• Title/Summary/Keyword: Carbon Equivalent

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Optimal Metal Dose of Alternative Cathode Catalyst Considering Organic Substances in Single Chamber Microbial Fuel Cells

  • Nam, Joo-Youn;Moon, Chungman;Jeong, Emma;Lee, Won-Tae;Shin, Hang-Sik;Kim, Hyun-Woo
    • Environmental Engineering Research
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    • v.18 no.3
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    • pp.145-150
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    • 2013
  • Optimal preparation guidelines of a cathode catalyst layer by non-precious metal catalysts were evaluated based on electrochemical performance in single-chamber microbial fuel cells (MFCs). Experiments for catalyst loading rate revealed that iron(II) phthalocyanine (FePc) can be a promising alternative, comparable to platinum (Pt) and cobalt tetramethoxyphenylporphyrin (CoTMPP), including effects of substrate concentration. Results showed that using an optimal FePc loading of $1mg/cm^2$ was equivalent to a Pt loading of $0.35mg/cm^2$ on the basis of maximum power density. Given higher loading rates or substrate concentrations, FePc proved to be a better alternative for Pt than CoTMPP. Under the optimal loading rate, it was further revealed that 40 wt% of FePc to carbon support allowed for the best power generation. These results suggest that proper control of the non-precious metal catalyst layer and substrate concentration are highly interrelated, and reveal how those combinations promote the economic power generation of single-chamber MFCs.

Strain gradient theory for vibration analysis of embedded CNT-reinforced micro Mindlin cylindrical shells considering agglomeration effects

  • Tohidi, H.;Hosseini-Hashemi, S.H.;Maghsoudpour, A.;Etemadi, S.
    • Structural Engineering and Mechanics
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    • v.62 no.5
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    • pp.551-565
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    • 2017
  • Based on the strain gradient theory (SGT), vibration analysis of an embedded micro cylindrical shell reinforced with agglomerated carbon nanotubes (CNTs) is investigated. The elastic medium is simulated by the orthotropic Pasternak foundation. The structure is subjected to magnetic field in the axial direction. For obtaining the equivalent material properties of structure and considering agglomeration effects, the Mori-Tanaka model is applied. The motion equations are derived on the basis of Mindlin cylindrical shell theory, energy method and Hamilton's principal. Differential quadrature method (DQM) is proposed to evaluate the frequency of system for different boundary conditions. The effects of different parameters such as CNTs volume percent, agglomeration of CNTs, elastic medium, magnetic field, boundary conditions, length to radius ratio and small scale parameter are shown on the frequency of the structure. The results indicate that the effect of CNTs agglomeration plays an important role in the frequency of system so that considering agglomeration leads to lower frequency. Furthermore, the frequency of structure increases with enhancing the small scale parameter.

Investigation of Cell Size Effects of Honeycomb Sandwich Composite Square Tubes Under Compressive Loadings (허니콤 샌드위치 복합소재 정사각 튜브의 셀 크기에 따른 압축거동평가)

  • Kim, Jung-Seok;Yoon, Hyuk-Jin;Kwon, Tae-Soo
    • Journal of the Korean Society for Railway
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    • v.13 no.1
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    • pp.31-36
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    • 2010
  • The objective of this study is to evaluate effects of honeycomb cell size for compressive behaviors of square sandwich composite tubes with woven fabric carbon/epoxy skin and Al honeycomb core. In order to achieve these goals, four different kinds of tubes were fabricated and compressed to 200mm~250mm under quasi-static load of 10mm/min. The Al honeycombs with cell size of 6.35mm and 9.53mm were used. The relationship of mean compressive load and cell size was evaluated. In addition, the effect of peel strength and equivalent elastic modulus in ribbon direction for the mean compressive load was investigated.

A Study on the Materials Characteristics of High Tensile Strength Steel(SM570) Plates (고장력(SM570)강재의 재료특성에 관한 연구)

  • Im, Sung Woo;Ko, Sang Ki;Ha, Dong Woo;Oh, Sang Hoon;Chang, In Hwa
    • Journal of Korean Society of Steel Construction
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    • v.12 no.6
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    • pp.649-659
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    • 2000
  • In this study, the chemical compositions and mechanical properties of high tensile strength steel plates in accordance with their thickness are quantitatively estimated, that are steel plates SM570 to be purposed to use in building structure. Test results of steel plates SM570 are compared with those of steel plates SS400 and steel plates SM490 mostly using building structure. It is found that chemical compositions, carbon equivalent, parameter of welding crack susceptibility, yield strength, tensile strength, elongation, and impact strength have satisfied the prescribed value in KS code for all case of thickness.

