• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.28 no.11
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• pp.727-730
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• 2015

In this paper, we fabricated organic compounds detector using the MWCNT/PMMA (multi-walled carbon nanotube / polymethylmethacrylate) composite film. We used polymer film as a matrix material for the device framework, and introduced CNTs for reacting with the organic compounds resulting in changing electrical conductivity. Spray coating method was used to form the MWCNT/PMMA composite film detector, and pattern formation of the detector was done by shadow mask during the spray coating process. We investigated changes of electrical conductivity of the detector before and after the organic compounds exposure. Electrical conductivity of the detector tended to decrease after the exposure with various organic compounds such as acetone, tetrahydrofuran (THF), toluene, and dimethylformamide (DMF). Finally we conclude that organic compounds detection by the MWCNT/PMMA composite film detector was possible, and expect the feasibility of commercial MWCNT/PMMA composite film detector for various organic compounds.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.63.1-63.1
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• 2011

현재 상용 중인 터치패널의 전도성 필름으로는 ITO가 주로 사용된다. 하지만, 디스플레이 기기의 수요 증가와 Indium의 고갈로 인한 ITO의 수요 공급 불균형으로 인한 원가 문제가 대두되고 있다. 이 때문에, Carbon nanotube (CNT), Graphene 등의 대체 투명 전도성 물질들이 연구 중에 있지만 투과율 및 저항 문제 등이 문제가 되고 있다. 본 연구에서는 투명 전도성 필름의 광 투과도 향상을 위하여, 자외선 경화 레진을 이용하여, 전도성 필름 상에 모스 아이 레진 패턴을 형성하는 실험을 진행하였다. 패턴이 형성된 이후에는 Scanning Electro Microscope를 통하여 패턴의 형성 유무를 관찰하였고, UV-vis와 4-point probe를 이용하여 투과도 및 저항을 측정하였다. 실험 결과 모스아이패턴을 필름에 패터닝 함으로써, 전체적으로 투과도가 증가된다는 것을 확인 할 수 있었으며, 투과도의 증가폭은 단면 패터닝보다는 양면 패터닝을 한 경우가 높았다. 그리고 저항 변화에 있어서는 패턴이 있는 부분의 경우 표면 잔여층으로 인하여 급격하게 증가하였지만, 전도면 반대편에 패터닝을 진행한 경우 거의 변화하지 않았다는 것을 확인할 수 있었다. 결과적으로, 본 연구를 통해 나노 임프린트 리소그래피를 통해 전도성 폴리머 필름 상부에 모스아이나노 구조물을 제작하였고, 이를 통해 기존의 전도성 폴리머 필름의 낮은 투과율을 향상시킬 수 있었다.

• Structural Engineering and Mechanics
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• v.64 no.3
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• pp.381-390
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• 2017

Present paper deals with the large amplitude flexural vibration of carbon nanotube reinforced composite (CNTRC) plates. Distribution of CNTs as reinforcements may be uniform or functionally graded (FG). The equivalent material properties of the composite media are obtained according to a refined rule of mixtures which contains efficiency parameters. To account for the large deformations, von $K{\acute{a}}rm{\acute{a}}n$ type of geometrical nonlinearity is included into the formulation. The matrix representation of the governing equations is obtained according to the Ritz method where the basic shape functions are written in terms of the Chebyshev polynomials. Time dependency of the problem is eliminated by means of the Galerkin method and the resulting nonlinear eigenvalue problem is solved employing a direct displacement control approach. Results are obtained for completely clamped and completely simply supported plates. Results are first validated for the especial cases of FG-CNTRC and cross-ply laminated plates. Afterwards, parametric studies are given for FG-CNTRC plates with different boundary conditions. It is shown that, nonlinear frequencies are highly dependent to the volume fraction and dispersion profiles of CNTs. Furthermore, mode redistribution is observed in both simply supported and clamped FG-CNTRC plates.

• Korean Journal of Chemical Engineering
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• v.35 no.12
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• pp.2421-2429
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• 2018

Thiol-based self-assembled anchor linked to glucose oxidase (GOx) and gold nanoparticle (GNP) cluster is suggested to enhance the performance of glucose biosensor. By the adoption of thiol-based anchors, the activity of biocatalyst consisting of GOx, GNP, polyethyleneimine (PEI) and carbon nanotube (CNT) is improved because they play a crucial role in preventing the leaching out of GOx. They also promote electron collection and transfer, and this is due to a strong hydrophobic interaction between the active site of GOx and the aromatic ring of anchor, while the effect is optimized with the use of thiophenol anchor due to its simple configuration. Based on that, it is quantified that by the adoption of thiophenol as anchor, the current density of flavin adenine dinucleotide (FAD) redox reaction increases about 42%, electron transfer rate constant ($k_s$) is $9.1{\pm}0.1s^{-1}$ and the value is 26% higher than that of catalyst that does not use the anchor structure.

