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Activated Carbon Performance for the Treatment of Diesel-Derived Polycyclic Aromatic Hydrocarbons

  • Choi, Yongju;Luthy, Richard G.
    • Ecology and Resilient Infrastructure
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    • v.2 no.2
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    • pp.177-184
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    • 2015
  • This study assessed the performance of activated carbon (AC) amendment to treat polycyclic aromatic hydrocarbons (PAHs) including both parent- and alkylated-moieties in sediment impacted by diesel. A field-collected, diesel-impacted sediment with a NAPL content of 1% was used for the study. No. 2 diesel fuel is weathered by heating at $70^{\circ}C$ for 4 days to obtain a weathered diesel sample having C3-naphthalenes to C2-phenanthrenes/anthracenes (N2/P3) ratio similar to the original sediment. The sediment samples spiked with the weathered diesel to obtain non-aqueous phase liquid (NAPL) contents of 1, 5 and 10% were contacted with AC with a dose of 5% as sediment dry weight for 1 month. By the AC-sediment contact, the freely-dissolved equilibrium concentrations were substantially reduced. Even for sediment with 10% NAPL content, the reductions in the freely-dissolved concentrations were 92% and 75% for total parent-and alkylated-PAHs, respectively. The effect of NAPL contents on the performance of AC was negligible for parent-PAHs, while for alkylated-PAHs, a slightly reduced AC performance was observed. The results suggest that the AC amendment can be an effective option for the treatment of petroleum-impacted sediment with relatively high NAPL contents.

Effect of Nb Contents and Processing Parameters on Dynamic Recrystallization Behavior of 0.15C-0.2Si-0.5Mn Low-Carbon Steels (0.15C-0.2Si-0.5Mn 저탄소강의 동적 재결정 거동에 미치는 Nb 첨가와 공정 변수의 영향)

  • Lee, Sang-In;Seo, Ha-Neul;Lee, Jae-Seung;Hwang, Byoungchul
    • Journal of the Korean Society for Heat Treatment
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    • v.29 no.5
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    • pp.209-215
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    • 2016
  • In this study, the effect of Nb contents and processing parameters on dynamic recrystallization behaviour of 0.15C-0.2Si-0.5Mn low-carbon steels was investigated. Three kinds of steel specimens with different Nb contents were fabricated and then high-temperature compressive deformation test was conducted by varying reheating temperature (RT), deformation temperature (DT), and strain rate (SR). The Nb2 and Nb4 specimens containing Nb had smaller prior austenite grain size than the Nb0 specimens, presumably due to pinning effect by the formation of carbides and carbonitrides precipitates at austenite grain boundaries. The high-temperature compressive deformation test results showed that dynamic recrystallization behavior was suppressed in the specimens containing Nb as the strain rate increased and deformation temperature decreased because of pinning effect by precipitates, grain boundary dragging effects by solute atoms, although the compressive stress increased with increasing strain rate and decreasing deformation temperature.

The evaluation for soil carbon sequestration with rice straw treatments in paddy fields

  • Seo, Myung-Chul;Cho, Hyeon-Suk;Seong, Ki-Yeong;Kim, Min-Tae;Ryu, Jin-Hee;Lee, Geon Hwi
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.340-340
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    • 2017
  • Rice straw is very important to maintain fertility in agricultural soil with several aspects such as carbon and nitrogen cycles in Korea. Recently, concerning about climate change, carbon sequestration in agricultural land has become one of the most interesting and debating issues. Rice straw is most representative source of organic material produced in agricultural sectors. In order to evaluate changes of soil carbon treated by rice straw during cultivating rice in paddy field, we carried out to treat rice straw with 0, 0.5, 1, 1.5, and $2.0ton\;ha^{-1}$ at $50{\times}50{\times}20cm$ blocks made of wood board, and analyze contents of fulvic acid and humic acid form, and total carbon periodically. The experiment was conducted in 2013-2016, and sampled with interval in a month. The organic material was applied to treatment blocks in 2 weeks ago in rice transplanting of each year. Total carbon in beginning time is low as $7.9g\;kg^{-1}$. The contents of total carbon with treatments of rice straw after experiment are recorded as 8.7, 11.2, 9.5, 10.5, and $10.9g\;kg^{-1}$ applied by 0, 0.5, 1, 1.5, and $2.0ton\;ha^{-1}$, respectively. When trend lines were calculated on changes of soil carbon in periods of experiments, The trend equations of soil carbon changes with treatments of 0, 0.5, 1, 1.5, and $2.0ton\;ha^{-1}$ were Y=0.0015X+8.479, Y=0.073X+8.2577, Y=0.0503X+8.4477, Y=0.0822X+8.2103, and Y=0.082X+8.5736. These trends suggested several results. When rice straw was applied in cultivating paddy fields, most carbon in rice straw would be decomposed regardless the amount of rice straw in soil. We calculated sequestration rate of applied rice straw as about 0.1% per year during rice cultivation in paddy fields. It means that if farmer want to increase 1% soil organic matter by using application of rice straw returned after cultivation, famer should apply rice straw continuously for ten years. The change of soil carbon as fulvic acid, humic acid, and humane is showed that only content of carbon as mumine is increased significantly while fulvic acid and humic acid were changed in range of 10 to 30% among total carbon in soil. In conclusion, to sequestrate soil carbon with rice straw, it is important for rice straw to apply continuously every year. The amount of rice straw applied is not much effected to increase soil organic matter.