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Characteristics in Paintability of Advanced High Strength Steels

  • Park, Ha Sun
    • Corrosion Science and Technology
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    • v.6 no.3
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    • pp.83-89
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    • 2007
  • It is expected that advanced high strength steels (AHSS) would be widely used for vehicles with better performance in automotive industries. One of distinctive features of AHSS is the high value of carbon equivalent (Ceq), which results in the different properties in formability, weldability and paintability from those of common grade of steel sheets. There is an exponential relation between Ceq and electric resistance, which seems also to have correlation with the thickness of electric deposition (ED) coat. Higher value of Ceq of AHSS lower the thickness of ED coat of AHSS. Some elements of AHSS such as silicon, if it is concentrated on the surface, affect negatively the formation of phosphates. In this case, silicon itself doesn't affect the phosphate, but its oxide does. This phenomenon is shown dramatically in the welding area. Arc welding or laser welding melts the base material. In the process of cooling of AHSS melt, the oxides of Si and Mn are easily concentrated on the surface of boundary between welded and non‐welded area because Si and Mn could be oxidized easier than Fe. More oxide on surface results in poor phosphating and ED coating. This is more distinctive in AHSS than in mild steel. General results on paintability of AHSS would be reported, being compared to those of mild steel.

High alloyed new stainless steel shielding material for gamma and fast neutron radiation

  • Aygun, Bunyamin
    • Nuclear Engineering and Technology
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    • v.52 no.3
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    • pp.647-653
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    • 2020
  • Stainless steel is used commonly in nuclear applications for shielding radiation, so in this study, three different types of new stainless steel samples were designed and developed. New stainless steel compound ratios were determined by using Monte Carlo Simulation program Geant 4 code. In the sample production, iron (Fe), nickel (Ni), chromium (Cr), silicium (Si), sulphur (S), carbon (C), molybdenum (Mo), manganese (Mn), wolfram (W), rhenium (Re), titanium (Ti) and vanadium (V), powder materials were used with powder metallurgy method. Total macroscopic cross sections, mean free path and transmission number were calculated for the fast neutron radiation shielding by using (Geant 4) code. In addition to neutron shielding, the gamma absorption parameters such as mass attenuation coefficients (MACs) and half value layer (HVL) were calculated using Win-XCOM software. Sulfuric acid abrasion and compressive strength tests were carried out and all samples showed good resistance to acid wear and pressure force. The neutron equivalent dose was measured using an average 4.5 MeV energy fast neutron source. Results were compared to 316LN type stainless steel, which commonly used in shielding radiation. New stainless steel samples were found to absorb neutron better than 316LN stainless steel at both low and high temperatures.

Floristic Composition, Grazing Effects and Above-ground Plant Biomass in the Hulunbeier Grasslands of Inner Mongolia, China

  • Kawada, Kiyokazu;Kurosu, Mayu;Cheng, Yunxiang;Tsendeekhuu, Tsagaanbandi;Wuyunna, Wuyunna;Nakamura, Toru;Hayashi, Ichiroku
    • Journal of Ecology and Environment
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    • v.31 no.4
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    • pp.297-307
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    • 2008
  • In order to assess the effect of grazing on grasslands using floristic composition, we studied the floristic composition and plant biomass of steppe vegetation in Hulunbeier, Inner Mongolia. The dominant species of the grasslands were Stipa krylovii, Stipa grandis and Leymus chinensis. Floristic composition changed according to grazing pressure, being light, heavy and moderate. Under heavy grazing conditions, the importance value of P. acaulis, C. korshinskyi and Cleistogenes squarrosa increased in the plant community. These species were indicators of heavily grazed stand. Plant biomass of the stands ranged within 11.6g $m^{-2}$ and 63.5g $m^{-2}$ and 69.5g $m^{-2}$ and 166.2g $m^{-2}$ to the west and east of Lake Hulun, respectively. These values are equivalent to ca. $450{\sim}1,000kg$ of atmospheric carbon per hector, which is retained within the stand during the summer season.

