• Title/Summary/Keyword: Carbon composition

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Study of Parameters on the Electrochemical Properties of Carbon-PTFE Electrode for Electric Double Layer Capacitor (EDLC용 Carbon-PTFE 전극의 전기화학적 특성에 미치는 변수 연구)

  • Kim, Ick-Jun;Yang, Sun-Hye;Jeon, Min-Je;Moon, Seong-In;Kim, Hyun-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.355-356
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    • 2006
  • This work describes the effect of the number of roll pressing and the composition of carbon black on the electric and mechanical properties of carbon-PTFE electrode, in which composition is MSP20 : carbon black: PTFE = 95-X : X : 5 wt.%. It was found that the best electric and mechanical properties were obtained for sheet electrode roll pressed about 15 times and for sheet electrode, in which composition is MSP20 carbon black : PTFE = 80 : 15 : 5 wt%. These behaviors could be explained by the network structure of PTFE fibrils and conducting paths linked with carbon blacks, respectively. On the other hand, cell capacitor using the sheet electrode with 15 wt.% of carbon black attached on aluminum current collector with the electric conductive adhesive, in composition is carbon black : CMC = 70 : 30 wt.%, has exhibited the best rate capability between 0.5 $mA/cm^2$ ~ 100 $mA/cm^2$ current density and the lowest ESR.

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Electrochemical Performance of Carbon-PTFE Electrode with High Capacitance and Density for EDLC (EDLC용 고용량, 고밀도 Carbon-PTFE 전극의 전기화학적 특성)

  • Kim, Ick-Jun;Jeon, Min-Je;Yang, Sun-Hye;Moon, Seong-In;Kim, Hyun-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.541-542
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    • 2006
  • This work describes the effect of the number of roll pressing and the composition of carbon black on the electric and mechanical properties of carbon-PTFE electrode, in which composition is MSP 20 : carbon black : PTFE = 95-X : X : 5 wt.%. It was found that the best electric and mechanical properties were obtained for sheet electrode roll pressed about 15 times and for sheet electrode, in which composition is MSP 20 : carbon black : PTFE = 80 : 15 : 5 wt.%. These behaviors could be explained by the network structure of PTFE fibrils and conducting paths linked with carbon blacks, respectively. On the other hand, cell capacitor using the sheet electrode with 15 wt.% of carbon black attached on aluminum current collector with the electric conductive adhesive, in composition is carbon black : CMC = 70 : 30 wt.%, has exhibited the best rate capability between $0.5mA/cm^2{\sim}100mA/cm^2$ current density and the lowest ESR.

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Preparation and Electrochemical Performance of Carbon-PTFE Electrode for Electric Double Layer Capacitor (EDLC용 Carbon-PTFE 전극의 제조 및 전기화학적 특성)

  • Kim, Ick-Jun;Lee, Sun-Young;Moon, Seong-In
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.9
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    • pp.833-839
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    • 2005
  • This work describes the effect of the number of roll pressing and the composition of carbon black on the electric and mechanical properties of carbon-PTFE electrode, in which composition is MSP20 : carbon black : $PTFE\;=\;95-X\;:\;X\;:\;5wt.\%$. It was found that the best electric and mechanical properties were obtained for sheet electrode roll pressed about 15 times and for sheet electrode, in which composition is MSP20 : carton black $PTFE\;=\;80\;:\;15\;:\;5wt.\%$. These behaviors could be explained by the network structure of PTFE fibrils and conducting Paths linked with carbon blacks, respectively. On the other hand, cell capacitor using the sheet electrode with $15wt.\%$ of carbon black attached on aluminum current collector with the electric conductive adhesive, in composition is carbon black $CMC\;=\;70\;:\;30wt.\%$, has exhibited the best rate capability between $0.5\;mA/cm^2\~100\;mA/cm^2$ current density and the lowest ESR.

