• Title/Summary/Keyword: Ca-Mg complex

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Effects of the Application of Different Fertilizers on the Forage Productivity and Quality on Newly Reclaimed Hilly Soil III. Mutual balances of mineral nutrients in the soils & mixed forages, and the grass tetany hazard in a mixed grass-clover sward (신개간 산지토양에서 초지조성비 비종별 목초의 생산성 및 품질 비교 III. 토양 및 목초 중 무기양분의 상호균형과 Grass tetany 위험성)

  • 정연규;임요섭;조주식
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.21 no.4
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    • pp.253-258
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    • 2001
  • This pot experiment was conducted to find out the forage productivity and quality in a grasslclover sward as affected by the application of three different fertilizers; double superphosphate(DS), fused Mg-phosphate (FP), and complex fertilizer(CF) on newly reclaimed hilly soil. This part was concerned with the mutual balances of mineral nutrients in the soils and mixed grass/clover sward in relation to grass tetany hazard. The results obtained are summarized as follows : 1. Concentration of exchangeable Mg and relative proportion of Mg to CEC in the soils before experiment were considerably below the critical level for good forage growth and prevention of grass tetany. It seems that these properties would be able to handicap by liming and NPK applications. 2. Comparing with the critical level for likelihood of tetany(Mg <0.2%, K >2.5%, and W(Ca+Mg) >2.2 in forages), mean concentration of Mg ranged from 0.14 in DS plot and 0.18 in FP plot to 0.24% in CF plot. Meanwhile, hazards of grass tetany in relation to the %K and ratio of K/(Ca+Mg) were not recognized. 3. Comparing with the optimum level of Carp(% ratio)=2.0 in forages for animal health, these ranged from 6.1 to 7.1. (Key words : Grass tetany, Fertilizer. Soil. Mineral nutrients)

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Biosorption of Cr, Cu and Al by Sargassum Biomass

  • Lee, Hak-Sung
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.2 no.2
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    • pp.126-131
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    • 1997
  • The biosorption and desorption of Cr, Cu and Al were carried out using brown marine algae Sargassum fluitans biomass, known as the good biosorbent of heavy metals. The content of alginate bound to light metals could be changed by physical and chemical pretreatment. The maximum uptake of Cr, Cu and Al was independent of the alginate content. The maximum uptaker of Al was two times(mole basis) than those of Cu and Cr. The aluminum-alginate complex was found in the sorption solution of raw and protonated biomass. Most of Cu, Al and light metals sorbed in the biomass were eluted at pH 1.1. However, only 5 to 10% of Cr sorbed was eluted at pH 1.1. The stoiceometric ion exchange between Cu and Ca ion was observed on Cu biosorption with Ca-loaded biomass. A part of Cr ion was bound to biomass as Cr(OH)2+ or Cr(OH)2+. Al was also bound to biomass as multi-valence ion and interfered with the desorbed Ca ion. The behavior of raw S. fluitans in ten consecutive sorption-desorption cycles has been investigated in a packed bed flow-through-column during a continuous removal of copper from a 35 mg/L aqueous solution at pH 5. The eluant used was a 1%(w/v) CaCl2/HC solution at pH 3.

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Geochemistry of Minerals in the Hongcheon Magnetite Deposits, Korea (홍천자철광상의 구성광물의 화학적 특징)

  • 이상헌
    • The Journal of the Petrological Society of Korea
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    • v.7 no.2
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    • pp.98-110
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    • 1998
  • Hongcheon magnetite deposit is embedded, as a lens shape, in biotite banded gneiss belonging to the Gyeonggi metamorphic complex. It gradationally changes to the host quartz-feldspathic banded gneiss in the mineral composition. Magnetite ore bodies are composed of magnetite ores and magnetite banded gneiss which gradationally change each other in the amount of magnetite. They consist mainly of magnetite, quartz, plagioclase and chlorite accompanied with amphibole, biotite, muscovite, monazite, apatite, ankerite, siderite, rhodochrositic dolomite, calcite and rutile. Amphibole is subdivided into hornblende, richterite and magnesio-riebekite in magnetite ores, and magnesio-, ferro- or actinolitic hornblende in magnetite banded gneiss. The variation in chemical composition may be influenced by bulk composition and controlled mainly by glaucophane $Na(M4)Al_3^{VI}=CaMg$ and richterite Na(M4)Na(A)=Ca substitutions. Biotite in magnetite banded gneiss has an annite composition. Chlorite changes in chemical composition from pycnochlorite to diabantite in magnetite ores and belongs to pycnochlorite in magnetite banded gneiss. The mafic minerals and feldspar have been strongly altered by carbonate minerals which are secondarily formed by introduced hydrothermal solution. Fe-bearing carbonate minerals can be subdivided into ankerite, siderite and rhodochrositic dolomite according to the ratio of Fe-Mg-Mn component.

