• Journal of Environmental Science International
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• v.10 no.4
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• pp.281-286
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• 2001

Wastewater from the pigment industry has high levels of organics and is known as hardly biodegradable. The objective of this study is to evaluate the applicability of aerobic fixed-bed boifilm reactor packed with ceramic support carrier for the pigment wastewater treatment. Orange 2(widely used azo pigment) adsorption experiment onto biofilm and activated sludge, and continuous treatment experiments were performed. In batch adsorption experiment, maximum adsorption quantity of biofilm was at least two times higher than that of activated sludge. In continuous experiment using aerobic fixed-bed biodilm reactor, the influent concentration of COD and Orange 2 were 75~500mg/${\ell}$(0.45~3.00kg COD/$m^3.day), 5~50mg/$\ell$(0.03~0.30kg Orange 2/$m^3$.day), respectively. At a COD loading rate 2.5kg COD/$m^3$.day and Orange 2 loading rate of 0.18kg Orange 2/$m^3$.day, removal efficiency of COD and Orange 2 were over 95%, 97%, respectively.

• Journal of Environmental Health Sciences
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• v.16 no.1
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• pp.21-28
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• 1990

As a research for treatment of waste water by biological method, we investigated general characteristics of waste water and isolated some useful bacteria which effectively treated waste water. Compositions of waste water were analyzed to give COD 2060 ppm, PVA 560 ppm, T-N 50 ppm, T-P 3.3 ppm and PH 12. Also, we inverstigated optimum nutrients requirement and growth conditions by mixed culture as well as the effect of coagulants. The COD removal rate reached maximum state for 48 hrs culture at pH 7.0 and 30$^{\circ}$C. Alum as the coagulated was the most effective. The COD removal rate was also increased by supplementing 10 ppm phosphorous sources as additional nutrients. The COD of waste water was reduced to 10% of its initial value by the continuous culture. As a result of overall experiments the COD of effluents became about 100 ppm and final pH 7.

• Journal of Environmental Health Sciences
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• v.35 no.1
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• pp.53-57
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• 2009

In order to treat the complex wastewater containing organic compound and solids, pre-treatment system associated with molecular separation process were investigated. The reductions of COD and turbidity were obtained after coagulation processes using Alum (Aluminium sulfate, $Al_2(SO_4)_2{\cdot}18H_{2}O$) and PACl (poly aluminium chloride as 17% $Al_{2}O_{3}$). The results of study were as follows: using variable dosage of Alum, COD removal was highest at 4,000 mg/l, and the reduction of COD and turbidity was 42% and 92%, respectively. The optimum coagulation would be effective at pH 7.3 than pH 9.0 by the addition of alum at a concentration of 6,000 mg/l and PACl was add at 4.25% in raw complex wastewater with 2,000 mg/l alum at pH 7.3, the reduction of COD was reduced by 32%. But coagulation aid experiments indicated that PACl would be more effective in sludge separation ability than COD removal efficiency.

• Journal of Environmental Science International
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• v.18 no.6
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• pp.667-674
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• 2009

This study has carried out to evaluate the effect of NaCI as electrolyte of single (electrolysis and UV process) and complex (electrolysis/UV) processes for the purpose of removal and mineralization of Rhodamine B (RhB) dye in water. It also evaluated the synergetic effect on the combination of electrolysis and UV process. The experimental results showed that RhB removal of UV process was decreased with increase of NaCl, while RhB removal of electrolysis and electrolysis/UV process was increased with increase of NaCI. The decolorization rate of the RhB solution in every process was more rapid than the mineralization rate identified by COD removal. The latter took longer time for further oxidation. Absorption spectra of an aqueous solution containing RhB showed a continued diminution of the RhB concentration in the bulk solution: concomitantly, no new absorption peaks appeared. This confirmed the decolorization of RhB, i.e., the breakup of the chromophores. It was observed that RhB removal in electrolysis/UV process is similar to the sum of the UV and electrolysis. However, it was found that the COD of RhB could be degraded more efficiently by the electrolysis/UV process than the sum of the two individual process. A synergetic effect was demonstrated in electrolysis/UV process.

