• Journal of Soil and Groundwater Environment
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• v.29 no.1
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• pp.39-50
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• 2024

Slags from steel-making industry have been recycled at a target rate of 95% and most of them are recycled as media-contact type such as fill and cover materials in Korea. However, as they contain free phase CaO during their generation, they may not only expand and collapse upon contact with water, but high pH leachate and heavy metals leaching may occur. In this study, the Korean leaching procedure (KLP) and up-flow percolation test were performed for the samples collected from 17 steel-making production plants in Korea. The waste quality criteria were met in all tests, but pH of the samples was above 10. There are no regulations on the pH of leachate in most of the countries, however, Germany, Italy, and Australia have set a pH range of 10 to 13 for the leachates. Although slag leachate cannot be considered hazardous based only on its high pH, it is necessary to reduce the pH of leachate to minimize the impact on the surrounding environment. Furthermore, conflicting regulations on wastes handling and management in Korea created confusion on the types of wastes subject to recycling. Therefore, an appropriate management plan for steel-making slags needs to be established. To this end, this study attempted to provide a guideline for managing steel-making slag waste by considering international guidelines and current management practices in Korea.

• Journal of the Korea institute for structural maintenance and inspection
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• v.11 no.4
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• pp.79-88
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• 2007

Concrete structures undergo degradation of durability performance and it generally propagates to the structural problems. Recently. a lot of materials for surface protection for concrete are developed, however, performance is not clearly improved due to the difficulties such as repair construction technique and quality of materials for repairing. In this study, liquid inorganic impregnant for concrete structures is developed and durability performance for impregnated concrete specimens is carried out. Furthermore, the performances of the concrete specimens with developed impregnant is also compared with those of the specimens with impregnant conventionally used. Additional CSH gel is formed through the reaction of calcium hydroxide ($Ca(OH)_2$) and impregnant with silicate. As a result of the reaction, impregnated concrete is evaluated to have more denser surface and resistance to deterioration. Finally it is experimentally verified that the concrete specimens with developed impregnant show better durability performance than normal specimens and those with conventional impregnant.

• Journal of Plant Biotechnology
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• v.41 no.2
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• pp.81-88
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• 2014

Salt cress (Thellungiella halophila or Thellungiella parvula), species closely related to Arabidopsis thaliana, represents an extremophile adapted to harsh saline environments. To isolate salt-tolerance genes from this species, we constructed a cDNA library from roots and leaves of salt cress plants treated with 200 mM NaCl. This cDNA library was subsequently shuttled into the destination binary vector [driven by the cauliflower mosaic virus (CaMV) 35S promoter] designed for plant transformation and expression via recombination- assisted cloning. In total, 305,400 pools of transgenic BASTA-resistant lines were generated in Arabidopsis using either T. halophila or T. parvula cDNA libraries. These were used for functional screening of genes involved in salt tolerance. Among these pools, 168,500 pools were used for primary screening to date from which 7,157 lines showed apparent salt tolerant-phenotypes in the initial screen. A secondary screen has now identified 165 salt tolerant transgenic lines using 1,551 (10.6%) lines that emerged in the first screen. The prevalent phenotype in these lines includes accelerated seed germination often accompanied by faster root growth compared to WT Arabidopsis under salt stress condition. In addition, other lines showed non-typical development of stems and flowers compared to WT Arabidopsis. Based on the close relationship of the tolerant species to the target species we suggest this approach as an appropriate method for the large-scale identification of salt tolerance genes from salt cress.

• Journal of the Korean Wood Science and Technology
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• v.37 no.4
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• pp.372-380
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• 2009

After supercritical water treatment of poplar wood meals (passed through 60 mesh) for 60s between 325 and $425^{\circ}C$ at the fixed pressure at $220{\pm}10atm$, some solid residues were present in the degradation products. They mainly consisted of chemically modified lignin and fibrous materials. Glucose and xylose were identified as main sugar components of fibrous materials, and the highest ratio of glucose/xylose was achieved at the highest reaction temperature. As reaction temperature was elevated, the portion of fibrous materials decreased in the solid residues, while lignin was further accumulated. The H : G : S ratio of lignin in solid residues was estimated by analytical pyrolysis. Irrespective of reaction temperatures, the H:G:S ratios were not significantly changed in the lignin in solid residues. Compared to poplar milled wood lignin (MWL), it was remarkable that H type monomers were further lowered, while portion of S type monomers increased. The amount of G type monomers were relative stable. In presence of HCl catalyst, lowering H type as well as enhancing S type was further distinguishable. According to the result of nitrobenzene oxidation (NBO), ca. 265 mg of vanillin and syringaldehyde was yielded from poplar MWL as main products. However, remarkably reduced amount of NBO products were determined from solid residues by raising operating temperature as well as by the addition of HCl catalyst. These results strongly indicate that $\beta$-O-4 linkage could be easily cleaved during supercritical water treatment, so that the lignins in the solid residues seem to be condensed phenol polymers, which are mainly formed by carbon-carbon linkages rather than $\beta$-O-4 linkage.

