• Title/Summary/Keyword: Capacity retention rate

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Study on the Factor of Water Retention Capacity of Cement Mortar by Hydroxyalkyl Methylcellulose Ether (히드록시알킬 메틸셀룰로오스가 시멘트 모르타르의 보수성에 미치는 영향에 관한 연구)

  • 이무진
    • Journal of the Korea Concrete Institute
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    • v.11 no.3
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    • pp.153-160
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    • 1999
  • Water soluble hydroxyalkyl methycellulose ethers are used in a variety of applications incluing building industry as a supplementary agent used for incresing adhesives, water retention capacity, workability and viscosity modify. Water retention capacity(WRC) is the capability to contain water in the ploymer chain under condition of being mixed with cement. In general, the WRC is affected by the viscosity, the adding amount, the particle size, the rate of dissolving and the amount of substituted chemical in cellulose ethers. In the other words, WRC is increased as higher the viscosity, more adding amount, finer the particle size and longer the dissolving time of cellulose ethers. This thesis investigated each factor that effect the WRC, particularly the relation between degree of substitution(DS), molar of substitution(MS) and WRC. It is observed that WRC is not nearly affected by DS of cellulose ethers, but is changes proportionally as MS increases in the narrow range(0.10~2.25)

Dispersion of Li[Ni0.2Li0.2Mn0.6]O2 Powder by Surfactant for High-power Li-ion Cell

  • Yun, Su-Hyun;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1598-1602
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    • 2009
  • The particle size of Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode powder was controlled effectively by dispersion using lauric acid as a surfactant. The samples treated by lauric acid showed smaller particles of approximately half the original size compared to the particles of a pristine sample. A structural change due to the dispersion of Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ powder was not detected. The rate performance of the Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode was improved by dispersion using lauric acid, which was likely due to the decrease of the particle size. In particular, a sample dispersed pristine powder using lauric acid (L2) presented a greatly enhanced discharge capacity and capacity retention at a high C rate. The discharge capacity of a pristine sample was only 133 m$Ahg^{-1}$ (3C rate) and 96 m$Ahg^{-1}$ (12C rate) at the tenth cycle. In contrast, the L2 electrode delivered higher discharge capacities of 160 m$Ahg^{-1}$ (3C rate) and 129 m$Ahg^{-1}$ (12C rate) at the tenth cycle. The capacity retention at a rate of 12C/2C was also enhanced from ~ 45% (pristine sample) to 57% (L2) by treatment with lauric acid.

Effects of Compost and Gypsum on Soil Water Movement and Retention of a Reclaimed Tidal Land

  • Lee, Jeong-Eun;Yun, Seok-In
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.5
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    • pp.340-344
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    • 2014
  • Compost and gypsum can be used to ameliorate soil physicochemical properties in reclaimed tidal lands as an organic and inorganic amendment, respectively. To evaluate effects of compost and gypsum on soil water movement and retention as a soil physical property, we measured the soil's saturated hydraulic conductivity and field capacity after treating the soil collected in a reclaimed tidal land with compost and gypsum. Saturated hydraulic conductivity of soil increased when compost was applied at the conventional application rate of $30Mg\;ha^{-1}$. However, the further application of compost insignificantly (P > 0.05) increased saturated hydraulic conductivity. On the other hand, additional gypsum application significantly increased soil saturated hydraulic conductivity while it decreased soil field capacity, implying the possible effect of gypsum on flocculating soil colloidal particles. The results in this study suggested that compost and gypsum can be used to improve hydrological properties of reclaimed tidal lands through increasing soil water retention and movement, respectively.

Electrochemical Performance of Graphite/Silicon/Carbon Composites as Anode Materials for Lithium-ion Batteries (리튬이온배터리 Graphite/Silicon/Carbon 복합 음극소재의 전기화학적 성능)

  • Jo, Yoon Ji;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.320-326
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    • 2018
  • In this study, Graphite/Silicon/Carbon (G/Si/C) composites were synthesized to improve the electrochemical properties of Graphite as an anode material of lithium ion battery. The prepared G/Si/C composites were analyzed by XRD, TGA and SEM. Also the electrochemical performances of G/Si/C composites as the anode were performed by constant current charge/discharge, rate performance, cyclic voltammetry and impedance tests in the electrolyte of $LiPF_6$ dissolved inorganic solvents (EC:DMC:EMC=1:1:1 vol%). Lithium ion battery using G/Si/C electrode showed better characteristics than graphite electrode. It was confirmed that as the silicon content increased, the capacity increased but the capacity retention ratio decreased. Also, it was shown that both the capacity and the rate performances were improved when using the Silicon (${\leq}25{\mu}m$). It is found that in the case of 10 wt% of Silicon (${\leq}25{\mu}m$), G/Si/C composites have the initial discharge capacity of 495 mAh/g, the capacity retention ratio of 89% and the retention rate capability of 80% in 2 C/0.1 C.

