• Journal of Environmental Health Sciences
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• v.13 no.1
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• pp.17-33
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• 1987

As a result of technical advances and industrialization, the characteristics of domestic and industrial wastes are becoming more complex. Accordingly, improved treatment and disposal systems are being continuously sought to take account of complex characteristics and to comply with economic restrictions. In this study, an application of pyrolysis to the treatment of industrial wastes, including waste scrap rubber, waste raw material used in making the slipper bottom and waste PVC pipe, and the effectiveness of pyrolysis in resource recovery from these wastes were investigated. Batches of wastes were pyrolysed by external heating to a temperature of 400-800$\circ$C in a 32 mm diameter x 0.9 m long silica tube to produce combustible gases, oils and chars. Before the start of pyrolysis runs, the entire system was purged with nitrogen gas to exclude the air. The temperature inside the retort was controlled by the thermocouple in the gas stream, and referred to as the pyrolysis temperature. Under these conditions three products were separately collected and further analyzed. The results were summarized as follows. 1. More gases and less chars were produced with higher pyrolyzing temperature and with higher rates of heating, but the yields of oils tended downwards at temperatures above 700$\circ$C. Accordingly, operating conditions of pyrolysis should be varied with desired material. 2. Calorific values and sulfur contents of produced oils were sufficient and suitable for fuel use. Chars from waste rubber had high heating values with low sulfur contents, but calorific values of chars from waste PVC and waste slipper were as low as 3, 065-4, 273 kcal/kg and 942-2, 545 kcal/kg, respectively. Therefore, char from these wastes are inappropriate for fuel. 3. Soluble contents of Pb, Cd, Cu and Zn in chars from waste rubber and waste slipper were below the Specific Hazardous Waste Treatment Standards. However soluble contents of Pb and Cd in chars from waste PVC were one or two times and five or seven times exceedingly the Specific Hazardous Waste Treatment Standards, respectively. 4. Post high heating is desirable for treatment method of waste PVC which generates toxic hydrogen chloride. 5. The proportions of hydrogen, methane and ethane in produced gases were in the range of 3.99-35.61% V/V, 18.22-32.50% V/V and 5.17-5.87% V/V, respectively. 6. Pyrolysis is a useful disposal method in case of waste slipper, which was hardly combustible, and thus investigations of this kind of materials are required for effective management of industrial waste. 7. Based upon the possible market development for products, overall pyroly economics to take account of treatment values of noncombustible or hazardous materials should be evaluated.

• Korean Journal of Soil Science and Fertilizer
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• v.46 no.5
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• pp.343-350
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• 2013

The objectives of this study were to estimate the potential biomass yield by using the biomass conversion index and evaluate the potential energy production by using the energy conversion index of biomass. Estimating the total biomass yield in Korea showed 9,646.3 thousand tons produced in 2012. Subsequent evaluation of the potential energy production using the estimated biomass yield in 2012 indicated that the calorific values were varied from 3,800 to 4,500 kcal $kg^{-1}$ for crop- and from 4,100 to 4,300 kcal $kg^{-1}$ for woody-based biomass, respectively. Among the examined biomass materials, the pruned branch of a nut tree appeared to be the greatest in bio-energy production showing 6,300 kcal $kg^{-1}$ in calorific value. Total potential energy production from agricultural by-products was estimated approximately at 3,966,000 TOE. Among the agricultural by-products examined, rice straw showed the greatest energy production potential being at 2,321,000 TOE. Furthermore, it might contribute to establishing the countermeasures of biomass utility in agricultural sector based on regional distribution chart of the potential biomass and energy yields in Korea.

