• Title/Summary/Keyword: Carbon Conversion

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Estimation of Soil Organic Carbon Stock in South Korea

  • Thi, Tuyet-May Do;Le, Xuan-Hien;Van, Linh Nguyen;Yeon, Minho;Lee, Giha
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.159-159
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    • 2022
  • Soil represents a substantial component within the global carbon cycle and small changes in the SOC stock may result in large changes of atmospheric CO2 particularly over tens to hundreds of years. In this study, we aim to (i) evaluate the SOC stock in the topsoil 0 - 15 cm from soil physical and chemical characteristics and (ii) find the correlation of SOC and soil organic matter (SOM) for national-scale in South Korea. First of all, based on the characteristics of the soil to calculate the soil hydraulic properties, SOC stock is the SOC mass per unit area for a given depth. It depends on bulk density (BD-g/cm3), SOC content (%), the depth of topsoil (cm), and gravel content (%). Due to insufficient data on BD observation, we establish a correlation between BD and SOC content, sand content, clay content parameter. Next, we present linear and non-linear regression models of BD and the interrelationship between SOC and SOM using a linear regression model and determine the conversion factor for them, comparing with Van Bemmelen 1890's factor value for the country scale. The results obtained, helps managers come up with suitable solutions to conserve land resources.

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Effect of carbonization temperature and chemical pre-treatment on the thermal change and fiber morphology of kenaf-based carbon fibers

  • Kim, Jin-Myung;Song, In-Seong;Cho, Dong-Hwan;Hong, Ik-Pyo
    • Carbon letters
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    • v.12 no.3
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    • pp.131-137
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    • 2011
  • Kenaf fibers, cellulose-based natural fibers, were used as precursor for preparing kenafbased carbon fibers. The effects of carbonization temperature ($700^{\circ}C$ to $1100^{\circ}C$) and chemical pre-treatment (NaOH and $NH_4Cl$) at various concentrations on the thermal change, chemical composition and fiber morphology of kenaf-based carbon fibers were investigated. Remarkable weight loss and longitudinal shrinkage were found to occur during the thermal conversion from kenaf precursor to kenaf-based carbon fiber, depending on the carbonization temperature. It was noted that the alkali pre-treatment of kenaf with NaOH played a role in reducing the weight loss and the longitudinal shrinkage and also in increasing the carbon content of kenaf-based carbon fibers. The number and size of the cells and the fiber diameter were reduced with increasing carbonization temperature. Morphological observations implied that the micrometer-sized cells were combined or fused and then re-organized with the neighboring cells during the carbonization process. By the pre-treatment of kenaf with 10 and 15 wt% NaOH solutions and the subsequent carbonization process, the inner cells completely disappeared through the transverse direction of the kenaf fiber, resulting in the fiber densification. It was noticeable that the alkali pre-treatment of the kenaf fibers prior to carbonization contributed to the forming of kenaf-based carbon fibers.

An Evaluation of Net-zero Contribution Regarding Hydrogen Energy Conversion in Urban Building and Transport Sector (도시의 건물 및 수송 부문에서의 수소에너지 전환에 따른 탄소중립 기여도 평가)

  • SO JEONG JANG;RAE SANG PARK;YOUNG HOON CHOI;YONG WOO HWANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.2
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    • pp.100-112
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    • 2023
  • This study evaluated the contribution of carbon neutrality by calculating the carbon reduction amount and reduction intensity targeting the hydrogen pilot city and applying it to the carbon neutral reduction target. In the building sector, the reduction amount for 2030 was 10.8% on average. In addition, by 2050, the contribution to carbon neutrality of plan A was 14.1% on average, and the contribution to carbon neutrality of plan B was 15.1% on average. In the 2030 reduction amount of the transportation sector, the contribution to carbon neutrality was 138.4% on average. In addition, by 2050, the contribution to carbon neutrality in plan A was 82.5% on average, and the contribution to carbon neutrality in plan B was 74.9%. From the above research results, additional carbon reduction is possible when creating a hydrogen city, so it will be used as a basis of city-level carbon neutral model. It will also be used as a basis for technology development and investment promotion for various hydrogen supply methods in the future.

Surface morphology modification of vertically-aligned carbon nanotubes by water vapor exposure

  • Adil, Hawsawi;Jeong, Goo-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.238.2-238.2
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    • 2015
  • Surface modification of vertically-aligned carbon nanotube (VACNT) is essential in order to meet specific demands for particular applications such as field emission displays, heat dissipation device and potential sun energy conversion due to their superior electrical and thermal conductivity and strong light absorption. In this study, we observe the effect of exposure to water vapor on a different lengths of the surfaces of VACNT. The study was conducted on three different lengths of the VACNT: short length around $200{\mu}m$, medium-length around $500{\mu}m$, and high length around 1 mm. Water exposure time ranges between 2-10 min and temperature of the water ranges from 60 to 120 oC. The result of water vapor exposure mainly show that increasing the exposure time and water temperature give rise to increase of the speed of change on the surface of the VACNT. Especially, the shorter VACNT change their surface morphology most rapidly.

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Improved Reduction of Carbon Monoxide by Highly Efficient Catalytic Shift for Fuel Cell Applications

  • Youn, M.J.;Chun, Y.N.
    • Environmental Engineering Research
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    • v.13 no.4
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    • pp.192-196
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    • 2008
  • The generation of high purity hydrogen from reformed hydrocarbon fuels, or syngas, is essential for efficient operation of the fuel cell (PEMFC, Polymer Electrolyte Membrane Fuel Cell). Usually, major components of reformed gas are $H_2$, CO, $CO_2$ and $H_2O$. Especially a major component, CO poisons the electrode of fuel cells. The water gas shifter (WGS) that shifts CO to $CO_2$ and simultaneously produces $H_2$, was developed to a two stage catalytic conversion process involving a high temperature shifter (HTS) and a low temperature shifter (LTS). Also, experiments were carried out to reduce the carbon monoxide up to $3{\sim}4%$ in the HTS and lower than 5,000 ppm via the LTS.