A Study on Analysis of Mode I interlaminar Fracture Toughness of Foam Core Sandwich Structures (FOAM CORE SANDWICH 구조재의 Mode I 층간분리 파괴인성의 해석에 관한 연구)

  • Son, Se-Won;Gwon, Dong-An;Hong, Seong-Hui
    • Journal of the Korean Society for Precision Engineering
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    • v.17 no.9
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    • pp.81-86
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    • 2000
  • This paper was carried out to investigate the characteristics of interlaminar fracture toughness of foam core sandwich structures under opening loading mode by using the double cantilever beam (DCB) specimens in Carbon/Epoxy and foam core composites. instead of using symmetric geometry of DCB specimen non-symmetric DCB specimen was used to calculate the interlaminar fracture toughness. Three approaches for calculating the energy release rate({{{{ {G }_{IC } }}}}) were compared. Fracture toughness of foam core sandwich structures by autoclave vacuum bagging and hotpress were compared and analyzed. Experiment nonlinear beam bending FEM method were performed. Suggested bonding surface compensation and equivalent area inertia moment was used to calculate the energy release rate in nonlinear analytical results. The conclusions among experimental nonlinear analytical and FEM results was observed. The vacuum bagging method was shown to be able to substitute method in stead of autoclave without serious loss of Mode I energy release rate({{{{ {G }_{IC }}}}}) to be able to substitute method in stead of autoclave without serious loss of Mode I energy release rate({{{{ {G }_{IC }}}}}).

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Nonlinear free vibration of FG-CNT reinforced composite plates

  • Mirzaei, Mostafa;Kiani, Yaser
    • Structural Engineering and Mechanics
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    • v.64 no.3
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    • pp.381-390
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    • 2017
  • Present paper deals with the large amplitude flexural vibration of carbon nanotube reinforced composite (CNTRC) plates. Distribution of CNTs as reinforcements may be uniform or functionally graded (FG). The equivalent material properties of the composite media are obtained according to a refined rule of mixtures which contains efficiency parameters. To account for the large deformations, von $K{\acute{a}}rm{\acute{a}}n$ type of geometrical nonlinearity is included into the formulation. The matrix representation of the governing equations is obtained according to the Ritz method where the basic shape functions are written in terms of the Chebyshev polynomials. Time dependency of the problem is eliminated by means of the Galerkin method and the resulting nonlinear eigenvalue problem is solved employing a direct displacement control approach. Results are obtained for completely clamped and completely simply supported plates. Results are first validated for the especial cases of FG-CNTRC and cross-ply laminated plates. Afterwards, parametric studies are given for FG-CNTRC plates with different boundary conditions. It is shown that, nonlinear frequencies are highly dependent to the volume fraction and dispersion profiles of CNTs. Furthermore, mode redistribution is observed in both simply supported and clamped FG-CNTRC plates.

Dynamic stability of nanocomposite Mindlin pipes conveying pulsating fluid flow subjected to magnetic field

  • Esmaeili, Hemat Ali;Khaki, Mehran;Abbasi, Morteza
    • Structural Engineering and Mechanics
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    • v.67 no.1
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    • pp.21-31
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    • 2018
  • In this work, the dynamic stability of carbon nanotubes (CNTs) reinforced composite pipes conveying pulsating fluid flow is investigated. The pipe is surrounded by viscoelastic medium containing spring, shear and damper coefficients. Due to the existence of CNTs, the pipe is subjected to a 2D magnetic field. The radial induced force by pulsating fluid is obtained by the Navier-Stokes equation. The equivalent characteristics of the nanocomposite structure are calculated using Mori-Tanaka model. Based on first order shear deformation theory (FSDT) or Mindlin theory, energy method and Hamilton's principle, the motion equations are derived. Using harmonic differential quadrature method (HDQM) in conjunction with the Bolotin's method, the dynamic instability region (DIR) of the system is calculated. The effects of different parameters such as volume fraction of CNTs, magnetic field, boundary conditions, fluid velocity and geometrical parameters of pipe are shown on the DIR of the structure. Results show that with increasing volume fraction of CNTs, the DIR shifts to the higher frequency. In addition, the DIR of the structure will be happened at lower excitation frequencies with increasing the fluid velocity.