A Determination Method of a Rainwater Retention-Pumping System Combination for Runoff Control from Building Roof Area (지붕면 유출제어를 위한 빗물의 저장-펌프 시스템 조합 결정방안)

  • Kim, Young-Jin;Han, Moo-Young
    • Proceedings of the Korea Water Resources Association Conference
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    • 2008.05a
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    • pp.495-499
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    • 2008
  • This study developed a determination method for a rainwater retention-pumping combination system for roof runoff control. The outflow and stored water volume in the rainwater system was simulated using a water balance equation. Its result is presented in the TPP (Tank capcity-Peak outflow-Pumping rate) curves for rainfall return periods. In a case study on reduction of the peak flow rate of 100-year return period to 5-year in Seoul, The range of pumping rate for $100m^2$ roof area is determined as $0{\sim}25{\ell}$/min. Additionally, retention volume of $8.5{\sim}10m^3$ can be combined with the pumping rate range. That is to say an effective combination of a retention-pumping system capacity can be determined from a system of $8.5m^3$ tank with $25{\ell}$/min to $10m^3$ tank without pump. Using the TPP curves, engineers can determine the effective combination range of retention & pumping system capacity. Furthermore, that can be helpful to decide a detail system capacity for field condition.

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Potential Water Retention Capacity as a Factor in Silage Effluent Control: Experiments with High Moisture By-product Feedstuffs

  • Razak, Okine Abdul;Masaaki, Hanada;Yimamu, Aibibula;Meiji, Okamoto
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.4
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    • pp.471-478
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    • 2012
  • The role of moisture absorptive capacity of pre-silage material and its relationship with silage effluent in high moisture by-product feedstuffs (HMBF) is assessed. The term water retention capacity which is sometimes used in explaining the rate of effluent control in ensilage may be inadequate, since it accounts exclusively for the capacity of an absorbent incorporated into a pre-silage material prior to ensiling, without consideration to how much the pre-silage material can release. A new terminology, 'potential water retention capacity' (PWRC), which attempts to address this shortcoming, is proposed. Data were pooled from a series of experiments conducted separately over a period of five years using laboratory silos with four categories of agro by-products (n = 27) with differing moisture contents (highest 96.9%, lowest 78.1% in fresh matter, respectively), and their silages (n = 81). These were from a vegetable source (Daikon, Raphanus sativus), a root tuber source (potato pulp), a fruit source (apple pomace) and a cereal source (brewer's grain), respectively. The pre-silage materials were adjusted with dry in-silo absorbents consisting wheat straw, wheat or rice bran, beet pulp and bean stalks. The pooled mean for the moisture contents of all pre-silage materials was 78.3% (${\pm}10.3$). Silage effluent decreased (p<0.01), with increase in PWRC of pre-silage material. The theoretical moisture content and PWRC of pre-silage material necessary to stem effluent flow completely in HMBF silage was 69.1% and 82.9 g/100 g in fresh matter, respectively. The high correlation (r = 0.76) between PWRC of ensiled material and silage effluent indicated that the latter is an important factor in silage-effluent relationship.

Analysis of Water Retention Capacity at Sasa borealis Stands in Jirisan National Park (지리산국립공원 내 조릿대 임분의 수원함양기능 분석)

  • Ji, Hyung Woo;Park, Jae Hyeon
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.11 no.3
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    • pp.1-11
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    • 2008
  • Although landslides were frequently occurred under Tripterygium regelii and Rubus sp. vegetations, the damage of landslide was not observed in sasa (Sasa borealis) stands. These phenomena may be affected by forest vegetation types. This result suggested that the landslide occurred in Jirisan (Mt.) National Park may be closely related to water retention capacity at Sasa borealis stands. This study compared and analyzed the water retention capacity of each soil horizon of sasa, larch (Larix leptolepis) and mongolian oak (Quercus mongorica) stands. Soil bulk density in A horizon was lower in sasa (0.776g/$cm^3$) than in mongolian oak (0.828g/$cm^3$) and in larch stands (1.282g/$cm^3$). Water permeability in A horizon was 0.02055cm/sec for sasa, 0.00575cm/sec for mongolian oak, and 0.0007cm/sec for larch stands, respectively. The water permeability of sasa stand was about 3.6 times and about 29 times higher than in mongolian oak and in larch stands, respectively. This result indicates that water infiltration of soil surface during a rain event is more rapid in sasa than in other two stands. Soil organic matter content in B horizon was lower in larch (0.7%) than in mongolian oak (6.5%) and in Sasa (3.3%) stands. The solid ratio in A horizon was highest in larch among three stands, but that of mongolian oak and larch stands showed a similar rate. Pore space rates was 70.7% for A horizon and 70.6% for B horizon of sasa, 68.9% for A horizon and 70.6% for B horizon of sasa, 68.9% for A horizon and 70.6% for B horizon of mongolian oak forests and 51.7% for A horizon and 49.2% for B horizon of larch forests, respectively. According to pore space rates, the water retention capacity may be poor in larch stand compared with other two stands. Soil strength in sasa and mongolian stands was over 25kgf/$cm^2$ from 40cm depth, while the strength was over 25kgf/$cm^2$ from 25cm depth in larch stand. The result indicates that tree growth and water permeability in larch stand could be limited due to high soil strength. Larch stand was poor for soil pore space development to be offered to the water retention capacity, but water retention capacity of A horizon soil in sasa stand was high than that of other two stands. Therefore, establishment of sasa stand under larch stand could help to prevent landslides.