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Evaluating Soil Carbon Changes in Paddy Field based on Different Fraction of Soil Organic Matter

  • Seo, Myung-Chul;Cho, Hyeon-Suk;Kim, Jun-Hwan;Sang, Wan-Gyu;Shin, Pyeong;Lee, Geon Hwi
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.6
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    • pp.736-743
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    • 2015
  • Organic matter plays important roles in soil ecosystem in terms of carbon and nitrogen cycles. Due to recent concerns on climate change, carbon sequestration in agricultural land has become one of the most interesting and debating issues. It is necessary to understand behavior of soil carbon for evaluating decomposition or sequestration of organic matter and analyzing potential carbon decomposition pattern about the kinds of organic matter sources to cope with well. In order to evaluate decomposition of soil carbon according to organic material during cultivating rice in paddy field, we treated organic material such as hairy vetch, rice straw, oil cake fertilizer, and manure compost at $50{\times}50{\times}20cm$ blocks made of wood board, and analyzed carbon contents of fulvic acid and humic acid fraction, and total carbon periodically in 2013 and 2014. Soil sampling was conducted on monthly basis. Four Kinds of organic matter were mixed with soil in treatment plots on 2 weeks before transplanting of rice. The treatment of animal compost showed the highest changes of total carbon, which showed $7.9gkg^{-1}$ in May 2013 to $11.6gkg^{-1}$ in October 2014. Fulvic acid fraction which is considered to easily decompose ranged from 1 to $2gkg^{-1}$. Humic acid fraction was changed between 1 to $3gkg^{-1}$ in all treatments until organic material had been applied in 2014. From May to August in the second year, the contents of humic acid fraction increased to about $4gkg^{-1}$. The average of humic fraction carbon at treatments of animal compost was recorded highest among treatments during two years, $2.1gkg^{-1}$. The treatment of animal compost has showed the lowest ratio of fulvic acid fraction, humic acid fraction compared with other treatments. The average ratio of fulvic fraction carbon in soil ranged from 16 to 20%, and humic fraction carbon ranged from 19 to 22%. In conclusion, animal compost including wood as bulking agent is superior in sequestrating carbon at agricultural land to other kinds of raw plant residue.

Comparing Organic Carbon Storage of Upper 15-cm Soils between Different Land Use Types in Korean Inland

  • Han, Kyung-Hwa;Cho, Hee-Rae;Lee, Jeong-Tae;Lee, Gye-Jun;Hong, Suk-Young;Zhang, Yong-Seon
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1314-1319
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    • 2011
  • This study was carried out to investigate the surface soil organic carbon fractions affecting by different land use types, including needle-leaf forest (FN), broad-leaf forest (FB), pasture, annual upland cropping land (upland), and paddy rice land (paddy). We chose seven regions across Korean inland, considering sea level altitude, and measured soil organic carbon content and physico-chemical properties such as bulk density at a depth of 0~15 cm using core samples in April for the each land use type. In addition, labile organic carbon fractions in soil including light fraction and hot water extractable carbon were investigated. From this study, organic carbon storage (Mg C per ha) in the upper 15-cm soils was highest in FB (37.8), and decreased in the order of pasture (29.1), FN (28.8), paddy (21.9), and upland crop (19.9). In forest, more than 20% of soil organic carbon existed as light fraction, the free organic matter. Hot-water extractable carbon contents of soils in five land use types were lower than 7% of their soil organic carbon content.

Design and Development of Carbon Emission Monitoring System in Sejong City, Korea (세종시 탄소배출 모니터링시스템(CEMS)의 설계)

  • Leem, Yountaik
    • The Journal of the Korea Contents Association
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    • v.14 no.2
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    • pp.482-493
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    • 2014
  • Many kinds of carbon emission monitoring systems or integrated systems have been developed so far. However, despite of the development of related techniques, they tend to be lack of statistic processing functions for feedback and policy-making data for users. In this study, a new CEMS (Carbon Emission Monitoring System) has been suggested and implemented in Sejong City, Korea. This system adapted automatic remote reading system from the site management agency as data hub to collect the electricity, gas and water usage of each household. The CEMS is consisted of 6 parts; carbon emission measurement, carbon emission standard setup and management, statistic analysis and the incentives. CEMS is distinguished with other systems for its UIs for users and the administrators. Also, data sharing with urban information system(UIS) of local government to produce information for users and policy-makers. This system makes it possible to investigate the change of energy consumption patterns, especially depending on the family structure and the housing characteristics. Furthermore, analyzing their correlation with carbon emission, it is expected to provide basic data used to establish urban environmental policies.