• Journal of the Korea Organic Resources Recycling Association
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• v.31 no.1
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• pp.47-56
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• 2023

This study describes the successful synthesize strategy for the silica nanoparticles utilizing various water sources, including tap, industrial, and stream waters without using deionized water. Also, as-synthesized silica nanoparticles are employed as dispersive materials for the electro-responsive smart fluid application. Specifically, homogeneous silica nanoparticles with sizes of 500-700nm are successfully prepared in large scale at once (ca. 12.0 g) with the described experimental method and showing similar structural and chemical characteristics with silica nanoparticles synthesized using the deionized water. The size of silica nanoparticles are varied according to the ion conductivity differences of tap, industrial, stream water, and deionized water. The size of silica nanoparticles decresed with the increased ion conductivity, indicating the ion suppression of growth of silica nanoparticles. Moreover, as-synthesized silica nanoparticles from various water sources of electro-responsive characteristic are investigated by the smart fluid application. The smart fluids containing silica nanoparticles synthesized by tap, industrial, and stream water exhibited higher shear stress compared to the deionized water, owing to the more rigid fibril-like structures formed by the smaller silica nanoparticles. Conclusively, uniform silica nanoparticles from various water sources without any purification are able to successfully prepared without usage of deionized water and resulting silica nanoparticles manifested higher electro-responsive performance.

• Journal of Korean Society of Forest Science
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• v.81 no.3
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• pp.273-279
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• 1992

Protoplasts isolated from leaf mesophyll tissues of Populus koreana ${\times}$ P. nigra var. italica were fused with those of P. euramericana cv. Guardi. Well expended healthy leaves of 5 to 7 week-old-plantlet grown in vitro were used as source materials. Leaves from P. koreana ${\times}$ P. nigra var. italica and P. euramericana cv. Guardi were digested in enzyme solution I (2.0% Cellulase, 1.2% Hemicellulase, 0.4% Macrozyme, 2.0% Driselase, 0.05% Pectolyase ; w/v) and enzyme solution II (1.0% Cellulase, 1.2% Hemicellulase, 0.4% Macrozyme, 2.0% Driselase, 0.05% Pectolyase ; w/v), respectively, The highest frequency of fusion among the protoplasts originated from the two source materials was approximately 21% using 40% PEG or 15% dextran. In addition, fusion frequency was enhanced by incorporating 30mM of $Ca^{2+}$ in eluting solution at pH 10.5. Dividing cells and/or mint-calli were obtained by culturing the fusion products in a liquid 8p-KM medium supplemented with 0.6M sucrose, $0.45{\mu}M$ 2, 4-D, and $0.5{\mu}M$ BA. Shoots were regenerated from the fusion product-derived calli after culture on MS medium containing $5.0{\mu}M$ zeatin. To verify the putative hybrid or cybrid, SDS-PAGE was carried out. From the 24 regenerants, just two plants showed intermediate protein band patterns compared with those of the original source plants.

• Journal of Environmental Impact Assessment
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• v.27 no.4
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• pp.353-366
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• 2018

The purpose of this study was assessment the quality of water by using the statistical analysis technique of the Water flow and water quality from January 2012 to December 2016 at the unit basin for total pollutant load management system (TPLMS) in the Imjin River. Water flow and water quality were monitored at an average of 8 day intervals, 11 parameters were used for correlation analysis, principal component analysis (PCA), factor analysis (FA), and cluster analysis (CA). The Hierarchical CA was classified into three according to the change of space, such as natural rivers, urban rivers, point with large influence of point pollution source, it was found that the type of contamination source the similarity of water quality affected the classification of cluster. Using one-way analysis of variance (ANOVA) and post-hoc Analysis, there were statistically significant differences between mean values among the clusters. Correlation analysis showed the correlation coefficient between $COD_{Mn}$ and TOC was 0.951 (p<0.01) and the correlation was statistically significantly higher. According to the result PCA and FA, 3 principal components can explaining 72% of the total variations in water quality characteristics and main factor was EC, $BOD_5$, $COD_{Mn}$, TN, TP and TOC indirect indicators of organic matter and nutrients were influenced. This study presented the regression equation obtained by applying the factor scores to the multiple linear regression analysis and concluded that the management Indirect indicators of organic matter and nutrients is important for water quality management in the Imjin River basin.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.4 no.3
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• pp.215-225
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• 1999

