• Title/Summary/Keyword: Capillary Pressure

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Enhanced Migration of Gasohol Fuels in Clay Soils and Sediments (Gasoline-ethanol(Gasohol)혼합액의 점토층 내 이동에 대한 연구)

  • Hee-Chul Choi;W.M. Stallard;Kwang-Soo Kim;In-Soo Kim
    • Journal of Korea Soil Environment Society
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    • v.1 no.1
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    • pp.67-79
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    • 1996
  • Clay soils typically have low hydraulic conductivities in the presence of high polarity pore fluid, such as water. Low polarity fluids, such as hydrocarbon fuels and halogenated organic solvents, typically cannot migrate into clay pores because they cannot displace the pore water. Oxygenated additives in gasoline, such as alcohols and methyl-tert-butyl ether, are increasingly used to control air pollution emissions. These relatively polar and highly water-soluble compounds may facilitate displacement of pore water and enhance migration of fuels and solvents through clay-rich soil strata. In the reported research, the migration of gasoline-alcohol fuel mixtures (gasohol) through consolidated clay was examined. Prepared kaolinite clay samples were consolidated from slurry, and various combinations of gasoline, alcohol, and water were applied to the clays under 152 Pa gauge pressure. Movement of the fluids into the clay samples was monitored by measur ing displaced pore fluid and by magnetic resonance imaging of the samples. The structures of selected samples were examined using environmental scanning electron microscopy. Results of the research suggest that alcohol added to hydrocarbon fuels can enhance migration through some clays significantly. Gasoline did not migrate appreciably into water saturated clay, even after 14 days under pressure. The gasohol mixture migrated readily into the clay in only 20 minutes. Increased hydraulic conductivity of the clay in the presence of gasohol is hypothesized to be due to the collapse of the clays pore structure when ethanol is present, creating larger pores. Increasing pore diameter decreases the capillary pressure needed for the gasohol to replace water and allows gasohol to migrate through the clay.

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Characteristics of film-type crystal growth mechanism of CO2 hydrate (CO2 하이드레이트의 film형 결정성장 거동에 관한 연구)

  • Lee, Hyunju;Kim, Soomin;Lee, Ju-Dong;Kim, Yangdo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.2
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    • pp.93-100
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    • 2013
  • Many researches have been carried out to reduce and/or to capture the major global warming gases. Especially, the hydrate formation mechanisms were intensively investigated for carbon dioxide sequestration and storage process applications. In this study, the characteristics of film-type crystal growth mechanism of carbon dioxide hydrate were comprehensively examined. Carbon dioxide hydrate crystal was formed in semi-batch type stir reactor at various pressure conditions while the temperature was fixed to be constant to reduce and minimize the guest gas solubility effects. A supply gas composition was 99.999 % of Carbon dioxide, the observation data was collected by optical microscope adopted CCD camera (Nikon DS-5M/Fi1/2M-U2). This study revealed that the guest gas pressure changes significantly altered the crystal growth mechanism and film growth rate of carbon dioxide hydrate crystal. The critical pressure of the carbon dioxide hydrate of crystal growth mechanism change was found to be 2.0 MPa. The capillary force and gas concentration gradient also significantly changed the film-type crystal growth mechanism of carbon dioxide hydrate crystal.

A Thermo-Hydro-Mechanical Coupled Numerical Simulation on the FE Experiment: Step 1 Simulation in Task C of DECOVALEX-2023 (Mont Terri FE 실험 대상 열-수리-역학 복합거동 수치해석: DECOVALEX-2023 Task C 내 Step 1 수치해석 연구)

  • Taehyun, Kim;Chan-Hee, Park;Changsoo, Lee;Jin-Seop, Kim
    • Tunnel and Underground Space
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    • v.32 no.6
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    • pp.518-529
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    • 2022
  • In Task C of the DECOVALEX-2023 project, nine institutes from six nations are developing their numerical codes to simulate thermo-hydro-mechanical coupled behavior for the FE experiment performed at Mont Terri underground rock laboratory, Switzerland. Currently, Step 1 for comparing the simulation results to field data is the ongoing stage, and we used the OGS-FLAC simulator for a series of numerical simulations. As a result, temperature increase depending on the heating hysteresis was well simulated, and saturation variation in the bentonite depending on phase change was observed. However, due to the suction overestimation, relative humidity and temperature change in the bentonite and the pressure variation in the Opalinus clay showed a difference compared to the field data. From the observation, it is confirmed that the effect of the bentonite capillary pressure is dominant to the flow analysis in the disposal system. We further plan to draw improved results considering tunnel support material and accurate initial water pressure distribution. Additionally, the thermal, hydrological, and mechanical anisotropy of the Opalinus clay was well simulated. From the simulation results, we confirmed the applicability of the OGS-FLAC simulator in the disposal system analysis.

