• Title/Summary/Keyword: CaO content

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Fabrication of Superconducting Thick Film by Spray Pyrolysis Method (Spray Pyrolysis에 의한 초전도 합성)

  • Lee, Sang-Heon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.1
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    • pp.120-122
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    • 2010
  • In this paper the effect of constituent content on superconductivity and phase in BiPbSrCaCuO system was reported. The zero resistance temperature reaches as high as 100k when dophant Sb was decreased dramatically with increasing Sb content in BiPbSrCaCuO system while the corresponding phase was changed fundamentally.

초지에 대한 인산질비료의 시용에 관한 연구 IV. 인산질비료의 시용수준이 목장의 식생구성과 무기물함량 및 토양화학성분에 미치는 영향 ( Studies on the Phosphatic fertilizer Application Grassland IV. Effect of phosphatic fertilizer levals on the botanial compos

  • 박근제;최기춘;이필상
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.14 no.3
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    • pp.223-229
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    • 1994
  • To find out the effects of phosphatic fertilizer application levels on the botanical composition, mineral contents and mineral nutrient deprivation of grasses and the chemical properties of soil, this expriment was arranged as a randomized complete block design with six treatments(0, 50, 100, 150, 200 and 250kg $P_2O_5$/ha) and conducted at hilly land in Gwangju, Gyeonggi Province from September, 1989 to October, 1992. The results obtained are summarized as follows: The botanical composition of grasses without posphatic fertilizer application was poor but with 150kg $P_2O_5$/ha application, remarkably increased in legume of grasses and decreaed in weed. As the phophatic fertilizer levels increase, P, Ca and Mg content of grasses were increased but N and K content tended not to be regular, and Ca/p and K/Ca+ Mg equivalent ratio were lowered. Up to 150kg $P_2O_5$/ha application level, the mineral nutrient content deprived by dry matter yield was increased but with that over application, tend not to be increased. Most of applied mineral elements were accumulated at a subsurface of grassland and as the phosphatic fertilizer application levels increase, the available $P_2O_5$ and exchangeable Mg contents of the soil tended to be remarkably increased and exchangeable K content tended to be decreased, but pH, OM and exchangeable Ca content tended not to be regular.

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Effect of "CellCaSi" recycling Coal Fly Ash on Soil Amendment and the growth of Turfgrass in Golf Course (석탄회를 재활용한 '셀카시'의 토양 개량과 골프 코스 잔디 생육에 대한 효과)

  • 이상재;허근영;정운익
    • Asian Journal of Turfgrass Science
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    • v.13 no.4
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    • pp.191-200
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    • 1999
  • The objective of this study was to improve the recycling rate of coal ash fly, industrial waste. This study was conducted to analyze the physico-chemical properties of \"CellCaSi\" and clarify the effects on the growth of Kentucky bluegrass(Poa pratensis L.) and creeping bentgrass(Agrostis paulstris Huds \"Penncross\") and the chemical properties of soil, which was cellular calcium silicate reproduced by coal ash fly. A field assay was carried out in Young-Pyong Golf Course. The results were as follows. 1. The main chemical composition of CellCaSi was $SiO_2$(45~55%) and CaO(25~35), which was 70~90% of total weight. CellCaSi showed pH 8~9. Bulk density of CellCaSi was 0.35~0.45g/㎤. Water content of CellCaSi was 52.5~67.5%. 2. In the applied plots, leaf width, grass density per $1\textrm{cm}^2$, rhizome number and length per plant, and root number per plant of Kentucky bluegrass(Poa pratensis L.) and creeping bentgrass(Agrostis paulstris Huds \"Penncross\") showed increasing tendency compared with the control. The application of CellCaSi increased the growth of turfgrasses. Their visual quality on hardness, grass shoot density per $1\textrm{cm}^2$ and root growth was very good. And, their visual quality on rhizome growth was good. 3. After the application of CellCaSi, pH, CEC, Ex-cation of the applied soil showed increasing tendency with the little range, $SiO_2$content increasing tendency considerably, and organic matter content decreasing tendency compared with the control.ncy compared with the control.

