• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.1996-2000
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• 2008

In autothermal reforming reaction, oxygen to carbon ratio (OCR) and steam to carbon ratio (SCR) are significant factors, which control temperature and carbon deposition into the reactor. The OCR is more sensitive than the SCR to affect the temperature distribution and reforming efficiency. In conventional operation, hydrocarbon fuel, steam, and oxygen was homogeneously mixed and injected into the reactor in order to get hydrogen-rich gas. The temperature was abruptly raised due to fast oxidation reaction in the former part of the reactor. Deactivation of packed catalysts can be accelerated there. In the present study, therefore, the effect of the oxygen distribution is introduced and investigated to suppress the carbon deposition and to maintain the reactor in the mild operating temperature (e.g., $700{\sim}800^{\circ}C$). In order to investigate the effect numerically, the following models are adopted; heterogeneous reaction model and two-medium model for heat balance.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2023년도 학술발표회
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• pp.447-447
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• 2023

Soil organic carbon (SOC) is a critical indicator of soil fertility. Its importance in maintaining ecological balance has received widespread attention. However, global temperatures have risen by 0.8℃ since the late 1800s due to human-induced greenhouse gas emissions, resulting in severe disruptions in SOC dynamics. To study the impacts of temperature variations on SOC and soil respiration, we used the Soil Carbon and Landscape co-Evolution (SCALE) model, which was capable of estimating the spatial distribution of soil carbon dynamics. The study site was located at Heshan Farm (125°20'10.5"E, 49°00'23.1"N), Nenjiang County in Heilongjiang Province, Northeast China. We validated the model using observed soil organic carbon and soil respiration in 2015 and achieved excellent agreement between observed and modeled variables. Our results showed considerable influences of temperature increases on SOC and soil respiration rates at both erosion and deposition areas. In particular, changes in SOC and soil respiration at the deposition area were greater than at the erosion area. Our study highlights that the impacts of temperature elevations are considerably dependent on soil erosion and deposition processes. Thus, it is important to implement effective soil conservation strategies to maintain soil fertility under global warming.

• 한국수소및신에너지학회논문집
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• 제20권3호
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• pp.245-255
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• 2009

Effect of CO$_2$ concentration on reduction reactivity of oxygen carrier particles for chemical-looping combustor were investigated. Four particles, NiO/bentonite, OCN601-650, OCN702-1100, OCN702-1250, were used as oxygen carrier particles and two kinds of gases (CH$_4$, 5%, N$_2$ balance and CH$_4$ 5%, CO$_2$ balance) were used as reactants for reduction. For all oxygen carrier particles, higher maximum conversion, reduction rate, oxygen transfer capacity, and oxygen transfer rate were achieved when we used N$_2$ balance gas. OCN601-650 particle showed higher oxygen transfer rate for all gases than other particles, and therefore we selected OCN601-650 particle as the best candidate. For all particles, lower carbon depositions were observed when we used CO$_2$ balance gas.

• 대기
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• 제33권1호
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• pp.61-72
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• 2023

Accurate estimation of forest carbon stocks is important in establishing greenhouse gas reduction plans. In this study, we estimate the spatial distribution of forest carbon stocks using machine learning techniques based on high-resolution remote sensing data and detailed field survey data. The high-resolution remote sensing data used in this study are Landsat indices (EVI, NDVI, NDII) for monitoring vegetation vitality and Shuttle Radar Topography Mission (SRTM) data for describing topography. We also used the forest growing stock data from the National Forest Inventory (NFI) for estimating forest biomass. Based on these data, we built a model based on machine learning methods and optimized for Korean forest types to calculate the forest carbon stocks per grid unit. With the newly developed estimation model, we created forest carbon stocks maps and estimated the forest carbon stocks in South Korea. As a result, forest carbon stock in South Korea was estimated to be 432,214,520 tC in 2020. Furthermore, we estimated the loss of forest carbon stocks due to the Donghae-Uljin forest fire in 2022 using the forest carbon stock map in this study. The surrounding forest destroyed around the fire area was estimated to be about 24,835 ha and the loss of forest carbon stocks was estimated to be 1,396,457 tC. Our model serves as a tool to estimate spatially distributed local forest carbon stocks and facilitates accounting of real-time changes in the carbon balance as well as managing the LULUCF part of greenhouse gas inventories.

• 신재생에너지
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• 제5권3호
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• pp.40-48
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• 2009

Recovered heat has been considered as a renewable energy in Europe since 2008 because its great effect on energy saving and carbon decreasing in plant process. Energy saving and decreasing green gas are critical issue today, so various technologies to save energy and decrease carbon dioxide in plant process have been applied to many industrial area. In this paper, the feasibility of condenser heat recovery by heat pump in power plant for district heating and fuel line preheating were reviewed by verifying energy (heat) balance and mass balance of power plant model. Some ways to compose proper system to recover heat of condenser are suggested and their possibilities are also reviewed. Limitations on heat recovery in power plant are also reviewed. The results are verified by calculating input/output energy based on actual performance test data of Taean Thermal Power Plant in Korea. There is noticeable improvement of plant performance in some cases which demand low temperature (<100 C) heat like distrcit heating, fuel line heating, and so forth.