• Korean Chemical Engineering Research
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• v.56 no.4
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• pp.547-554
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• 2018

Torrefaction is the promising process of pretreating biomass materials to increase the quality of their energy, especially to upgrade the materials' grindability so that it is suitable for a commercial pulverizer machine. In this study, torrefaction of oak, bamboo, oil palm trunk, and rice husk was carried out under different torrefaction temperatures ($300^{\circ}C$, $330^{\circ}C$, and $350^{\circ}C$) and different torrefaction residence times (30, 45, and 60 minutes). Complete characterization of the torrefied biomass, including proximate analysis, calorific value, thermogravimetric analysis, mass yield, energy yield, and grindability properties (Hardgrove Grindability Index) was carried out. Increasing the torrefaction temperature and residence time significantly improved the calorific value, energy density (by reducing the product mass), and grindability of the product. Furthermore, for commercial purposes, the torrefaction conditions that produced the desired grindability properties of the torrefied product were $330^{\circ}C-30minutes$ and $300^{\circ}-45minutes$, and the latter condition produced a higher energy yield for bamboo, oil palm trunk, and rice husk; however, torrefaction of oak did not achieve the targeted grindability property values.

• Journal of Biosystems Engineering
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• v.35 no.1
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• pp.64-68
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• 2010

Cattle feedlot manure could be used effectively as the solid fuel for heating of agricultural facilities. Therefore, this study was carried out to investigate the thermal and physicochemical characteristics of solid fuel extruded with cattle feedlot manure. Calorific values of the solid fuel extruded with cattle feedlot manure, which was dried to the moisture contents of 0.0% (w.b) and 35.0% (w.b,) were 14,906 kJ/kg and 11,797 kJ/kg, respectively. Calorific value of extruded solid fuel was linearly decreased with the increase of moisture content. The first, second, and third reaction point during thermal pyrolysis of solid fuels extruded with cattle feedlot manure was investigated as $108.1^{\circ}C$, $312.2^{\circ}C$, and $459.4^{\circ}C$, respectively. The maximum reaction point was presented at the temperature of $312.2^{\circ}C$. Weight loss of extruded cattle feedlot manure during thermal pyrolysis until $600^{\circ}C$ was reached to about 60%. Volume decrease of initial extruded cattle feedlot manure was 61% during drying for the use as solid fuel. Maximum strength of extruded cattle feedlot manure, which was dried as the moisture content of 10% (w.b.) was 41,9150 N/$m^2$. Ignition gas analysis of extruded cattle feedlot manure presented that it has small amount of $NO_x$ and $SO_x$. It was shown that dried cattle feedlot manure had main components of C and O including small amount of Mg, Si, and Ca.

• Journal of the Korea Organic Resources Recycling Association
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• v.18 no.4
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• pp.54-63
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• 2010

When MBT(Mechanical Biological Treatment) facility is designed, the management system adequate for domestic circumstance in Korea has been insufficient and power plant's load on seasonal variation has not been resolved yet. Thus, this study introduced MBT facility and MSW(Municipal Solid Waste)'s seasonal emission characteristics were investigated in order to establish new MBT management system. and additional thermal buffer-materials's calorific values were also considered to reduce the power plant's load. The results showed that the screening efficiency of MBT facility and the physical characteristics of each waste can be identified, and the calorific value by seasonal variation for MBT facility can be kept constant all the year round by using an additional thermal buffer-materials.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.2
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• pp.107-116
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• 1998

Coal gasification fuel has generally a lower calorific values than natural gas and also contains ammonia which is a main source of fuel NOx. Such a fuel is in need of the advanced technologies for the NOx reduction with higher combustion efficiency. Therefore fuel staged combustion was investigated for the fuel NOx control using a bench scale gas combustoi for the fuel NOx control. Parametric screening studies were performed with the variation of air ratio, retention length and reburning fuel. The NOx reduction efficiency was increased with an increase of total air ratio having optimum reburning air ratio differently, The Increased retention length of the reburning zone was preferable for NOx reduction. Hydrocarbonic reburning fuels like propane and butane were more effective for the NOx reduction efficiency than hydrogen fuel. The NOx concentration at exit was linearly increased according to the fuel-N the fuel.