• Computers and Concrete
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• v.23 no.5
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• pp.361-376
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• 2019

In this research, bending analysis of a micro sandwich skew plate with isotropic core and piezoelectric composite face sheets reinforced by carbon nanotube on the elastic foundations are studied. The classical plate theory (CPT) are used to model micro sandwich skew plate and to apply size dependent effects based on modified strain gradient theory. Eshelby-Mori-Tanaka approach is considered for the effective mechanical properties of the nanocomposite face sheets. The governing equations of equilibrium are derived using minimum principle of total potential energy and then solved by extended Kantorovich method (EKM). The effects of width to thickness ratio and length to width of the sandwich plate, core-to-face sheet thickness ratio, the material length scale parameters, volume fraction of CNT, the angle of skew plate, different boundary conditions and types of cores on the deflection of micro sandwich skew plate are investigated. One of the most important results is the reduction of the deflection by increasing the angle of the micro sandwich skew plate and decreasing the deflection by decreasing the thickness of the structural core. The results of this research can be used in modern construction in the form of reinforced slabs or stiffened plates and also used in construction of bridges, the wing of airplane.

• Journal of Ocean Engineering and Technology
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• v.37 no.5
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• pp.215-224
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• 2023

While melting glaciers due to global warming have facilitated the development of polar routes, Arctic vessels require reliable anti-icing methods to prevent hull icing. Currently, the existing anti-icing method, i.e., the heating coil method, has disadvantages, such as disconnection and power inefficiency. Therefore, a carbon nanotube-based surface heating element method was developed to address these limitations. In this study, the numerical analysis of the surface heating element method was performed using ANSYS. The numerical analysis included conjugate heat transfer and computational fluid dynamics to consider the conduction solids and the effects of wind speed and temperature in cold environments. The numerical analysis method of the surface heating element method was validated by comparing the experimental results of the heating coil method with the numerical analysis results (under the -30 ℃ conditions). The surface heating element method demonstrated significantly higher efficiency, ranging from 56.65-80.17%, depending on the conditions compared to the heating coil method. Moreover, even under extreme environmental conditions (-45 ℃), the surface heating element method satisfied anti-icing requirements. The surface heating element method is more efficient and economical than the heating coil method. However, proper heat flux calculation for environmental conditions is required to prevent excessive design.

• Journal of the Korean Vacuum Society
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• v.18 no.3
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• pp.229-235
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• 2009

Millimeter-scale aligned arrays of thin-multiwalled carbon nanotube (t-MWCNT) on layered Si substrates have been synthesized by oxygen-assisted microwave plasma chemical vapor deposition (MPCVD). We have succeeded in growth of vertically aligned MWCNTs up to 2.7 mm in height for 150 min. The effect of $O_2$ and water vapour on growth rate was systematically investigated. In the case of $O_2$ gas, the growth rate was ${\sim}22{\mu}m/min$, which is outstanding growth rate comparing with those of conventional thermal CVD (TCVD). Scanning electron microscope (SEM), energy-dispersive spectroscopy (EDS), and Raman spectroscopy were used to analyze the CNT morphology, composition and growth mechanism. The role of $O_2$ gas during the CNT growth was discussed on.

• Korean Chemical Engineering Research
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• v.61 no.2
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• pp.175-188
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• 2023

Global interest in hydrogen energy is increasing as an eco-friendly future energy that can replace fossil fuels. Accordingly, a next-generation hydrogen production technology using microorganisms, nuclear power, etc. is being developed, while a lot of time and effort are still required to overcome the cost of hydrogen production based on fossil fuels. As a way to minimize greenhouse gas emissions in the hydrocarbon-based hydrogen production process, methane direct decomposition technology has recently attracted attention. In order to improve the economic feasibility of the process, the simultaneous production of value-added carbon materials with hydrogen can be one of the most essential aspects. For that purpose, various studies on catalysis related to the quality and yield of high-value carbon materials such as carbon nanotubes (CNTs). In terms of process technology, a number of the research and development of fluidized-bed reactors capable of continuous production and improved gas-solid contact efficiency has been attempted. Recently, methane direct decomposition technology using a fluidized bed has been developed to the extent that it can produce 270 kg/day of hydrogen and 1000 kg/day of carbon. Plus, with the development of catalyst regeneration, separation and recirculation technologies, the process efficiency can be further improved. This review paper investigates the recent development of catalysts and fluidized bed reactor for methane direct pyrolysis to identify the key challenges and opportunities.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.03a
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• pp.123-123
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• 2003