Performance Evaluation of Propane(R290)/Isobutane(R600a) Mixture as a Substitute for CFC12 in Domestic Refrigerators (프로판/이소부탄 혼합냉매를 적용한 가정용 냉장고의 성능에 관한 연구)

  • Lim, B.H.;Park, Y.B.;Yoo, H.K.;Jung, D.S.;Kim, C.B.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.2
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    • pp.249-265
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    • 1995
  • The performance of a refrigerant mixture of propane(R290)/isobutane(R600a) as a substitute for CFC12 was investigated in a domestic refrigerator with single evaporator. A thermodynamic cycle simulation indicated an increase in COP of a 1.7 to 2.4% with R-290/600a in the composition range of 0.2 to 0.6 mass fraction of R290 compared to CFC12. For the tests, two units($299{\ell}$, $465{\ell}$) were used. All refrigeration components remained the same throughout the tests, except that the length of capillary tube and amount of charge were changed for the mixture. The refrigerators were fully instrumented with more than 20 thermocouples, 2 pressure transducers, and watt/watt-hour meter for each refrigerator. 'Energy consumption test' and 'no load pulldown test' were performed under the same condition. The experimental results obtained with the same compressor indicated that R-290/600a mixture at 0.6 mass fraction of R290 showed a 3 to 5% increase in energy efficiency and a faster cooling speed compared to CFC12. The R-290/600a mixture showed a shorter compressor on-time and a lower compressor dome temperature than CFC12. In conclusion, the proposed hydrocarbon mixture seems to be an appropriate candidate to replace CFC12 without causing more environmental problems.

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Action of atmospheric pressure non-thermal plasma on the biomolecules and bio-organism

  • Attri, Pankaj;Park, Ji Hoon;Kumar, Naresh;Ali, Anser;Kim, In Tae;Lee, Weontae;Choi, Eun Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.66.1-66.1
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    • 2015
  • Plasma medicine is an upcoming research area that has attracted the scientists to explore more deeply the utility of plasma. So, apart from the treating biomaterials and tissues with plasma, we have studied the effect of plasma with different feeding gases on modification of biomolecules. Additionally, we have checked the action of nanosecond pulsed plasma on the biomolecules. We have checked the plasma action on proteins ((Hemoglobin (Hb) Myoglobin (Mb) and lysoenzyme), calf thymus DNA and amino acids. The structural changes or structural modification of proteins and DNA have been studied using circular dichroism (CD), dynamic light scattering (DLS), gel electrophoresis, protein oxidation test, UV-vis spectroscopy and 1D NMR, while Liquid Chromatograph/Capillary Electrophoresis-Mass Spectrometer(LC/CE-MS) based qualitative bio-analysis have been used to study the modification of amino acids. We have also shown the effect of NaCl and ionic liquid on the formation of OH radicals using electron spin resonance and fluorescence techinques.

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First-Pass Observation using Tailored-RF Gradient Echo (TRFGE) MR Imaging in Cat Brain (자기공명 Tailored-RF 경사자계반향영상법을 이용한 고양이 뇌에서의 First-Pass관찰)

  • 문치웅;노용만
    • Journal of Biomedical Engineering Research
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    • v.16 no.2
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    • pp.209-216
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    • 1995
  • Recently, a new tailored RF gradient echo (TRFGE) sequence was reported. This technique not only enhances the magnetic susceptibility effect but also allows us to measure local changes in brain oxygenation. In this study, a phantom and cat brain experiments were performed on a 4.7 Tesla BIQSPEC (BRUKER) instrument with a 26 cm gradient system. We have demonstrated that the signal intensity (SI) of the TRFGE sequence varies according to the concentration of susceptibility contrast agent. Three capillary tubes with different concentrations of Gd-DTPA (0.01, 0.05, 0.1 mMOI/l) were placed at the middle of a cylindrical water phantom. Using both TRFGE and conventional gradient echo (CGE) sequences, phantom images of the slices which contain all three tubes were obtained. For the animal experiment, cats were anesthetized and ventilated using halotane (0.5%) and a $N_2O/ O_2$ mixture (2:1), and blood pressure and heart rate were monitored and kept normal. For the observation of tue first pass of Gd- DTPA, imaging was started at t = 0. At t = 8 ~ 12s, 0.2 mMol/Kg Gd-DTPA was manually injected in the femoral vein. The imaging parameters were TRITE = 25/10 msec, flip angle = $30^{\circ}$, FOV = 10cm, image matrix size = $128{\times}128$ with 64 phase encodings and the image data acquisition window was 10 msec. SI-time curves were then obtained from a series of 30 images which were collected at 2 sec intervals using both CGE and TRFGE pulse sequences before, during, and following the contrast injection.

