• Journal of the Architectural Institute of Korea Structure & Construction
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• v.35 no.2
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• pp.21-28
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• 2019

Handmade hydrated lime has been used for preservation and repair of architectural heritage in Korea. However, the effect of the amount of water used for slaking quicklime on the physical and chemical properties of the hydrated lime, which is the result of the slaking process, has not been clearly understood. In this study, particle size distribution, chemical composition and crystalline phases of the hydrated lime are investigated by varying the amount of water used for the slaking. In addition, temperature history during the slaking process is examined. For this, various experiments, such as laser diffraction analysis, X-ray fluorescence, X-ray diffraction, thermogravimetric analysis, and temperature recording using a thermocouple, were performed. When the quicklime came into contact with water, its temperature reached $100^{\circ}C$ within 10 min due to sudden exothermic reaction of calcium oxide, and this temperature was maintained for about 30 min. The water to lime ratio influenced the cooling rate during the slaking process; that is, the more water was used, the longer it took to reach an ambient temperature. The amount of water for the slaking did not have a noticeable effect on the contents of major components of the hydrated lime such as calcium hydroxide and calcium carbonate, but when slaked with more amount of water, average particle size of the lime tended to decrease. The experimental results in this study can be used as references for developing guidelines on the safety or appropriate amount of water in the lime slaking process.

• Environmental Engineering Research
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• v.12 no.3
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• pp.101-108
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• 2007

Fixation of lead contaminants in the solidification/stabilization using Portland cement has been investigated by X-ray diffraction, scanning electron microscopy and compressive strength. The presence of lead was observed to produce lead carbonate sulfate hydroxide ($Pb_4SO_4(CO_3)_2(OH)_2$), lead carbonate hydroxide hydrate ($3PbCO_3{\cdot}2Pb(OH)_2{\cdot}H_2O$) and two other unidentified lead salts in cavity areas and was observed to significantly retard the hydration of cement. By 28 days, howevere, the XRD peaks of most of the lead precipitates have essentially disappeared with only residual traces of lead carbonate sulfate hydroxide and lead carbonate hydroxide hydrate evident. After 28 days of curing, hydration appears well advanced with a strong portlandite peak present though C-S-H gel peaks are not particularly evident. Lead species produced with the dissolution of lead precipitates are fixed into the cement matrix to be calcium lead silicate hydrate (C-Pb-S-H) during cement-based solidification.

• Resources Recycling
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• v.23 no.3
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• pp.21-29
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• 2014

This study was conducted to obtain the basic data for designing the lithium recovery process from the "salar de Uyuni" in Bolivia. For this study, the mock brine which has the similar chemical composition with the brine of "salar de Uyuni" was prepared, and the effects of reaction factors such as temperature, time, pH and so forth on the precitation reaction of magnesium hydroxide were investigated.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.9 no.2
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• pp.63-71
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• 2011

A large volume of uranium electrokinetic leachate has been generated during the electrokinetic decontamination to remove uranium from contaminated soil. The treatment technology for the reuse of the uranium leachate was developed. The concentration of uranium in the generated uranium leachate was 180 ppm and concentrations of Mg(II), K(I), Fe(II), and Al(III) ions ranged from 20 ppm to 1,210 ppm. The treatment process for uranium leachate consisted mainly of mixing and cohesion, precipitation, concentration, and filtration. In order to obtain the pH=11 of a precipitate solution, the calcium hydroxide needs to be 3.0g/100ml and the sodium hydroxide needed to be 2.7g/100ml. The results of several precipitation experiments showed that a mixture of NaOH+0.2g alum+0.15g magnetite was an optimal precipitant for filtration. The average particle size of precipitate with NaOH+alum+0.15g magnetite was $600\;{\mu}m$. Because the total value of metal concentrations in supernatant at pH=9 was the smallest, sodium hydroxide should be added with 0.2g alum and 0.15g magnetite for pH=9 of leachate.

• Geotechnical Engineering
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• v.2 no.3
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• pp.5-14
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• 1986

The results of stabilization process in silty.clays and sand-silts, which were, respectively, treated with Calcium hydroxide of the Calcium series and Aluminium Sulphate of the Aluminium series are follows. 1) In the former case used calcium hydrate and calcium cabonate for silty-clays, calcium aluminnium cabonate oxide hydrate and calcium carbonate for sandy-silts were produced 2) In the latter case used Aluminium Sulphate, by X-ray diffraction test, it was found that Aluminium Oxide was produced both in silty-clays and sandy-silts 3) As the results of stabilization process, in the former case, unconfined compression strength was increased greatly but in the latter case it was little increased.