A Study on the Antimicrobial Effect of Natural Artemisia Extract using Super Critical Carbon Dioxide (초임계 이산화탄소를 이용한 쑥 추출물의 항균효과에 관한 연구)

  • Sung, Ki-Chun
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.4
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    • pp.309-315
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    • 2003
  • Extraction of Natural Artemisia by using super critical carbon dioxide is operated under $40-50^{\circ}C$ and 200-250 atm, thus, conversion rate is very low as 7wt% while high energy is being wasted. When Natural Artemisia Extract is applied in the control of microbe, concentration and reaction time greatly affected to the growth of microbe. Especially, when refined oil concentration from Natural Artemisia added more than 1,000ppm, staphylococcus aureus and fungi are terminated completely. Thus, it is proven that Natural Artemisia Extract has antimicrobial effect.

Measurement of Gas Concentration and flow Rate Using Hot Wire (열선을 이용한 혼합기체의 농도와 유량의 측정)

  • Kim, Young-Han;Park, Jong-Jueng
    • Journal of Institute of Control, Robotics and Systems
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    • v.8 no.5
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    • pp.407-412
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    • 2002
  • A measurement device for gas concentration and flow rate using hot wire is developed for the utilization in industrial applications. The device has two cells of measuring and reference, and a bridge circuit is installed to detect electric current through the hot wire in the cells. An amplification of the signal and conversion to digital output are conducted for the on-line measurement with a personal computer. The flow rate of air and carbon dioxide gas is separately measured for the performance examination of the device. Also, the concentration of air-carbon dioxide and carbon dioxide-argon mixtures is determined for the same evaluation. The outcome of the performance test indicates that the accuracy and stability of the device is satisfactory for the purpose of industrial applications.

Study on Characteristics of Change in Calorific Value and Carbon Emission Factor of Domestic Petroleum Energy Source (국내 석유계 에너지원의 열량 및 탄소배출계수 변화 특성 연구)

  • Doe, Jin-woo;Lim, Wan-gyu;Kang, Hyung-kyu;Hwang, In-ha;Ha, Jong-han;Na, Byung-ki
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.1046-1057
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    • 2017
  • Country-specific emission factors should be developed and used instead of IPCC defaults to improve national GHG inventories to Tier 2 and above. Since the country-specific emission factors depend on the type of energy source, energy process, and time trend, identifying the value of each energy source is an important part of building an accurate inventory. In this study, calorific value and carbon emission factor for petroleum energy sources on the basis of calorific value conversion standard for energy source, which are notified in Korea, are collected by 2013 and 2016, and calorific value, carbon content and carbon emission factor And a comparative analysis was conducted. In addition, net calorific values and carbon emission factors calculated for each petroleum based energy source are compared with those shown in 2006 IPCC Guideline.

The Effects of Sonic Waves on the Reduction of Aromatic Nitro Groups Using Iron, Hydrazine Hydrate and Activated Carbon (유기 초음파화학. 초음파가 히드라진, 철, 활성탄을 이용한 방향족 니트로기의 환원반응에 미치는 영향)

  • Dae Hyun Shin;Byung Hee Han;Sung Yun Cho
    • Journal of the Korean Chemical Society
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    • v.30 no.1
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    • pp.105-108
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    • 1986
  • Ultrasound(50KHz) accelerated the reduction reaction of aromatic nitro group to aromatic amino group in high yield with mild condition using iron, hydrazine hydrate and activated carbon under room temperature and atmospheric pressure. The activated carbon has been used as a mixing material to highly active metals. However, aromatic nitro group does not reduce at all only with iron-hydrazine witliout adding activated carbon even under ultrasonic irradiation. We also discovered that the conversion yield from nitro group to amino group is directly proportional to the amount of activated carbon.

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Effect of Nitrogen Compounds and Organic Carbon Concentrations on $N_2O$ Emission during Denitrification (탈질에서 질소성분 및 유기탄소 농도가 $N_2O$ 배출에 미치는 영향)

  • Kim, Dong-Jin;Kim, Heon-Ki;Kim, Yu-Ri
    • Clean Technology
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    • v.17 no.2
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    • pp.134-141
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    • 2011
  • The effects of the compounds and concentrations of nitrogenous electron acceptor, the ratio of electron donor/electron acceptor (C/N), and the complexity of electron donor on the emission of $N_2O$ during wastewater denitrification were quantitatively investigated in this study. The higher ${NO_3}^-$ and ${NO_2}^-$ concentrations, the more $N_2O$ emission was observed. ${NO_2}^-$ has strong effect on $N_2O$ emission as it emitted morc $N_2O$ than ${NO_3}^-$, 50 mg/L of ${NO_2}^-$-N gave the highest conversion (9.3%) and yield (9.8%) of $N_2O$ while ${NO_3}^-$-N (50 mg/L) gave 5.6% conversion and 11.0% yield. Lower C/N ratio decreases nitrogen removal efficiency, but it increases the conversion of $N_2O$ because of the incomplete denitrification by the limited organic carbon. When real domestic wastewater is used as the electron donor of the denitrification, $N_2O$ emission is reduced to 1/10 of the emission when single carbon (acetate) is used. It is thought that multiple carbon source utilizes many denitrification pathways and it seems to be helpful for the reduction of $N_2O$ emission.