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Use of an Imaging Technology for Characterizing Core-scale Multiphase Flow: Application to CO2 Geological Storage (이미징기술을 활용한 코어규모의 다상유체 유동 특성화: 이산화탄소 지중저장 연구에의 적용)

  • Kim, Kue-Young
    • The Journal of Engineering Geology
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    • v.28 no.1
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    • pp.35-45
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    • 2018
  • Imaging technologies are applied at various geological scales including pore scale, core scale and intermediate scale in order to characterize pore space of rocks as well as to map the fluid distribution in porous media. This technical report presents experimental results using core-flooding apparatus suited with imaging technology. Three different core samples, that are homogeneous, fractured and heterogeneous cores, were used to assess the two-phase fluid migration behavior as $CO_2$ displaces resident brine. We show that imaging technology can be effective in characterizing salt-precipitation, capillary pressure and spatio-temporal variation of trapping mechanisms.

The Effect of Kamijaeumganghwatang(KJI) on Hypertension (가미자음강화탕(加味滋陰降火湯)이 SHR의 혈압에 미치는 영향)

  • Baek, Kyung-Min;Jo, Hyun-Kyung;Yoo, Ho-Rhyong;Kim, Yoon-Sik;Seol, In-Chan
    • The Journal of Internal Korean Medicine
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    • v.27 no.1
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    • pp.1-15
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    • 2006
  • Objective : This study was done to investigate the effect of KJT on hypertension. Methods : Spontaneous Hypertensive Rats were sensitized and challenged with Kamijaeumganghwatang(KJT) for 5 weeks. Experimental group was treated with $200mg/day/2m{\ell}$ of KJT orally and control group was treated with $2m{\ell}/day$ of normal saline instead. Results : 1. KJT significantly showed significant protection against cytotoxicity and toxicity in the liver and the kidney. 2. KJT significantly decreased the blood pressure in SHR. 3. KJT significantly decreased the levels of aldosterone in SHR. 4. KJT significantly decreased the levels of dopamine, norepinephrine and epinephrine in SHR. 5. KJT significantly decreased the levels of sodium and potassium in SHR, but it did not decrease the levels of chloride in SHR. Levels of calcium in SHR increased, but only insignificantly. 6. KJT significantly decreased the levels of IL-6 in SHR, and significantly increased the levels of IL-10 in SHR. 7. For histological effects, KJT dillated capillary vessels in the kidney, significantly decreased eosinophilic changes in heart cells, and significantly decreased endothelial damage in the aorta. Conclusion: These results suggest that KJT is useful in treatment of hypertension.

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Left Atrial Thrombi in Patients With Mitral Stenosis (Risk Factors Related to left Atrial Thrombosis) (승모판협착증 환자의 좌심방혈전)

  • Kim, Kwang-Ho;Hong, Sung-Nok
    • Journal of Chest Surgery
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    • v.15 no.2
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    • pp.204-212
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    • 1982
  • The presence of left atrial thrombus in mitral stenosis has been reported to be associated with several factors. These are age, sex, presence of atrial fibrillation, episodes of congestave heart failure, calcification of mitral valve, embolic episode, etc. Since none of these single factor has been always related to the presence of left atrial thrombus, related risk factors to left atrial thrombosis were studied in patients with mitral stenosis using chi square test. We had operated on 191 cases of mitral valvular heart disease from Jan. 1978 to June 1981 at Severance Hospital, Yunsei University College of Medicine. The left atrial thrombi were present in 41 cases among 191 cases of mitral valvular heart disease and it was present in 31 cases among 89 cases of pure mitral stenosis. Only 10 cases among 74 cases of mitral stenoregurgitation had left atrlal thrombi, whereas no left atrlal thrombus was found in patients with pure mitral regurgitation. Related risk factors studied herein were sex, episodes of congestive heart failure, atrial fibrillation, pulmonary capillary wedge pressure, mitral valve area calculated by Gorlin and Gorlin`s formula cardiac output and left atrial dimension by echocardiogram. In this study presence of atrial fibrillation was deemed to be one of the most potential risk factors and other factors of age, duration of symptoms, episode of embolization, calclfication of mitral valve, associated aortic and tricuspid valve disease, ejection fraction of left ventricle by cineangiocardiogram and echocardiogram were not significantly related to the presence of left atrlal thrombi in a statistical viewpoint.

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Development of Alkoxysilane Mixed Solution as Stone Preservation and Consolidation Materials (알콕시 실란계 석재 보존 및 강화제 개발)

  • Kim, Eun-Kyung;Park, Seong-Yong;Cho, Hyun-Dong;Won, Jong-Ok;Do, Jin-Young;Kim, Sa-Dug
    • Journal of Conservation Science
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    • v.21
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    • pp.21-32
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    • 2007
  • Low-viscosity alkoxysilanes that polymerize into the porous network of decayed stone by a sol-gel process are widely used as stone consolidants. During drying, the gel network contracts due to capillary pressure generated by solvent evaporation. We have prepared tetraethoxysilane mixed solution containing methyltrisilane, ethyl trisilane and (3-glycidyloxypropyl)trimethoxysilane having epoxy ring in order to reduce the shrinkage happened inside the stone porous structure during the gel formation. Mixed solutions were applied into sandstone and granites and characterized by FT-IR, SEM. The gelation time, water uptake, contact angles were measured and compared with those of the commercial stone conservation materials.

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