• Journal of the Korea Institute of Building Construction
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• v.13 no.5
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• pp.457-464
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• 2013

Traditionally, the material used for the form in reinforced concrete construction has been wood or steel. But recently, aluminum forms have been widely used in wall structures such as apartment buildings. Aluminum is light, easy to handle, and economically advantageous, but the hydrogen gas created due to its reaction with the alkali component in concrete gives rise to air pockets on the concrete's surface, and deteriorates the surface's finishability. In this research, to determine the influence of aluminum material on concrete, the cement paste W/C and its chemical reactivity in alkali and acid solution were analyzed. As a prevention plan, the influence of the number of applications of calcium hydroxide and various surface coating materials was analyzed. Through the analysis, it was found that the surface voids on the aluminum form are the result of the reaction of hydrogen gas with an alkali such as $Ca(OH)_2$. This can be prevented by the surface treatment of $Ca(OH)_2$, separating material and coating material. However, poor surface form and damages to the form are expected to cause quality degradation because of the aluminum-concrete interaction. Therefore, thorough surface treatment, rather than the type of separating material or coating material, is considered the most important target of management.

• Journal of the korean academy of Pediatric Dentistry
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• v.21 no.2
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• pp.518-524
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• 1994

A traumatically intruded tooth is one that is forcefully and abruptly dispaced from its position into the surrounding alveolar bone. Although intrusion of permanent teeth is infrequent, the sequelae compromise the longevity of the tooth and often include pulp necrosis, internal and external root resorption, rupture of periodontal ligament and loss of marginal bone. The purpose of this study was to examine three common management techniques for traumatic intrusion, observation for re-eruption, surgical repositioning & fixation and orthodontic extrusion. In the recent, the accepted treatment was to allow the permanent teeth to reerupt spontaneously for 6-8 weeks. If this did not occur, orthodontic traction was applied. The pulpal status of the teeth was monitored and either calcium hydroxide therapy or conventional endodontics was instituted following pulpal necrosis depending on the maturity of the root end. Pulpectomy and a calcium hydroxide filling were also the treatment of choice if there was evidence of internal or external root resorption. This will reduce the chance of root resorption and provide a period of monitoring prior to a definitive root canal filling.

• KIEAE Journal
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• v.7 no.4
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• pp.113-118
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• 2007

From the construction material the cement and the concrete which will reach to 90% are used to construction. But the cement occurrence (from the whole industry 4.4% of carbon dioxide exhaust quantity) makes the carbon dioxide of manufacture hour and anti- the recognition which is an environment industry. The cement absorbs the carbon dioxide during life period of the life time. It calls carbonation. In this study in order to evaluate the carbon dioxide absorption of the cement test produced the mortar specimens which it follows in the W/C. And carbonatable material of mortar specimens (calcium hydroxide) the quantitly it measured, reference study it led and absorption of carbon dioxide quantity it produced. Finally two result comparisons leads and it is a fundamental study which does the test evaluation possibility and a propriety investigation of carbon dioxide absorption quantity in objective.

• Journal of the Korean Ceramic Society
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• v.44 no.1 s.296
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• pp.12-17
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• 2007

Recently, Korean food culture has westernized and the consumption of meat has been increased. As a result an enormous amount of disposal of bone is generated and most of them are buried without reutilization. By making bone ash using pig bone, the possibilities of application are examined. The purpose of this study is to establish a manufacturing process of bone ash for the celadon bone body using pig bone. The calcination of the pig bone was mostly to change to the calcium phosphate hydroxide $(Ca_5(PO_4)_3OH)$. The celadon body mixed with pig bone ash 8%, $CaCO_3$ 9%, when fired at $1240^{\circ}C$ under reduction atmosphere, shows 0.1% of water absorption, 65.23 MPa of bending strength.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.11a
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• pp.31-32
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• 2011

Granulated slag from metal industries and fly ash from the combustion of coal are industrial by-products that have been widely used as mineral admixtures in normal and high strength concrete. Due to the reaction between calcium hydroxide and fly ash or slag, the hydration of concrete containing fly ash or slag is much more complex compared with that of Portland cement. In this paper, the production of calcium hydroxide in cement hydration and its consumption in the reaction of mineral admixtures is considered in order to develop a numerical model that simulates the hydration of concrete containing fly ash or slag. The heat evolution rates of fly ash- or slag-blended concrete is determined by the contribution of both cement hydration and the reaction of the mineral admixtures. Furthermore, the temperature distribution and temperature history in hardening blended concrete are evaluated based on the degree of hydration of the cement and the mineral admixtures. The proposed model is verified through experimental data on concrete with different water-to-cement ratios and mineral admixture substitution ratios.