• Journal of the Korean institute of surface engineering
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• v.51 no.5
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• pp.325-331
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• 2018

Calcium carbonate($CaCO_3$) films were formed by an eco-friendly electro-chemical technique on steel substrates in synthesized distilled water solutions containing $NaHCO_3$, $CaCl_2$ and $MgCl_2$ with different ratio respectively. It was investigated to confirm the effect of $Mg^{2+}$ concentration by Scanning Electron Microscopy(SEM), Energy Dispersive x-ray Spectroscopy(EDS) and X-Ray Diffraction(XRD) respectively. From an experimental result, only calcite crystals were found in solution containing no $Mg^{2+}$. By increasing concentration of $Mg^{2+}$, deposition rate decreased and crystal structure was transformed form calcite to aragonite. In case of including $MgCl_2$ 300mM in synthesized solutions containing $NaHCO_3$, $CaCl_2$ 60mM, it was showed over the 90% of aragonite contents which have quite high deposition rate of aragonite. Also, it was confirmed that $Mg^{2+}$ acted as inhibitor on the films which made transforming from calcite to aragonite.

• Biotechnology and Bioprocess Engineering:BBE
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• v.2 no.2
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• pp.109-112
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• 1997

Morphology of carbonate crystals grown on the surface of artificial cell membranes was controlled by changing the interfacial chemistry. For octadecyltriethoxysilane (OTE) films with terminal methyl groups interacting little with an aqueous calcium carbonate solution calcite (104) crystals were formed. Polymerized pentacosadiynoic acid (PDA) films with terminal carboxylic acid groups induced deposition of calcite (012) crystals aligned along with each other within a polymer domain. On the other hand, stearyl alcohol (StOH) films with terminal hydroxyl groups induced deposition of aragonite crystals. When PDA was mixed with StOH, the 8:1 PDA:StOH (molar ratio) film produced dominating calcite (012) crystals without any crystal alignment, and the 4:1 mixture film produced minor calcite (012) crystals and major aragonite crystals. For the 2:1, 1:1, 1:2, and 1:4 mixture films, aragonite crystals were dominating. Hence, it is found that the chemical composition at the interface plays a very important role in controlling the morphology of deposited carbonate crystals.

• Journal of Adhesion and Interface
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• v.9 no.2
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• pp.24-31
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• 2008

In this work, calcium hydroxide and magnesium carbonate as metal ionic crosslinking agents were used to introduce ionic crosslinking points to the ethylene vinylacetate (EVA) emulsions for the enhancement of water resistance and mechanical properties of emulsion films. The properties of EVA emulsion film were investigated in crosslinking density, thermal features, surface energy, and mechanical properties, such as tensile strength, elongation at break and tear strength. With the increasing content of metal ionic crosslinking agent, the crosslinking density of the EVA emulsion film increases, resulting into the improvement of water resistance. The surface energy and mechanical properties of the EVA emulsion film, however, showed somewhat different behaviors. The highest surface energy, tensile strength, and tear strength were observed when 0.4% for calcium hydroxide and 0.5% for magnesium carbonate was added respectively, because the EVA emulsion containing carboxylic acid forms strong carboxylate-metal bond of ionically-crosslinked system. Therefore, it can be concluded that metal ionic crosslinking agents, such as magnesium carbonate and calcium hydroxide are considered to improve water resistance and mechanical properties of the EVA emulsion.

• Resources Recycling
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• v.17 no.3
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• pp.10-20
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• 2008

In order to study the behaviors of inorganic fillers in recycling of the waste agricultural plastic films, the washed PE fluffs from Shihwa and Jungeup Plant belonging to ENVICO were used respectively. First of all, the test pellets were manufactured by adding of inorganic fillers suchlike calcium carbonate and calpet by certain portions to PE fluffs and then the tested sheets were formed. The mechanical and thermal properties of the samples were measured and compared with others. The items measured were tensile, flexural, Izod impact, HDT, MFT, and so on. Morphologies were also investigated for various samples using the SEM. Finally, optimum ratios between recycled PE and inorganic additives were found out for the best products in physical condition as well as in economic point of view.

• Corrosion Science and Technology
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• v.4 no.3
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• pp.89-94
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• 2005

This paper presents the results of a study that was undertaken to optimize the ratio of the components of a new multi-component inhibitor blend composed of orthophosphate/ phosphonates/ acrylate copolymer/ isothiazolone. The effects of newly developed inhibitor on carbon steel dissolution in synthetic cooling water were studied through weight loss tests, electrochemical tests, scale tests, and micro-organism tests. The obtained results were compared to blank (uninhibited specimen) and showed that developed inhibitor revealed very good corrosion, scale, and micro-organism inhibition simultaneously. All measurements indicated that the efficiency of the blended mixture exceeded 90 %. The inhibitive effects arose from formation of protective films which might contain calcium phosphate, calcium phosphonate, and iron oxide. The nature of protective films formed on the carbon steel was studied by scanning electron microscopy (SEM) and auger electron spe ctroscopy (AES). Inhibitor used in this study appeared to have better performance for scale inhibition due to their superior crystal modification effect and excellent calcium carbonate scale inhibition properties. The effect of inhibitor on microorganisms was evaluated through minimum inhibitory concentration (MIC) test. All kinds of micro-organisms used in this study were inhibited under 78ppm concentration of inhibitor.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2013.05a
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• pp.146-147
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• 2013