To study the vertical variations of major elements, trace elements and rare earth elements(REEs) contents in deep-sea sediments, six cores from Korea Deep-sea Environmental Study area(KODES) were analyzed. Topmost sediment layers of KODES area are divided into two Units; brown-colored and peneliquid Unit I and pale brown-colored and relatively solidified Unit II. Contents of major elements, REEs, Cu, Sr and Rb in each Unit are almost same, while contents of Mn, Ni and Co in Unit I are two or three times higher than those in Unit II. R-mode factor analysis represents that surface sediments are composed of alumino-silicate phase (AI-Ti-K-Mg-Fe-Rb-Ce), apatite phase (Ca-P-Cu-Sr-Trivalent Rare Earth Elements) and Mn-oxide phase(Mn-Ni-Co). Factor scores in silicate and apatite phases in each Unit are nearly same, whereas those in Mn-oxide phase in Unit I is higher than those in Unit II. While NilCu ratio in Unit I is two times higher than that in Unit II. We interprete the geochemical fractionation of Ni and Cu as a result that Ni can be remobilized in oxygen-depleted micro-environment in Units I and II and then easily reprecipitated in Unit I, while most of Cu supplied together with organic material is decomposed mostly in Unit I and sorbed into apatite.

• Korean Journal of Organic Agriculture
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• v.9 no.2
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• pp.101-115
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• 2001

Nitrogen applied as fertilizer for crop production is partly absorbed by plant , and the remaining nitrogen in soil might be leached out through complicated processes to the subsoil layer Especially, NO$_3$-N in leachate causes environmental pollution. The purpose of this study was focused on understanding of uptake of nutrients by plants, the behaviors of nutrients in soil and the possibility of leaching loss when nitrogen fertilizer and completely decomposed compost were applied. Lysimeters(Volume 0.15㎥, Diameter 62cm, Height 62.8cm) were installed for collecting leachate in the Jeju volcanic ash soils. Lysimeter study consisted of thirteen treatments : fallow, fallow with weeding, cropping without fertilizer and compost, three N fertilizer soil surface applications(16, 32, 64kg/10a), three N fertilizer and compost soil surface applications(16+800, 32+1600, 64+32kg/10a), two water dissolved N fertilizer applications(16, 32kg/10a), and low and high plant densities. N fertilizer was applied as urea. The growth of com(preceding crop) and potatoes(succeeding crop) and leaching loss were determined during the experimental period. The results obtained were summarized as follows ; With Increased N, pH of leachate tended to decrease and NO$_3$-N concentration of leachate increased. NO$_3$-N leaching loss was remarkably greater in soil from the bare plot without fertilization and the weed control than from plots with medium N rate and was least in the cropping plot without fertilization. NO$_3$-N concentration in leachates from the water dissolved N fertilizer application plots was 64% of that from the soil surface application plots. The concentration of Ca and K ions and the leaching loss of these ions were least from the cropping plot without fertilization and were greatest from bare plots(T1 and T2) without fertilization. The proportion of leaching and residual N in soil increased as N rate increased indicting that higher N rates increase the possibility of N leaching to subsoil layer The proportion of N leaching losses was lower at the low N rate and the high plant density. In future, fertilization prescription which can maximize fertilizer use efficiency and minimize the pollution of ground water will be needed for conserving the environments.

• Korean Journal of Organic Agriculture
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• v.25 no.2
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• pp.329-344
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• 2017

This study was carried out to investigate the hot pepper yield, chemical properties of soil and distribution of animalcule with split irrigation and input of organic matter under no-tillage hot pepper green house condition. After experiment, soil pH maintained range of 5.6~6.2 in whole treatments. Organic matter content of soil was range of $32{\sim}42g{\cdot}kg^{-1}$. Soil salinity (EC) content of soil was range of $1.0{\sim}2.7dS{\cdot}m^{-1}$. Exchangeable cations in soil were range of $0.08{\sim}0.24cmol^+{\cdot}kg^{-1}$ in K, $9.5{\sim}12.8cmol^+{\cdot}kg^{-1}$ in Ca, and $2.7{\sim}3.2cmol^+{\cdot}kg^{-1}$ in Mg. Avaliable phosphorus ($P_2O_4$) content in soil was range of $1,011{\sim}1,137mg{\cdot}kg^{-1}$. Yield of pepper was more decreased in treatment of soybean cake fertilizer than no-treatment of soybean cake fertilizer. Yield of pepper in treatment of soybean cake fertilizer was increased at 33% of standard fertilizer application. Yield of pepper in no-treatment of soybean cake fertilizer was increased at 33% and 66% of standard fertilizer application. Number of fruits was increased range of 12.5~34.9% at half division irrigation compared with whole quantity irrigation. Yield of pepper was increased range of 13.5~34.4% at half division irrigation compared with whole quantity irrigation. Nine index of nature status and 271 Individual were captured in treatment of soybean cake fertilizer. Five index of nature status and 54 Individual were captured in treatment of soybean cake fertilizer. Nature status for environmental change as index organism was 11 points and 5 points, at treatment of soybean cake fertilizer and no-treatment of soybean cake fertilizer, respectively.