• 한국대기환경학회지
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• 제22권1호
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• pp.43-51
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• 2006

Nonthermal plasma-driven catalysis (PDC) was investigated for the decomposition of benzene and toluene as model compounds of volatile organic compounds (VOCs) at atmospheric pressure and low temperature. Two types of catalysts Ag/$TiO_{2}$ and Pt/$\gamma-Al_{2}O_{3}$ were tested in this study. The amount of catalysts packed in the PDC reactor did not influence on the decomposition efficiency of benzene. The type of catalysts also had no influence on the decomposition efficiency of toluene and carbon balance. The Ag/$TiO_{2}$ catalyst showed constant $CO_{2}$ selectivity of about $73\%$ regardless of the specific input energy. However, the selectivity of $CO_{2}$ was greatly enhanced with the Pt/$\gamma-Al_{2}O_{3}$ catalysts, and reached $97\%$ at 205 J/L. Two test runs with 20 fold difference in the gas flow clearly indicated that lab-scale data can be successfully applied for the scaling-up of PDC system.

• 열처리공학회지
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• 제21권6호
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• pp.281-286
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• 2008

In the 1.1 Mn steel containing boron, effects of the 0.1 V addition and processing condition were studied. In the $550^{\circ}C$ interrupted cooling where the main structure is (ferrite + pearlite), the impact toughness decreased as the tensile strength increased by the 0.1 V addition. The $800^{\circ}C$ rolling including two step rolling of $800-770^{\circ}C$, exhibited better strength-toughness balance, as compared to the $770^{\circ}C$ rolling. This seems to be kind of conditioning effect at higher temperature, e.g., more uniform deformation effect. In the accelerated cooling after the $750^{\circ}C$ rolling in a dual phase range, the impact toughness was enhanced, despite a large increase in tensile strength. This is believed to be related to the change of main structure from (ferrite + pearlite) to (ferrite + bainite).

• 에너지공학
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• 제17권4호
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• pp.182-188
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• 2008

본 연구에서는 탄소 균형 및 1차식에 의한 공연비 산정방법을 대체연료에 적용하여 그 결과를 비교하였다. 이전의 연구에서는 Eltinge 차트의 확장, 미연탄화수소의 보상 및 다양한 방법으로부터 계산한 결과를 비교하였다. 또한 Eltinge 방법은 현재 공연비를 산정하는 방법 중 가장 일반적인 식이라는 것을 확인하였다. 그러나 최근 지구온난화 방지를 포함하여 환경 보호와 에너지보존에 대한 요구가 증가하면서 내연기관에 대체연료를 사용이 도입되기 시작하면서 이러한 대체연료들에 대한 공연비의 정확한 산정이 필요하게 되었다. 특히, 산소를 포함하는 연료에서는 Eltigne방법을 제외하고 모든 공연비 산정법들이 다시 유도되어야한다. 이 연구에서는 이미 그 정확성이 확인된 탄소균형식을 이용하여 대체연료의 공연비를 산정하기 위해 다시 유도하였고, 각 대체 연료에 실제로 적용이 가능한 1차식을 새로이 제시하였다. 평가 결과, 탄소균형식으로 계산한 공연비는 가솔린 연료와 비교하여 다소 오차가 증가하였지만, 그 정확도는 다양한 대체 연료들에 적용하기에 충분하다는 결론을 얻었다. 또한, 제시된 1차식은 $\lambda=1.2$이하에서는 그 정확도가 매우 높았다.

• Carbon letters
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• 제3권4호
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• pp.187-191
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• 2002

In the present research, we prepared the activated carbon (AC) sorbents to remove gas-phase mercury. The mercury adsorption of virgin AC, chemically treated AC and fly ash was performed. Sulfur impregnated and sulfuric acid impregnated ACs were used as the chemically treated ACs. A simulated flue gas was made of SOx, NOx and mercury vapor in nitrogen balance. A reduced mercury adsorption capacity was obtained with the simulated gas as compared with that containing only mercury vapor in nitrogen. With the simulated gas, the sulfuric acid treated AC showed the highest performance, but it might have the problem of corrosion due to the emission of sulfuric acid. It was also found that the high sulfur impregnated AC also released a portion of sulfur at $140^{\circ}C$. Thus, it was concluded that the low sulfur impregnated AC was suitable for the treatment of flue gas in terms of stability and efficiency.

• 한국재료학회지
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• 제14권2호
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• pp.157-162
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• 2004

The object of this research is to develop a carbon molecular sieve(below CMS) which can separate selectively to convert mixture gases spout at waste landfill into fuel. And this research is meaningful from the viewpoint of a quality improvement of CH$_4$ gas and an utilization of by-product. CMS was prepared using coconut shell powder as starting material and the effects of activators, temperature and modifier on the reaction were investigated in this research. Also, pore diameter, surface area of CMS and adsorption rate were measured and studied by cahn balance and ASAP2010. Its specific surface area and pore distribution were controlled easily at 800^{\circ}C and adsorption rate was very good. The CMS prepared in this research is shown to be able to separate landfill gases very effectively.