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Microwave Dielectric Properties of CaO Added $(Ba, Pb)O-Nd_2O_3-TiO_2$ Ceramics (CaO첨가$(Ba, Pb)O-Nd_2O_3-TiO_2$ 세라믹스의 고주파 유전특성)

  • Yoon, Sang-Ok;Choi, Whan;Kim, Kyung-Yong
    • Journal of the Korean Ceramic Society
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    • v.30 no.2
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    • pp.101-106
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    • 1993
  • Effects of CaO on microwave dielectric properties of (Ba, Pb)O-Nd2O3-TiO2 ceramic ystem were investigated. As the content of CaO increases, the sintered bulk density decreases due to the decrease of sinterability. However, with increasing the sintering tmperature, the relative dielectric constants increases. This has been attributed on the formation of the 2nd phase inclusion, TiO2(rutile). The Q values increase due to the compensation effect of Ca ions up to 1 wt%, and then decrease due to the interfacial relaxation effects. The temperature coefficient of resonance frequency increases to a positive direction with increasing the amounts of CaO.

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Oxidation behavior of CaO added Mg and Mg-Al alloys (CaO을 첨가한 Mg 및 Mg-Al 합금의 산화거동)

  • Ha, Seong-Ho;Lee, Jin-Kyu;Jung, Seung-Boo;Kim, Young-Jig;Jo, Hyung-Ho;Kim, Shae-K.
    • Journal of Korea Foundry Society
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    • v.27 no.3
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    • pp.126-130
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    • 2007
  • Oxidation behavior of CaO added Mg and Mg-5Al alloys was investigated. At $500^{\circ}C$, oxidation rate of pure Mg was abruptly increased, while that of CaO added Mg was remarkably reduced with increasing CaO content. As a result of surface analysis by AES, there was the thin oxide layer mixed with MgO and CaO in CaO added Mg. Oxidation behavior of CaO added Mg was similar to that of Ca added Mg. Oxidation rate of 0.6CaO added Mg-5Al alloy was much lower than that of Mg-5Al alloy at $500^{\circ}C$ and both alloys showed the linear weight change at $400^{\circ}C$.

Effect of modifiers on the properties of glass-ceramics containing coal bottom ash (석탄 바닥재가 포함된 결정화 유리의 특성에 미치는 수식제의 영향)

  • Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.1
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    • pp.53-57
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    • 2010
  • The influence of CaO addition on the crystallization temperature, crystal types, and microstructure of L-A-S ($Li_2O-Al_2O_3-SiO_2$) glass-ceramics system fabricated from a coal bottom ash, produced at thermal power plant, was studied. The glass transition and crystallization temperatures were shifted to the higher temperature position with increasing CaO content in a non-isothermal analysis using a DTA. The major crystalline phases of L-A-S glass-ceramics system produced were identified as ${\beta}$-spodumene ($LiAlSi_2O_6$) and eucryptite ($LiAlSiO_4$). The glass-ceramics showed a bulk and surface crystallization behavior at a time. With increasing CaO content, the ${\beta}$-spodumene peak in XRD increased and some CaO-related phases were formed. The surface crystal grown from the exterior to the center in glass-ceramics showed various shapes by amount of CaO added. Some cracks were generated at the glass-ceramics containing CaO above 9 wt% due to the mismatch of thermal expansion coefficients between a ${\beta}$-spodumene and CaO-related crystal phases.

Effect of Chemical Composition on the Latent Hydraulic Activity of Blast Furnace Slag (고로슬래그의 잠재수경성에 미치는 화학조성의 영향)

  • 장복기;임용무
    • Journal of the Korean Ceramic Society
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    • v.37 no.5
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    • pp.453-458
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    • 2000
  • Glasses showing the composition of blast furnace slag were made in the laboratory, and the effect of the chemical composition on the latent hydraulic activity of the slags was examined. The latent hydraulicity was greatly influenced by the composition change, the optimal characteristic of the hydraulicity was achieved at the slag composition of 47CaO:20Al2O3:33SiO2. The content of CaO and Al2O3 were not equivalent to the hydraulic activity of the slags as the b-formula (KS L 5210) indicates. Good latent hydraulicity was shown when Al2O3 was richly contained at the high (CaO+Al2O3):SiO ratio, while the more the MgO content was, the more negative the result turned out.

