• Transactions of the Korean Society of Mechanical Engineers B
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• v.32 no.9
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• pp.669-675
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• 2008

The objectives of this paper are to examine the effect of nano-particles on the pool type absorption heat transfer enhancement and to find the optimal conditions to design a highly effective compact absorber for ammonia/water absorption system. The effect of $Al_2O_3$ nano-particles and carbon nanotube(CNT) on the absorption performance is studied experimentally. The experimental ranges of the key parameters are 20% of ammonia concentration, $0{\sim}0.08\;vol%$ (volume fraction) of CNT particles, and $0{\sim}0.06 \;vol%$ of $Al_2O_3$ nano-particles. For the ammonia/water nanofluids, the heat transfer rate and absorption rate with 0.02 vol% $Al_2O_3$ nano-particles were found to be 29% and 18% higher than those without nano-particles, respectively. It is recommended that the concentration of 0.02 vol% of $Al_2O_3$ nano-particles be the best candidate for ammonia/water absorption performance enhancement.

• Steel and Composite Structures
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• v.52 no.4
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• pp.487-499
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• 2024

The primary objective of this study is to analyze the free vibration behavior of a sandwich cylindrical shell with a defective core and wavy carbon nanotube (CNT)-enhanced face sheets, utilizing the three-dimensional theory of elasticity. The intricate equations of motion for the structure are solved semi-analytically using the generalized differential quadrature method. The shell structure consists of a damaged isotropic core and two external face sheets. The distributions of CNTs are either functionally graded (FG) or uniform across the thickness, with their mechanical properties determined through an extended rule of mixture. In this research, the conventional theory regarding the mechanical effectiveness of a matrix embedding finite-length fibers has been enhanced by introducing tube-to-tube random contact. This enhancement explicitly addresses the progressive reduction in the tubes' effective aspect ratio as the filler content increases. The study investigates the influence of a damaged matrix, CNT distribution, volume fraction, aspect ratio, and waviness on the free vibration characteristics of the sandwich cylindrical shell with wavy CNT-reinforced face sheets. Unlike two-dimensional theories such as classical and the first shear deformation plate theories, this inquiry is grounded in the three-dimensional theory of elasticity, which comprehensively accounts for transverse normal deformations.

• Computers and Concrete
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• v.34 no.3
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• pp.297-305
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• 2024

This study investigates the buckling behavior of CNTRC beams on a Winkler-Pasternak elastic foundation, considering their stiffness. To achieve the highest accuracy, the shear stiffness is taken into account based on the Higher-order Shear Deformation Theory (HSDT). A novel exponential power-law distribution of the CNT volume fraction across the beam thickness is employed to model CNTRC beams. Various reinforcement patterns are incorporated into the polymer matrix, featuring single-walled carbon nanotubes (SWCNT) that are both aligned and distributed. The effective mechanical properties of the CNTRC beam are predicted using the rule of mixtures. Hamilton's principle is applied to derive the differential equations of motion. This theoretical framework enables the validation of the approach by comparing numerical simulation results with previous studies. The impact of the exponent order (n), CNT volume fraction, geometrical ratio, and Winkler-Pasternak parameters on buckling analysis is thoroughly presented and discussed. The results indicate that, among the different types of analyzed CNTRC beams, the X-Beam pattern demonstrates the highest buckling load capacity.

• Journal of the Korean Electrochemical Society
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• v.13 no.4
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• pp.240-245
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• 2010

This work explored the catalytic effect of Pt in multi-wall carbon nanotube and poly-pyrrole conductive polymer electrocatalysts (Pt/PPy/MWCNT). A home-made Pt/PPy/MWCNT catalyst was first evaluated by comparing its electrochemical active surface area (ESA) with E-Tek commercial catalysts by cyclic voltammetry in $H_2SO_4$ solution. Then, the methanol oxidation currents of Pt/PPy/MWCNT and the hydrogen peaks in $H_2SO_4$ solution were serially measured with microporous electrode. This provided the current density of methanol oxidation based on the ESA, allowing a quantitative comparison of catalytic activity. The current densities were also measured for Pt/C catalysts of E-Tek and Tanaka Precious Metal Co. The current densities for the different catalysts were similar, implying that catalytic activity depended directly on the ESA rather than charge transfer or electronic conductivity.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.495-495
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• 2011

Miniaturized sensors capable of both sensitive and selective real-time monitoring of target analytes are tremendously valuable for various applications ranging from hazard detection to medical diagnostics. The wide-spread use of such sensors is currently limited due to insufficient selectivity for target molecules. We developed selective nanocoatings by combining trinitrotoluene (TNT) receptors bound to conjugated polydiacetylene (PDA) with single-walled carbon nanotube-field effect transistors (SWNT-FET). Selective binding events between TNT molecules and phage display derived TNT receptors were effectively transduced to sensitive SWNT-FET conductance sensors through the PDA coating. The resulting sensors exhibited unprecedented 1 fM sensitivity toward TNT in real time, with excellent selectivity over various similar aromatic compounds. Our biomimetic receptor coating approach may be useful for the development of sensitive and selective micro and nanoelectronic sensor devices for various other target analytes.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.13 no.6
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• pp.119-126
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• 2014