The Electrochemical Properties of Sponge Type S@ZIF67/rGO as the Cathode Material for Lithium Sulfur Batteries (리튬 황 전지용 Sponge 형태의 S@ZIF 67/rGO 양극재의 전기화학 특성 분석)

  • Chaelin Seo;Sunghoon Kim;Wook Ahn
    • Journal of the Korean Electrochemical Society
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    • v.27 no.1
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    • pp.47-54
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    • 2024
  • In this study, ZIF67/rGO was used to minimize the battery life degradation due to the insulating properties of sulfur and the elution of lithium polysulfide. ZIF67 wrapped in rGO creates more space within the carbon sponge and can hold a large amount of sulfur. The sulfur@ZIF67/rGO composite was synthesized and prepared as a sponge to enhance the sulfur retention capacity. The result showed a high initial capacity, with a value of about 1093 mAh g-1 and a capacity retention rate of 84% after 100 cycles. The high interaction with sulfur through the complexation of cobalt and carbon confirmed that ZIF67/rGO exhibits high performance as a carrier for sulfur, the anode active material of lithium-sulfur batteries, and the high initial capacity and improved capacity retention rate were confirmed.

Electrochemical Performance of PFO Pitch coated Natural Graphite using Dry Speed Mixer (건식 스피드 믹서를 이용한 PFO 피치 코팅 천연 흑연의 전기화학적 성능)

  • Youn, Jae Woong;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.410-416
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    • 2021
  • To improve the capacity and stability of natural graphite, the electrochemical performances were investigated by using the prepared natural graphite coated with petroleum pitch for anode materials. The pitch coated natural graphite was prepared using a dry speed mixer by adjusting the rotation speed of the mixer, time, composition of graphite and softening point of the pitch. The physical properties of the anode material were analyzed using SEM, TEM, and PSD. The electrochemical performances were investigated by cycle, C-rate, EIS and CV test. When the pitch coated natural graphite was tested in the condition of 9000 RPM, 10 wt%, 2 h, and softening point of 150 ℃, it showed the highest capacity of 324.5 mAh/g at 0.1 C and a capacity retention rate of 98.9% after 50 cycles. In the test for evaluating rate performance, the capacity retention rate (5 C/0.1 C) was 80.3% and was improved by about 1.7 times over the pristine natural graphite.

Development of a New Process for PVA Degradation in Desize Wastewater by lmmobilized Symbiotic Bacteria (고정화 공생 Bacteria를 이용한 호발폐수 중 PVA분해 신공정 개발)

  • 김정목;조무환조윤래정선용
    • KSBB Journal
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    • v.6 no.4
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    • pp.395-402
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    • 1991
  • A new process was developed to degrade PVA(polyvinyl alcohol) in desize wastewater. Two symbiotic bacteria of Pseudomonas strain G5Y and PW were immobilized on the media by adsorption. A natural zeolite was chosen as the best media considering cell adhesion capacity, sedimentation rate, and material cost. PVA and COD removal efficiencies of this system for synthetic wastewater were 84% and 85% at the retention time of 6 hr, when the volumetric loading rate was PVA 8g/L·day and COD 8g/L·day, and cell density was 19,775 mg/L. In case of desire wastewater, they were 78% and 72% at the retention time of 6 hr, respectively, when the volumetric loading rate was PVA 8g/L·day and COD 13.2g/L·day, and cell density was 32,899mg/L. In case of desize wastewater, PVA and COD removal efficiencies were lower than synthetic wastewater, but cell density of the desize wastewater was lower than that of the synthetic wastewater, because there were insufficiency of necessary nutrition and variety of desize materials in the desize wastewater. A pilot test was successfully performed showing 88% and 82%, PVA and COD removal efficiencies at the retention time of 24 hr, when volumetric loading rate were 4.7 PVA g/L·day and COD 6.9g/L·day, and cell density was 12,,324 mg/L.

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