• Particle and aerosol research
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• v.9 no.3
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• pp.173-185
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• 2013

Oxidations of metal generate large quantity of thermal and light energies but no toxic pollutants, so that metals with high calorific values, such as beryllium, boron, aluminum, magnesium, and lithium, are possible to be used as clean fuels instead of fossil fuels. However, they are so explosive due to very high oxidation rates that they should be stabilized by their surface passivation with oxides, organics and inorganics. For reasonable use of energetic metal particles as solid fuel, therefore, some detail information, such as thermal properties, preparation and passivation methods, and application area, of the energetic metals is introduced in this manuscript.

• Asian-Australasian Journal of Animal Sciences
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• v.5 no.1
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• pp.75-79
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• 1992

Fourteen Sahiwal ${\times}$ Friesian crossbred heifers were used in a 10-wk feeding trial to determine maintenance energy requirements and efficiency of gain. The heifers were individually fed with a diet consisting of 30% dry grass and 70% concentrates at either 110, 140 or 180% of the anticipated maintenance requirement ($494kJ\;ME/kg^{0.75}/day$). Liveweight of individual heifers was measured weekly to calculate diet requirements and average daily gain (ADG). Diet digestibility was determined for all heifers to determine ME intake. Retained energy (RE) of individual heifers was determined from changes in total body fat and protein using a TOH isotope dilution procedure and, assuming calorific values of 39.3 and 23.6 kJ/g for fat and protein respectively. The estimated ME for maintenance was 433 and $470kJ/kg^{0.75}/day$ by liveweight (ADG) equilibrium and energy (RE) equilibrium analysis respectively. ME requirement for one g of liveight gain was 28 kJ.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.3
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• pp.55-61
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• 2018

This study evaluated if the selected samples meets the Solid Refuse Fuel quality criteria in Korea. Biomass and plastic wastes generated in D City were mixed in diverse ratio. When the biomass content was about 40%, the moisture content was close to the SRF criteria and was measured to be 9.8%. The ash contents were analyzed up to 4.19%, and the lower calorific values based on Steuer, Dulong Equation and Bomb Calorimeter were at least 4,851, 4,181 and 3,847 kcal/kg, respectively. As a result of the elemental analysis, sulfur and chloride content were measured up to 0.05%. Those values satisfied the SRF criteria. Also, heavy metals(Hg, Cd, Pb, As) were analyzed to be below the SRF criteria. This makes it possible to use efficiently the wood byproducts abandoned in the woods, and the physical properties of wood being weak to moisture can be supplemented with plastics. Consequently, if plastic and biomass were well mixed and made into SRF, it would overcome the problem of shortening the life span of incineration facilities due to the high temperature of plastic wastes in the incinerator.

• Korean Journal of Soil Science and Fertilizer
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• v.42 no.6
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• pp.486-491
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• 2009

To evaluate the potential value of the major bioenergy crops which are wheat, canola, barley, corn, and sweet potato in Korea, we investigated the production of biomass and calorific value of crops, and also compared input and output factors among bioenergy crops during the cultivation period. There was difference between the biomass values in Agricultural and Forestry statistical yearbook(2006) and the one investigated in this experiment, also there was difference in crops and in species. Among the crops investigated, sweet potato(Jinhongmi, Yulmi) was shown the highest amount of biomass production and corn(Gangdaok) was shown the highest amount of the total biomass which is the total aboveground biomass at harvest. Oilseed canola which is presently a major source of bio-diesel had highest calorific value as $6,673{\sim}6,725cal\;g^{-1}$. Wheat and corn grains which are source of bio-ethanol were in the range of $3,879{\sim}4,317cal\;g^{-1}$. Gangdaok(Corn) produce the highest total calorific value in unit cultivating area among the crops as $8,263kcal\;m^{-2}$. Corn was shown that the input and output factors were the highest level among bioenergy crops during cultivation period. Sweet potato also was shown that output factor was the highest level though its input factors were average level. It is needed to be investigated more crops for collecting the higher potential value of bioenergy production further considering small land area and its effective utilization in Korea.