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Effect of High-Molecular-Weight Poly-$\gamma$-Glutamic Acid from Bacillus subtilis (chungkookjang) on Ca Solubility and Intestinal Absorption

  • PARK CHUNG;CHOI YOON-HO;SHIN HYUN-JIN;POO HARYOUNG;SONG JAE JUN;KIM CHUL-JOONG;SUNG MOON-HEE
    • Journal of Microbiology and Biotechnology
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    • v.15 no.4
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    • pp.855-858
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    • 2005
  • The bioavailability of Ca is currently one of the most important topics in nutrition research and is correlated with gastrointestinal solubility. Thus, to increase the solubility of calcium, this study was undertaken to examine the effect of $\gamma$-PGA on intestinal Ca solubility. The calcium solubility increased when the amount of $\gamma$-PGA was increased, due to the inhibition of the formation of an insoluble Ca complex with phosphate. Therefore, when $\gamma$-PGA-500 (avg. MW 5,000 kDa) was added at 0.5 mg/ml, $75\%$ of the total Ca was soluble. The amount of soluble Ca uptake in the small intestine was investigated using Balb/c mice as an animal model system. The soluble Ca uptake in the mice orally administered with $\gamma$-PGA-500 (avg. MW 5,000 kDa) was significantly higher than that in the $\gamma$-PGA-l00 (avg. MW 1,000 kDa)-administered mice (P<0.05). Accordingly, these results strongly support the notion that the molecular size of $\gamma$-PGA is correlated with Ca solubility. The effects of other factors, such as casein phosphopeptide and vitamin D, on intestinal Ca absorption have also previously been investigated. Therefore, it is hoped that the present observations will help clarify the role of $\gamma$-PGA in Ca solubility and its industrial application as an additive.

Electrical Conduction and Emission Properties of (tb-PMP)3Tb-(Ph3PO) Single Layer OLEDs ((tb-PMP)3Tb-(Ph3PO) 단일층 OLEDs의 전기전도 및 발광 특성)

  • Moon, Dae-Gyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.9
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    • pp.878-882
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    • 2006
  • We have fabricated single organic layer devices of the organolanthanide complex, terbium tris-(1-phenyl-3-methyl-4-(tertiarybutyry)pyrazol-5-one)triphenylphosphine oxide [$(tb-PMP)_{3}Tb-(Ph_{3}PO)$] for the investigation of its light emission and electrical conduction properties. The thickness of ($(tb-PMP)_{3}Tb-(Ph_{3}PO)$) layer was varied to 60, 75, 95 nm. Mg and Ca layers were used for the cathode contact. The electrical conduction in the $(tb-PMP)_{3}Tb-(Ph_{3}PO)$ single layer devices was dominated by the injection of electrons into the organic layer from the cathode. A higher current density at much lower voltages can be attained with Ca cathode because of the enhanced electron injection. The device shows very sharp emission at 548 nm. The FWHM of the strongest emission peak was 12 nm.

Biosynthesis of polyhydroxyalkanoate by mixed microbial cultures from hydrolysate of waste activated sludge (혼합미생물배양체를 이용한 폐활성슬러지 가용화 산물로부터 polyhydroxyalkanoate 생합성)

  • Park, Taejun;Yoo, Young Jae;Jung, Dong Hoon;Lee, Sun Hee;Rhee, Young Ha
    • Korean Journal of Microbiology
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    • v.53 no.3
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    • pp.200-207
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    • 2017
  • A new approach to the solubilization of waste activated sludge (WAS) using alginate-quaternary ammonium complex beads was investigated under controlled mild alkaline conditions. The complex beads were prepared by the reaction of sodium alginate (SA) with 3-(trimethoxysilyl)propyl-octadecyldimethylammonium chloride (TSA) in acid solution, followed by crosslinking with $CaCl_2$. Treatment of WAS with SA-TSA complex beads was effective for enhancing the efficacy of WAS solubilization. The highest value of soluble chemical oxygen demand (SCOD) concentration (3,900 mg/L) was achieved after 10 days of treatment with 30% (v/v) SA-TSA complex beads. The WAS solubilization efficacy of the complex beads was also evaluated by estimating the concentrations of volatile fatty acids (VFAs). The maximum value of VFAs was 2,961 mg/L, and the overall proportions of VFAs were more than 75% of SCOD. The main components of VFAs were acetic, propionic, iso-butyric, and butyric acids. These results suggest that SA-TSA complex beads might be useful for enhancing the solubilization of WAS. The potential use of VFAs as the external carbon substrate for the production of polyhydroxyalkanoate (PHA) by a mixed microbial culture (MMC) was also examined. The enrichment of PHA-accumulating MMC could be achieved by periodic feeding of VFAs generated from WAS in a sequencing batch reactor. The composition of PHA synthesized from VFAs mainly consisted of 3-hydroxybutyrate. The maximum PHA content accounted for 25.9% of dry cell weight. PHA production by this process is considered to be promising since it has a doubly beneficial effect on the environment by reducing the amount of WAS and concomitantly producing an eco-friendly biopolymer.