Comparison of Organic Carbon Composition in Profile by Using Solid 13C CPNMR Spectroscopy in Volcanic Ash Soil

  • Sonn, Yeon Kyu;Kang, Seong Soo;Ha, Sang Keun;Kim, Yoo Hak;Lee, Chang Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.5
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    • pp.391-398
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    • 2013
  • Soil organic carbon (SOC) has the potential to promote the soil quality for sustainability and mitigation of global warming. There is little information on organic carbon composition despite of having resistance of carbon degradation in soil. In this study, to understand the effect of volcanic ash on organic carbon composition and quantity in soil, we investigated characteristics of volcanic soil and compared organic carbon composition of soil and humic extract by using $^{13}C$-CPMAS-NMR spectra under soil profiles of Namweon series in Jeju. SOC contents of inner soil profiles were 134.8, 101.3, and 27.4 g C $kg^{-1}$ at the layer of depth 10-20, 70-80 and 90-100 cm, respectively. These layers were significantly different to soil pH, oxalate Al contents, and soil moisture contents. Alkyl C/O-alkyl C ratio in soil was higher than that of humic extracts, which was decreased below soil depth. Aromaticity of soil and humic extract was ranged from 29-38 and 24-32%, which was highest at the humic extract of 70-80 cm in soil depth. These results indicate that the changes of SOC in volcanic ash soil resulted from alteration of organic composition by pyrolysis and stability of organic carbon by allophane in volcanic ash soil.

Characterization of Nanostructure and Electronic Properties of Catalytically Grown Carbon Nanofiber (촉매법으로 제조한 나노탄소섬유의 미세구조 및 전기적 특성 제어 연구)

  • 김명수;우원준;송희석;임연수;이재춘
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.345-353
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    • 2000
  • Carbon nanofibers were prepared from the decomposition of various carbon-containing gases over pure Ni, pure Fe and their alloys with Cu. They yields, properties, and structure of carbon nanofibers obtained from the various reaction conditions were analyzed. Type of reacting gas, reaction temperature and catalyst composition were changed as the reaction variable. With Ni-Cu catalysts, the maximum yields of carbon nanofibers were obtained at temperatures between 550 and 650$^{\circ}C$ according to the reacting gas mixtures of C2H2-H2, C2H4-H2 and C3H8-H2, and the surface areas of the carbon nanofibers produced were 20∼350㎡/g. In the case of CO-H2 mixture, the rapid deposition of carbon nanofibers occurred with Fe-Cu catalyst and the maximum yield were obtained around 550$^{\circ}C$ with the range of surface areas of 140∼170㎡/g. The electrical resistivity of carbon nanofiber regarded as the key property of filler for the application of electromagnetic interference shielding was very sensitive to the type of reactant gas and the catalyst composition ranging 0.07∼1.5Ωcm at a pressure of 10000 psi, and the resistivity of carbon nanofibers produced over pure nickel catalyst were lower than those over alloy catalysts. SEM observation showed that the carbon nanofibers produced had the diameters ranging 20∼300 nm and the straight structure of carbon nanofibers changed into the twisted or helical conformation by the variation of reacting gas and catalyst composition.

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Study on the check list composition at Sustainable building strategies and Design methods of Long-life housing (장수명 공동주택의 친환경 요소기술 및 계획기법 체크리스트 구성에 관한 연구)

  • Han, Nam-Soo;Lee, Young
    • Journal of the Korean housing association
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    • v.21 no.1
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    • pp.103-112
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    • 2010
  • This Study is about the check-List composition for 'Low carbon green growth' of Long-life housing. That utilization for required the check-list composition at Sustainable building strategies and Design methods. That for long life housing, sustainable building strategies part of building construction and interior, the proper foundation for legislative system, maintenance methods with in building life cycle, sustainable and green architecture capability realization prepare for connection plan with 'Low carbon-green growth'. Extracting from elements of Architectural planing answer to basic concept of Low carbon-green growth and aimed at Low carbon scheme for energy saving, green growth scheme for environmental conservation as to each application purpose reconstitute by classify Check-list category about elements of Architectural planing. Through this architectural research deduce elements of architectural planing that can be research utilization with in Check-list composition.