• Journal of Korean Society of Water and Wastewater
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• v.24 no.4
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• pp.407-412
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• 2010

The purpose of this study was to investigate removal efficiencies of contaminants in night soil treatment plant using the B3 system. The samples were collected from retaining tank and settlement tank in Yechon night soil plant. We experimented concentrations of BOD, COD, SS, TN and TP. Concentration data were processed using removal efficiencies by season and correlation analysis with pilot running parameters. Removal efficiencies of total organic carbon was over 96%, TN was 98% during summer, 80.9% during winter. In the case of TP, the highest removal efficiencies was 94.1% during fall and the lowest removal efficiencies was 82% during spring. Results of correlation analysis showed two positive correlation groups and one negative group. Positive correlations were among temperature, BOD and TN. The others were pH, BOD, COD, SS, TN and TP. Negative correlation were among MLSS, BOD, COD, SS, TN, TP.

• Journal of Korean Society of Water and Wastewater
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• v.24 no.1
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• pp.5-14
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• 2010

A pilot-scale biological aerated filter (BAF) was operated with an anaerobic, anoxic and oxic zone at $23{\pm}1^{\circ}C$. The influent sCOD and total nitrogen concentrations in the feedwater were approximately 250 mg/L and 35 mg N/L, respectively. sCOD removal at optimum hydraulic retention time (HRT) of 3 hours with recirculation rates of 100, 200 and 300% in the column was more than 96%. Total nitrogen removal was consistently above 80% for 4 and 6 hours HRT at 300% recirculation. For 3 hours HRT and 300% recirculation, total nitrogen removal was approximately 79%. Based on fitting results, the kinetic parameter values on nitrification and denitrification show that as recirculation rates increased, the rate of ammonia and nitrate transformation increased. The ammonium loading rates for maximum ammonium removed were 0.15 and 0.19 kg $NH_3$-N/$m^3$-day for 100% and 200% recirculation, respectively. The experimental results demonstrated that the BAF can be operated at an HRT of 3 hours with 200 - 300% recirculation rates with more than 96 % removal of sCOD and ammonium, and at least 75% removal of total nitrogen.

• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3521-3526
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• 2014

A magnetic sonophotocatalyst $Fe_3O_4@SiO_2@TiO_2$ is synthesized for the enhanced biodegradability of organophosphate pesticide. The as-prepared catalysts were characterized using different techniques, such as X-ray diffraction (XRD) and transmission electron microscopy (TEM). The radial sonophotocatalytic activity of $Fe_3O_4@SiO_2@TiO_2$ nanocomposite was investigated, in which commercial dichlorvos (DDVP) was chosen as an object. The degradation efficiency was evaluated in terms of chemical oxygen demand (COD) and enhancement of biodegradability. The effect of different factors, such as reaction time, pH, the added amount of catalyst on $COD_{Cr}$ removal efficiency were investigated. The average $COD_{Cr}$ removal efficiency reached 63.13% after 240 min in 12 L sonophotocatalytic reactor (catalyst $0.2gL^{-1}$, pH 7.3). The synergistic effect occurs in the combined sonolysis and photocatalysis which is proved by the significant improvement in $COD_{Cr}$ removal efficiency compared with that of solo photocatalysis. Under this experimental condition, the $BOD_5/COD_{Cr}$ ratio rose from 0.131 to 0.411, showing a remarkable improvement in biodegradability. These results showed that sonophotocatalysis may be applied as pre-treatment of pesticide wastewater, and then for biological treatment. The synthesized magnetic nanocomposite had good photocatalytic performance and stability, as when it was used for the fifth time, the $COD_{Cr}$ removal efficiency was still about 62.38%.