Effect of a Hot Water Extract of Sparasis Crispa on the Expression of Tight Junction-Associated Genes in HaCaT Cells (꽃송이버섯 열수추출물이 HaCaT의 세포 연접 관련 유전자의 발현에 대한 영향)

  • Han, Hyo-Sang
    • Journal of The Korean Society of Integrative Medicine
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    • v.9 no.2
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    • pp.83-92
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    • 2021
  • Purpose : Keratinocytes are the main cellular components involved in wound healing during re-epithelization and inflammation. Dysfunction of tight junction (TJ) adhesions is a major feature in the pathogenesis of various diseases. The purpose of this study was to identify the various effects of a Sparassis crispa water extract (SC) on HaCaT cells and to investigate whether these effects might be applicable to human skin. Methods : We investigated the effectiveness of SC on cell HaCaT viability using MTS. The antioxidant effect of SC was analyzed by comparing the effectiveness of ABTS to that of the well-known antioxidant resveratrol. Reverse-transcription quantitative polymerase chain reaction (qRT-PCR) is the most widely applied method Quantitative RT-PCR analysis has shown that SC in HaCaT cells affects mRNA expression of tight-junction genes associated with skin moisturization. In addition, Wound healing is one of the most complex processes in the human body. It involves the spatial and temporal synchronization of a variety of cell types with distinct roles in the phases of hemostasis, inflammation, growth, re-epithelialization, and remodeling. wound healing analysis demonstrated altered cell migration in SC-treated HaCaT cells. Results : MTS analysis in HaCaT cells was found to be more cytotoxic in SC at a concentration of 0.5 mg/㎖. Compared to 100 µM resveratrol, 4 mg/㎖ SC exhibited similar or superior antioxidant effects. SC treatment in HaCaT cells reduced levels of claudin 1, claudin 3, claudin 4, claudin 6, claudin 7, claudin 8, ZO-1, ZO-2, JAM-A, occludin, and Tricellulin mRNA expression by about 1.13 times. Wound healing analysis demonstrated altered cell migration in SC-treated HaCaT cells and HaCaT cell migration was also reduced to 73.2 % by SC treatment. Conclusion : SC, which acts as an antioxidant, reduces oxidative stress and prevents aging of the skin. Further research is needed to address the effects of SC on human skin given the observed alteration of mRNA expression of tight-junction genes and the decreased the cell migration of HaCaT cells.

Phosphorescent Azacrown Ether-appended Iridium (III) Complex for the Selective Detection of Hg2+ in Aqueous Acetonitrile

  • Li, Yinan;Yoon, Ung-Chan;Hyun, Myung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.32 no.1
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    • pp.122-126
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    • 2011
  • A new phosphorescent cyclometalated heteroleptic iridium (III) complex with an ancillary ligand of 4-azacrownpicolinate was prepared and its metal ion selective phosphorescent chemosensing behavior was investigated. The new iridium (III) complex exhibits notable phosphorescence quenching for Hg2+ in aqueous 50% acetonitrile solution with respect to the selective phosphorescent detection of various metal ions including $Li^+,Na^+,K^+,Cs^+,Mg^{2+},Ca^{2+},Ba^{2+},Fe^{2+},Ni^{2+},Cu^{2+},Zn^{2+},Ag^+,Pb^{2+},Cd^{2+},Cr^{2+},Cr^{3+}$ and $Hg^{2+}$. The phosphorescence quenching for $Hg^{2+}$ increased linearly with increasing concentration of $Hg^{2+}$ in the range of $10{\mu}M-700{\mu}M$ even in the presence of other metal ions, except for $Cu^{2+}$. Consequently, the new iridium (III) complex has the potential to be utilized for the determination of parts per million levels of $Hg^{2+}$ in aqueous acetonitrile media.

Analysis of Trace Elements in Mud Flat with Neutron Activation Analysis (NAA) and Atomic Spectroscopy (중성자 방사화 분석법과 원자 분광법을 이용한 갯벌 시료 중 미량원소 분석법에 관한 연구)

  • Nam, Sang-Ho;Kim, Min-Jae;Chung, Yong-Sam;Kim, Sun-Ha
    • Analytical Science and Technology
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    • v.15 no.6
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    • pp.521-528
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    • 2002
  • Neutron Activation Analysis (NAA) and Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) have been applied for the determination of inorganic elements in mud flat of south seaside in Korea. The analytical results of Al, Ca, Fe, Mg, K and Na by NAA were compared with those by ICP-AES. The results show that NAA is superior to ICP-AES for the determination of minor elements in sediment. Accordingly, NAA will play an important role in the analysis of environment samples such as mud flat and sediment having complex matrix.