Nitrogenation of Coal Ash in the Presence of Carbon and Product Distributions of AlN, SiC and $Si_3N_4$ (석탄회의 탄소가 첨가된 질화반응과 AlN, SiC 그리고 $Si_3N_4$의 생성분포)

  • 양현수;홍원표;노재성;서동수;손응권
    • Journal of the Korean Ceramic Society
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    • v.27 no.8
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    • pp.965-970
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    • 1990
  • A nitrogenation of coal ash in the presence of carbon was carried out to examine the effects of reaction temperature, reaction time and carbon composition on the formation of AlN, SiC and Si3N4. Decreasing the particle size increased the formation of AlN and its maximum composition in the product was obtaiend under 1450~150$0^{\circ}C$, 2 hours of reaction time and about 30% of carbon addition(on the basis of sample weight). Compositions of SiC and Si3N4 were distributed to the opposite so that SiC showed a higher composition compared with Si3N4 at a lower temperature, a shorter reaction time and a greater carbon addition.

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Experimental Investigation of the Effect of Composition on the Performance and Characteristics of PEM Fuel Cell Catalyst Layers

  • Baik, Jung-Shik;Seong, Dong-Mug;Kim, Tae-Min
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.157-160
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    • 2007
  • The catalyst layer of a proton exchange membrane (PEM) fuel cell is a mixture of polymer, carbon, and platinum. The characteristics of the catalyst layer play critical role in determining the performance of the PEM fuel cell. This research investigates the role of catalyst layer composition using a Central Composite Design (CCD) experiment with two factors which are Nafion content and carbon loading while the platinum catalyst surface area is held constant. For each catalyst layer composition, polarization curves are measured to evaluate cell performance at common operating conditions, Electrochemical Impedance Spectroscopy (EIS), and Cyclic Voltammetry (CV) are then applied to investigate the cause of the observed variations in performance. The results show that both Nafion and carbon content significantly affect MEA performance. The ohmic resistance and active catalyst area of the cell do not correlate with catalyst layer composition, and observed variations in the cell resistance and active catalyst area produced changes in performance that were not significant relative to compositions of catalyst layers.

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Flame Synthesis of Carbon Nanofibers using SUS304 Substrates (촉매금속 기판을 사용한 탄소나노섬유의 화염합성)

  • Lee, Gyo-Woo;Jurng, Jong-Soo;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.8 no.2
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    • pp.50-55
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    • 2003
  • Synthesis of carbon nanofibers on a metal substrate by an ethylene fueled inverse diffusion flame was observed. Stainless steel plates were used for the catalytic metal substrate. The effects of radial distance and residence time of the substrate were investigated. The role of hydrocarbon composition in the fuel was also viewed. Nanofibers with a diameter range of 30-70nm were found on the substrate. The carbon nanofibers were formed and grown in the region from 4 to 5.5mm from the central axis of a flame outside of the visible flame front in the radial direction. The minimum residence time required for the formation of carbon nanofibers were about 20 seconds, and over 60 seconds were required for the full-scale growth. The characteristic time of the formation of carbon nanofibers was much shorter than that of the substrate temperature growth. In this study, the variation in hydrocarbon composition had no significant effect on the formation and growth of the carbon nanofibers.

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EPMA quantification on the chemical composition of retained austenite in a Fe-Mn-Si-C-based multi-phase steel

  • Yoon‑Uk Heo;Chang‑Gon Jeong;Soo‑Hyun Kim;Gun‑Young Yoon;T. T. T. Trang;Youngyun Woo;Eun Yoo Yoon;Young‑Seon Lee
    • Applied Microscopy
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    • v.52
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    • pp.14.1-14.10
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    • 2022
  • An electron probe X-ray microanalyzer (EPMA) is an essential tool for studying chemical composition distribution in the microstructure. Quantifying chemical composition using standard specimens is commonly used to determine the composition of individual phases. However, the local difference in chemical composition in the standard specimens brings the deviation of the quantified composition from the actual one. This study introduces how to overcome the error of quantification in EPMA in the practical aspect. The obtained results are applied to evaluate the chemical com position of retained austenite in multi-phase steel. Film-type austenite shows higher carbon content than blocky-type one. The measured carbon contents of the retained austenite show good coherency with the calculated value from the X-ray diffraction.