탄소나노튜브는 지금까지의 많은 연구를 통해 다양한 분야에 대한 응용 가능성이 확인되었으며, 그 중에서도 특히 탄소나노튜브를 이용한 전계방출표시소자(carbon nanotube field emission display, CNT-FED)는 상용화를 눈앞에 두고 있는 상황이다. 본 연구에서는 탄소나 노튜브를 합성할 수 있는 여러 가지 방법 중에서 열화학기상증착법(thermal chemical vapor deposition, thermal CVD)을 이용하여 유리기판 위에 탄소나노튜브를 합성하였다. Electron beam evaporation으로 유리기판 위에 전극층으로 Cr을 150nm를 증착하고 연속하여 촉매층인 Invar(Fe-53%Ni-6%Co 합금)를 10nm의 두께로 형성하였다. 사진식각으로 Cr층을 line 패턴한 후 Cr line 내의 Invar층을 line 및 dot 패턴하였다. 나노튜브 합성을 위해 480-58$0^{\circ}C$까지 진공분위기 또는 질소 분위기에서 20분간 승온한 후 CO(150sccm)와 H$_2$(1200sccm)를 주입하여 20분간 성장시키고 질소 분위기에서 냉각시켰다. 성장된 탄소나노튜브는 SEM, TEM, Raman spectroscopy 등을 통하여 구조 및 형상분석을 하였다. 진공승온의 경우 탄소불순물인 a-C이 많은 양 증착 되었으며 탄소나노튜브는 온도에 따라 1-5$\mu\textrm{m}$의 두께로 성장하였으나, 질소분위기 승온의 경우는 a-C이 거의 증착되지 않았으며 나노튜브의 두께가 10-20$\mu\textrm{m}$였다. 본 연구에서는 diode구조를 갖는 탄소나노튜브 에미터의 수명예측을 위해 여러 가지 가속측정조건에서 전계방출 특성을 연구하였다. Anode와 cathode 간의 간격을 400$\mu\textrm{m}$로 유지한 diode 구조에 대해 $10^{-6}$ torr 이하의 진공에서 전계방출을 측정하였다. 100 line의 에미터를 60Hz의 주파수에서 1/100 duty로 구동하였으며, duty비 증가에 따라 pulse의 on-time을 고정하고 frequency를 변화시켰다. dc까지 duty비가 증가됨에 따라 방출전류의 양이 선형적으로 증가하였다. 전압을 일정하게 고정시키고 각 duty비에서 시간에 따라 방출전류를 측정한 결과 duty비가 높을수록 방출전류가 시간에 따라 급격히 감소하였다. 각 duty비에서 방출전류의 양이 1/2로 감소하는 시점을 에미터의 수명으로 볼 때 duty비 대 에미터 수명관계를 구해 높은 duty비에서 전계방출을 시킴으로써 실제의 구동조건인 낮은 duty비에서의 수명을 단시간에 예측할 수 있었다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.152-152
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• 2008

탄소나노튜브(carbon nanotube) 필름은 낮은 전기저항, 높은 투명도, 우수한 기계적 강도 및 유연성, 열적 안정성 등의 뛰어난 특성을 가지고 있다. 본 연구에서는 다양한 계면활성제로 분산시킨 수용액으로부터 제조된 단일벽 탄소나노튜브(single-walled CNT) 필름의 면저항(sheet resistance) 특성을 비교하였다. 먼저 나노튜브의 분산을 위해 널리 사용되는 계면활성제인 sodium dodecyl sulfate(SDS)를 기준으로 탄소나노튜브의 양, 원심분리 시간, 초음파 세기 및 시간 등의 최적 공정조건을 정한 후 각 계면활성제에 대해 분산을 위한 최적 첨가량을 알아내어 계면활성제 별로 탄소나노튜브 수용액을 제조하였다. 다양한 계면활성제로 분산된 단일벽 탄소나노튜브 수용액을 알루미나 재질의 필터에 정량적으로 vacuum-filtration하여 필름을 만들었다. 이 필름들의 면저항을 측정함으로써 계면 활성제에 따른 전기적 특성의 차이를 관찰하였다. 본 연구에서 사용한 여러 가지 계면활성제 중 sodium dodecylbenze nesulfonate (NaDDBS)를 사용하여 만든 필름이 가장 낮은 면저항을 나타내었으며, 이는 NaDDBS가 단일벽 탄소나노 튜브 다발들을 개개의 튜브로 잘 분산시키기 때문인 것으로 생각된다.