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The Study on the Bulk Crystallization in $Na_2O-CaO-MgO-Al_2O_3-SiO_2$ Glass-Ceramics ($Na_2O-CaO-MgO-Al_2O_3-SiO_2$계 Glass-Ceramics에 있어서 Bulk Crystallization에 관한 연구)

  • 강원호;이정호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.2 no.2
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    • pp.20-32
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    • 1992
  • $Na_2O-CaO-MgO-Al_2O_3-SiO_2$ glass was taken as a basic glass and then $Li_2O$ O.5wt%, $K_2O$ 2.0wt% were substituted to $Na_2O$content, MgO 12.0wt %, ZnO 6.0wt % to CaO content. And also nucleation agent $ZrO_2 and $CaF_2$ were added to 1-2wt% respectively. The crystal according to the compositions appeared wollastonite, diopside and diopside.tremolite. The glasses substituted NazO by LizO was decreased thermal expansion coeffcient but substituted by ZnO was opposite direction and both of them increased bending strength. In the ratio of ZrOz to CaF, each 1: 1 and 1: 2 have shown considerable crystal growth at $1000^{circ}C~1050^{\circ}C$ and high bending strength, but the glass in the ratio 1: 2 have shown lowest thermal expansion coefficient. The activation energy was at the glass in the ratio of ZrO, to CaFz 1:2 evaluated 55.24kvsl/mol by Ozawa type and 53.05kal/mol by kissinger type.

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Pyrometallurgy Process for a Low Graded Gold Alloy with PbO and CaO (저품위 금합금의 PbO와 CaO를 이용한 건식 정련 공정)

  • Song, Jeongho;Song, Ohsung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.4
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    • pp.608-613
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    • 2017
  • We proposed a pyrometallurgical process to achieve gold alloy with an Au content of more than 80wt% from low grade (<35wt%) gold alloys. We performed the heat treatment at a temperature of $1200^{\circ}C$ for 5 hrs using Au35wt%-Ag5wt%-Cu60wt% gold alloys mixed with 1/2 weighed PbO and CaO flux by varying the ratio of PbO/(PbO+CaO) from 0 to 1. We investigated the change in content of the samples with energy dispersive X-ray spectroscopy (EDS) and time of flight secondary ion mass spectrometry (ToF-SIMS). The EDS results showed that the Au content increased from 35.0wt% in the PbO-only sample to 86.7wt% (in the PbO/(PbO+CaO) 1:1 sample), while the other samples achieved more that 84wt%. In addition, the 2/3 flux ratio sample showed the lowest Ag loss into the flux. In the ToF-SIMS results, the PbO only and CaO only fluxes had Au+ peak intensities of 349 and 37, respectively. Although the CaO-only flux might be more favorable considering the loss of Au into the flux, we concluded that the amount of Au lost into the flux could be ignored. Our results imply that that the pyrometallurgical process using a mixed flux is an effective hydrometallurgical process.

Hydration Characteristics of Coal-Fly Ash Containing High CaO Compound (CaO 화합물이 다량 함유된 비산재의 수화 특성에 관한 연구)

  • Sim, Jun-Soo;Lee, Ki-Gang;Kim, Yu-Taek;Kang, Seung-Ku
    • Journal of the Korean Ceramic Society
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    • v.49 no.2
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    • pp.185-190
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    • 2012
  • The purpose of this study was to examine a possibility that fly ash could be used as raw material for carbonation by conducting the experiment on magnetic separation and hydration of fly ash that contained a large amount of CaO composite. Wet magnetic separation experiment was performed to remove the component of magnetic substance that contained fly ash, which aimed at increasing the content of CaO in the non-magnetic domain. The selected fly ash was used for hydration experiment before the TG-DTA, XRF and XRD analyses were made to confirm the Ca component that could be carbonated. Then, the fly ash was turned to a hydrate that was favorable to dissociation of $Ca^{2+}$ ion. As a result, the magnetic separation enabled detecting the content of CaO component by up to 61 wt% in the non-magnetic domain. Since the hydrate was confirmed, it is believed that the fly ash can be used as raw material for carbonation.