Development of a Simulator for the Intermediate Storage Hub Selection Modeling and Visualization of Carbon Dioxide Transport Using a Pipeline (파이프라인을 이용한 이산화탄소 수송에서 중간 저장 허브 선정 모델링 및 시각화를 위한 시뮬레이터 개발)

  • Lee, Ji-Yong
    • The Journal of the Korea Contents Association
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    • v.16 no.12
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    • pp.373-382
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    • 2016
  • Carbon dioxide Capture and Storage/Sequestration (CCS) technology has attracted attention as an ideal method for most carbon dioxide reduction needs. When the collected carbon dioxide is transported to storage via pipelines, the direct transport is made if the storage is close, otherwise it can also be transported via an intermediate storage hub. Determining the number and the location of the intermediate storage hubs is an important problem. A decision-making algorithm using a mathematical model for solving the problem requires considerably more variables and constraints to describe the multi-objective decision, but the computational complexity of the problem increases and it also does not guarantee the optimality. This research proposes an algorithm to determine the location and the number of the intermediate storage hub and develop a simulator for the connection network of the carbon dioxide emission site. The simulator also provides the course of transportation of the carbon dioxide. As a case study, this model is applied to Korea.

Statistically estimated storage potential of organic carbon by its association with clay content for Korean upland subsoil

  • Han, Kyung-Hwa;Zhang, Yong-Seon;Jung, Kang-Ho;Cho, Hee-Rae;Seo, Mi-Jin;Sonn, Yeon-Kyu
    • Korean Journal of Agricultural Science
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    • v.43 no.3
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    • pp.353-359
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    • 2016
  • Soil organic carbon (SOC) retention has gradually gotten attention due to the need for mitigation of increased atmospheric carbon dioxide and the simultaneous increase in crop productivity. We estimated the statistical maximum value of soil organic carbon (SOC) fixed by clay content using the Korean detailed soil map database. Clay content is a major factor determining SOC of subsoil because it influences the vertical mobility and adsorption capacity of dissolved organic matter. We selected 1,912 soil data of B and C horizons from 13 soil series, Sangju, Jigog, Jungdong, Bonryang, Anryong, Banho, Baegsan, Daegog, Yeongog, Bugog, Weongog, Gopyeong, and Bancheon, mainly distributed in Korean upland. The ranges of SOC and clay content were $0-40g\;kg^{-1}$ and 0 - 60%, respectively. Soils having more than 25% clay content had much lower SOC in subsoil than topsoil, probably due to low vertical mobility of dissolved organic carbon. The statistical analysis of SOC storage potential of upland subsoil, performed using 90%, 95%, and 99% maximum values in cumulative SOC frequency distribution in a range of clay content, revealed that these results could be applicable to soils with 1% - 25% of clay content. The 90% SOC maximum values, closest to the inflection point, at 5%, 10%, 15%, and 25% of clay contents were $7g\;kg^{-1}$, $10g\;kg^{-1}$, $12g\;kg^{-1}$, and $13g\;kg^{-1}$, respectively. We expect that the statistical analysis of SOC maximum values for different clay contents could contribute to quantifying the soil carbon sink capacity of Korean upland soils.

Applicability of DGCI (Dark Green Color Index) to Assess Potential Impacts of CO2 Leakage from the Geological Storage Site (이산화탄소 지중저장 시설의 잠재적 누출 판단을 위한 DGCI(Dark Green Color Index) 적용 가능성 평가)

  • Yoo, Sin Yee;Song, Yoon Jin;Oh, Hee Joo;Kim, You Jin;Yoo, Ga Young
    • Journal of Climate Change Research
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    • v.7 no.3
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    • pp.351-356
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    • 2016
  • The carbon capture and storage (CCS), which collects and stores carbon dioxide in a geological site, is a promising option to mitigate climate change. However, there is the possibility of carbon dioxide leakage from the soil in the steps of collecting, transporting, and storing. To ensure the feasibility of this technology, it is important to monitor the leakage of carbon dioxide and to assess the potential impacts. As plants are sensitive to the changes in carbon dioxide in the soil environment, we can utilize plant parameter to detect the carbon dioxide leakage. Currently, chlorophyll a content is a conventional index indicating the changes in plants, however, this method is labor intensive and it only utilizes a small portion of leaves. To overcome its limitations, a simple spectroscopic parameter, DGCI (dark green color index), was suggested as an easy and quick indicator. In this study, we compared the values of chlorophyll a contents with DGCI from the experiment investigating the impacts of high underground $CO_2$ on grape plants. Results suggest that DGCI had high correlation with chlorophyll a contents and it has high potential to be utilized as an easy indicator to monitor plants' responses to $CO_2$ treatment.

INVESTIGATION ON WELDING OF VIRGO 104 LOW CARBON MARTENSITIC STAINLESS STEEL

  • Du, Bing;Jia, Yuli;Zhou, Baojin;Zhou, Shifeng
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.255-259
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    • 2002
  • VIRGO 104 is a low carbon martensitic stainless steel that is applied to the famous Three Gorges Project. By using VOD melting process VIRGO 104 has low carbon and [H] [O] contents, and shows excellent mechanical properties and weldability. The best solution to guarantee welding quality is PWHT by 600 Cx8h.

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