)

  • Jeong, Young Ae;Jang, Dong Cheol;Kwon, Jin Kyung;Kim, Dae Hyun;Choi, Eun Young
    • Journal of Bio-Environment Control
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    • v.31 no.3
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    • pp.221-229
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    • 2022
  • This study was aimed to investigate spatial and vertical characteristics of greenhouse environments according to the location of the environmental sensors, and to investigate the correlations between temperature, light intensity, and carbon dioxide (CO2) concentration according to the type of greenhouse. Temperature, relative humidity (RH), CO2, and light sensors were installed in the four-different vertical positions of the whole canopy as well as ground and roof space at the five spatial locations of the Venlo greenhouse. Also, correlations between temperature, light intensity, and CO2 concentration in Venlo and semi-closed greenhouses were analyzed using the Curve Expert Professional program. The deviations among the spatial locations were larger in the CO2 concentration than other environmental factors in the Venlo greenhouse. The average CO2 concentration ranged from 465 to 761 µmol·mol-1 with the highest value (646 µmol·mol-1) at the Middle End (4ME) close to the main pipe (50Ø) of the liquefied CO2 gas supply and lowest (436 µmol·mol-1) at the Left Middle (5LM). The deviation among the vertical positions was greater in temperature and relative humidity than other environments. The time zone with the largest deviation in average temperature was 2 p.m. with the highest temperature (26.51℃) at the Upper Air (UA) and the lowest temperature (25.62℃) at the Lower Canopy (LC). The time zone with the largest deviation in average RH was 1 p.m. with the highest RH (76.90%) at the LC and the lowest RH (71.74%) at the UA. The highest average CO2 concentration at each hour was Roof Air (RF) and Ground (GD). The coefficient of correlations between temperature, light intensity, and CO2 concentration were 0.07 for semi-closed greenhouse and 0.66 for Venlo greenhouse. All the results indicate that while the CO2 concentration in the greenhouse needs to be analyzed in the spatial locations, temperature and humidity needs to be analyzed in the vertical positions of canopy. The target CO2 fertilization concentration for the semi-closed greenhouse with low ventilation rate should be different from that of general greenhouses.

The Influence of the Contact Amount of Supercritical CO2 on Dyeing Uniformity (초임계 CO2 접촉량이 염색 균염성에 미치는 영향에 대한 연구)

  • Park, Shin;Choi, Hyunseuk;Kim, Taeyoung;Song, Taehyun
    • Textile Coloration and Finishing
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    • v.31 no.1
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    • pp.25-32
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    • 2019
  • The influence of the contact amount of carbon dioxide per unit mass of dyestuff(${\alpha}$) on dyeing uniformity in supercritical fluid dyeing is analyzed in this study. The experiments using a 5L class Pilot Scale dyeing machine is carried out for this study purpose. For a fixed temperature and pressure, the amount of sample and the dyeing leveling time were considered as process variables. The results show that the increase in the amount of the sample causes a higher color difference than the reference sample, and it also increases the amount of residual dye. On the other hand, the color difference tended to decrease with the increase in dyeing time. Based on these results, the correlation between ${\alpha}$ value and dyeing uniformity in supercritical fluid dyeing is obtained.

Attraction and Repellent Behaviors of Culicoides Biting Midges toward Cow Dung, Carbon Dioxide, and Essential Oils

  • Yang, Daram;Yang, Myeon-Sik;Kim, Bumseok
    • Parasites, Hosts and Diseases
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    • v.59 no.5
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    • pp.465-471
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    • 2021
  • Culicoides biting midges (Diptera: Ceratopogonidae) are hematophagous arthropod vectors that transmit epizootic arthropod-borne viruses (arboviruses). Arboviruses are recognized as causes of pregnancy loss, encephalomyelitis, and congenital malformations in ruminants. Therefore, continuous monitoring and control of Culicoides, which causes significant damage to industrial animals are necessary. We performed attraction and repellent tests in Culicoides using various essential oils, cow dung, and carbon dioxide (CO2). Culicoides tended to move more to cow dung (60.8%, P<0.0001) and CO2 (63.8%, P<0.01). To the essential oils as repellents, 26.1% (P<0.0001), 18.7% (P<0.001), and 25.5% (P<0.01) of the Culicoides moved to the lavender, lemongrass, and eucalyptus chamber, respectively. The Culicoides that moved to the 3 essential oils chambers showed markedly low activity. Collectively, it was showed that Culicoides tended to be attractive to cow dung and CO2, and repellent from the 3 essential oils.