Micro-holes of conductive ceramic are required in micro structures. Micro-electrical discharge machining (Micro-EDM) is an effective machining method since EDM is as process for shaping hard metals and complex-shaped holes by spark erosion in all kinds of electro-conductive materials. However, as the depth of micro hole increases, the machining condition becomes more unstable due to inefficient removal of debris between the electrode and the workpiece. In this paper, micro-EDM was performed to evaluate machining characteristic such as electrode wear, machining time, taper angle, radial clearance with varying voltage and ultrasonic vibration on 10 vol.% Carbon-nanotube reinforced conductive $Al_2O_3$ composite fabricated by spark plasma sintering in previous research.

• Advances in nano research
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• v.16 no.4
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• pp.395-412
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• 2024

This article develops a nonclassical size dependent nanoplate model to study the dynamic response of functionally graded carbon nanotube (FGCNT) nanoplates under a moving load. Both nonlocal and microstructure effects are incorporated through the nonlocal strain gradient elasticity theory. To investigate the effect of reinforcement orientation of CNT, four different configurations are studied and analysed. The FGM gradation thorough the thickness direction is simulated using the power law. In the context of the first order shear deformation theory, the dynamic equations of motion and the associated boundary conditions are derived by Hamilton's principle. An analytical solution of the dynamic equations of motion is derived based on the Navier methodology. The proposed model is verified and compared with the available results in the literature and good agreement is found. The numerical results show that the dynamic performance of FGCNT nanoplates could be governed by the reinforcement pattern and volume fraction in addition to the non-classical parameters and the moving load dimensionless parameter. Obtained results are reassuring in design and analysis of nanoplates reinforced with CNTs.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.3
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• pp.319-324
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• 2013

In this study, an EP (electro-polishing)-MAP (magnetic abrasive polishing) hybrid process was developed as a precision finishing process. To evaluate the characteristics of this EP-MAP hybrid process, a series of experiments were carried out using various working gaps, current densities, and electrolyte concentrations. As a result, $NaNO_3$ was found to be very suitable as the electrolyte of the hybrid process because there was no electrochemical reaction with the CNT-Co composite. Moreover, an increase in the magnetic flux density affected the liquidity of the electrolyte and prevented it from flowing into the CNT-Co composite powder. For that reason, the lower liquidity of the electrolyte increased the thermal energy on the surface of the workpiece.

• Advances in nano research
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• v.7 no.1
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• pp.39-49
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• 2019

This paper focuses on two main objectives. The first one is to exploit an energy equivalent model and finite element method to evaluate the equivalent Young's modulus of single walled carbon nanotubes (SWCNTs) at any orientation angle by using tensile test. The calculated Young's modulus is validated with published experimental results. The second target is to exploit the finite element simulation to investigate mechanical buckling and natural frequencies of SWCNTs. Energy equivalent model is presented to describe the atomic bonding interactions and their chemical energy with mechanical structural energies. A Program of Nanotube modeler is used to generate a geometry of SWCNTs structure by defining its chirality angle, overall length of nanotube and bond length between two adjacent nodes. SWCNTs are simulated as a frame like structure; the bonds between each two neighboring atoms are treated as isotropic beam members with a uniform circular cross section. Carbon bonds is simulated as a beam and the atoms as nodes. A finite element model using 3D beam elements is built under the environment of ANSYS MAPDL environment to simulate a tensile test and characterize equivalent Young's modulus of whole CNT structure. Numerical results are presented to show critical buckling loads, axial and transverse natural frequencies of SWCNTs with different orientation angles and lengths. The understanding of mechanical behaviors of CNTs are essential in developing such structures due to their great potential in wide range of engineering applications.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.63 no.4
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• pp.351-355
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• 2014

Graphite electrodes are used for secondary batteries, fuel cells, and super capacitors. Research is underway to increased the reaction area of graphite electrodes used carbon nanotube (CNT) and porous carbon. CNT is limited to device utilization in order to used a metal catalyst by lack of surface area to improve. In contrast carbon nanowall (CNW) is chemically very stable. So this paper, microwave plasma enhanced chemical vapor deposition (PECVD) system was used to grow carbon nanowall (CNW) on Si substrate with methane ($CH_4$) and hydrogen ($H_2$) gases. To find the growth properties of CNW according to the reaction gas ratio, we have changed the methane to hydrogen gas ratios (4:1, 2:1, 1:2, and 1:4). The vertical and surficial conditions of the grown CNW according to the gas ratios were characterized by a field emission scanning electron microscopy (FE-SEM) and Raman spectroscopy measurements showed structure variations.