• Journal of Environmental Science International
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• v.12 no.10
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• pp.1085-1093
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• 2003

This study was conducted to investigate anoxic-RBC (rotating biological contactor) and its application in advanced municipal wastewater treatment process to remove biologically organics and ammonia nitrogen. Effluent COD and nitrogen concentration increased as the increase of volumetric loading rate. But, the concentration changes of NO$_2$$\^$-/ -N and NO$_3$$\^$-/ -N were little, as compared to COD and NH$_4$$\^$+/ -N. When the volumetric loading rate increased, COD removal efficiency and nitrification appeared very high as 96.7∼98.8% and 92.5∼98.8%, respectively. However, denitrification rate decreased to 76.2∼88.0%. These results showed that the change of volumetric loading rate affected to the denitrification rate more than COD removal efficiency or nitrification rate. The surface loading rates applied to RBC were 0.13～6.0lg COD/㎡-day and 0.312∼1.677g NH$_4$$\^$+/-N㎡-day and they were increased as the increase of volumetric loading rate. However, the nitrification rate showed higher than 90%. The thickness of the biofilm in RBC was 0.130 ∼0.141mm and the density of biofilm was 79.62∼83.78mg/㎤. They were increased as surface loading rate increased. From batch kinetic tests, the k$\_$maxH/ and k$\_$maxN/ were obtained as 1.586 g C/g VSS-day, and 0.276 g N/g VSS-day, respectively. Kinetic constants of denitrifer in anoxic reactor, Y, k$\_$e/, K$\_$s/, and k were 0.678 mg VSS/mg N, 0.0032 day$\^$-1/, 29.0 mg N/l , and 0.108 day$\^$-l/, respectively. P and K$\_$s/, values of nitrification and organics removal in RBC were 0.556 g N/㎡-day and 18.71 g COD/㎡-day, respectively.

• Membrane Journal
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• v.20 no.3
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• pp.241-248
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• 2010

The effect of organic material loadings on nutrient removal characteristics were investigated in sequencing batch reactor, in which a flat sheet type microfiltration membrane with a pore size of $0.4\;{\mu}m$ was submerged. Three organic concentrations of 200 mg/L (Run-1), 400 mg/L (Run-2) and 800 mg/L (Run-3) were carried out continuously to identify their effect on the filtration performance and nutrient removal. The removal efficiencies of T-N and T-P were increased with the increase of COD/N and COD/P. The T-N removal efficiencies of Run-1, Run-2 and Run-3 were 28.1, 32.6 and 90.4%, the average concentrations of T-N in permeate were 32.0, 30.0, and 4.3 mg/L, respectively. The T-P removal efficiencies of Run-1, Run-2 and Run-3 were 13.6, 35.3 and 93.1%, the average concentrations of T-P in permeate were 3.11, 2.33, and 0.25 mg/L, respectively.

• KSBB Journal
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• v.17 no.3
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• pp.241-246
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• 2002

Today, many problems of dye-processing wastewaters were raised due to industry of dyeing and textiles. It is difficult to treat them perfectly because they contain many poorly degradable matters, such as surfactants, ethylene glycol, polyvinyl alcohol, and so on. To improve the performances of conventional physicochemical treatment and activated sludge process, new systems of combining jet-loop reactor (JLR) with physicochemical treatment were developed. Volumetric oxygen transfer coefficient ($k_{L}a$) of JLR was significantly larger than that of air-lift reactor. Also, for the effective treatment of dye-processing wastewater, JLR with active carbon supports (JLRAS) were investigated. Removal efficiency of BOD, $COD_{Mn}$, $COD_{Cr} and color were found as 99, 86, 84, 83%, respectively, when HRT was 8 hrs. And performance of JLRAS was rapidly restored after step change of $COD_{Mn}$ loading late. The optimal coagulant and dosage of second physicochemical treatment after JLRAS were polyferric sulfate and 130 mg/L, respectively, when removal efficiencies of $COD_{Mn} and color were 85 and 73%, respectively. In conclusion, this system enables the reduction of operation cost, and the effective removal of many organics.