본 연구에서는 탄산칼슘을 대면적의 막으로 형성하고, 그 결정구조를 제어하기 위해 제작된 합성용액 중 염(NaCl)의 첨가에 의한 Ca이온의 농도변화가 탄산칼슘 결정구조 변화에 미치는 영향을 알아보고자 하였다. 제작된 탄산칼슘 막은 SEM, EDS 및 XRD를 통해서 분석되었으며, 시간 별 탄산칼슘 막의 제작 및 분석을 통해서 결정구조 변화의 메커니즘을 규명하고자 하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2012.11a
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• pp.91-92
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• 2012

본 연구에서는 $NaHCO_3$, $CaCl_2$ 용액 중 $Mg^{2+}$의 농도를 조절하며 전착프로세스에 의해 다양한 결정구조의 환경친화적인 탄산칼슘 막을 제작할 수 있었다. 특히, 여기서는 이들 막의 효율-실용적 설계 제작을 위해 상기한 용액 조건 중 NaCl의 첨가 농도를 달리하여 탄산칼슘 막의 석출량을 도출함으로써 최적 석출 속도를 제시할 수 있었다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2012.11a
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• pp.93-94
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• 2012

$NaHCO_3$, $CaCl_2$ 용액 중 전착프로세스에 의해 환경친화적인 탄산칼슘 막을 형성시킴은 물론 이와 같은 용액 중 염화마그네슘의 첨가를 통해 $Mg^{2+}$의 농도를 조절함으로써 탄산칼슘 전착막의 결정구조를 제어할 수 있었다. 여기서는 특히 상기 용액 조건 중 합성 온도의 변화가 탄산칼슘 막의 석출속도, 석출량 및 결정구조 등에 어떤 영향을 미치는지 검토함으로써 이들 막에 대한 전착 설계에 유효한 지침을 제시하였다.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.11a
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• pp.196-197
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• 2005

Cathodic protection is one of the successful ways to prevent corrosion of steel structures in marine environments. The unique feature of cathodic protection in seawater is the formation of calcareous deposits on cathodic metal surface. The formation principles of calcareous deposit seawater had been known for a long time. That is, cathodic reduction reactions associated with cathodic protection in seawater generate $OH^-$ at the metal surface in accordance with the formular ; 1/2 $O_2$ + $H_2O$ + $2e^-$ $2OH^-$ and $2H_2O$ + $2e^-$ ${\rightarrow}$ $H_2$ + $2OH^-$. These reactions increase the pH at the metal / seawater interface. The high pH causes precipitation of $Mg(OH)_2$ and $CaCO_3$ in accordance with the formular ; $Mg^{2+}$ + $2(OH)^-$ ${\rightarrow}$ $Mg(OH)_2$ and $Ca^{2+}$ + $HCO_3^-$ + $OH^-$ ${\rightarrow}$ $H_2O$ + $CaCO_3$. These are typically the main compounds in calcareous deposits. It obviously has several advantages compared to the conventional coatings, since the environment-friendly calcareous deposit coating is formed by the elements($Mg^{2+}$, $Ca^{2+}$) naturally present in seawater. In this study, environmental friendly calcareous deposit films were prepared on steel plates by electro plating technic in natural seawater. The influence of current density on composition ratio, structure and morphology of the coated films were investigated by scanning electron microscopy formation process of calcareous deposits films in natural seawater. And we confirmed the properties of all the films can be improved greatly by controlling the material structure and morphology with effective use of the electroplating method in natural seawater.

• Textile Coloration and Finishing
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• v.34 no.1
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• pp.68-75
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• 2022

The breathable film refers to a high-functional film that allows gas and water vapor to pass through very fine and sophisticated pores but not liquid. In this research, the breathable film was prepared based on linear low-density polyethylene (LLDPE) and CaCO₃ particles by extrude method. The LLDPE composite film containing CaCO₃ particles had excellent mechanical properties and functionalties. The drawing is a technologically simple and excellent method for improving the mechanical properties of composite films. In this work, the effects of draw ratio on morphology, crystallinity, pore size distribution, mechanical properties, and water vapor permeability of the films were examined. The results revealed that both surface morphology and breathability were affected by the influence of chain orientation and crystal growth with increasing the draw ratio. The mechanical properties were improved with increasing the draw ratio.