• 제목/요약/키워드: COD loading rate

검색결과 222건 처리시간 0.03초

유량-오염부하량 관계식과 요인분석을 이용한 경안천의 수질특성 평가 (Evaluation of Water Quality Characteristics at Kyeongan Stream Using the Flow-Loading Equation and Factor Analysis)

  • 권필상;박민지;이영준;조용철;노창완;정우석;김지호;유순주
    • Ecology and Resilient Infrastructure
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    • 제4권4호
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    • pp.226-236
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    • 2017
  • 본 연구에서는 경안천의 10년 수질변화 특성을 분석하고 유량-오염부하량 관계식을 이용하여 고찰하였다. 통계분석을 이용하여 수질 항목간의 상관분석과 수질에 영향을 미치는 요인분석을 하였다. 수질변화 특성 결과 $BOD_5$, $COD_{Mn}$, TOC는 연도별로 증가와 감소를 반복하는 것으로 나타났고 TN, TP는 연도별로 감소하는 것으로 나타났다. 유량-오염부하량 관계식을 통한 오염물질 유출특성결과 유량 증가 시 $BOD_5$, $COD_{Mn}$, TOC, TN농도는 감소하였으나, TP농도 변화에는 영향을 주지 않는 것으로 나타났다. 상관분석 결과 $BOD_5$$COD_{Mn}$, TOC의 상관계수가 0.890 (p<0.01), 0.721 (p<0.01)로 상관성이 통계적으로 높게 나타났다. 요인분석결과 경안천은 유기물 지표항목에 의한 요인이 가장 크며 계절변화에 따른 질소물질에 의한 요인, 유량증가에 따른 부유물질 유입요인 순으로 수질에 영향을 받고 있는 것으로 설명할 수 있다.

연속 회분식 고온 혐기성 공정의 운전특성 연구 (Operational Characteristics of the Anaerobic Sequencing Batch Reactor Process at a Thermophilic Temperature)

  • 이종훈;정태학;장덕
    • 상하수도학회지
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    • 제11권1호
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    • pp.33-41
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    • 1997
  • An attempt was made to enhance anaerobic treatment efficiency by adopting the anaerobic sequencing batch reactor(ASBR) process at a thermophilic temperature. Operational characteristics of the ASBR process were studied using laboratory scale reactors and concentrated organic wastewater composed of soluble starch and essential nutrients. Effects of fill to react ratio (F/R) were examined in the Phase I experiment, where the equivalent hydraulic retention time(HRT) was maintained at 5 days with the influent COD of 10g/L. A continuous stirred tank reactor(CSTR) was operated in parallel as a reference. Treatment efficiency was higher for the ASBRs because of continuous accumulation of volatile suspended solids(VSS) compared to the CSTR. However, the rate of gas production and organic removal per unit VSS in the ASBRs was much lower than the CSTR. This was caused by reduced methane fermentation due to accumulation of volatile acids(VA), especially for the case of low F/R, during the fill period. When the F/R was high, maximum VA was low and the VA decreased in short period. Consequently, more stable operation was possible with higher F/R. Effects of hydraulic loading rate on the efficiency was studied in the Phase II experiment, where the organic loading rate was elevated to 3333mg/L-d with the F/R of 0.12. Reduction of organic removal along with rapid increase of VA was observed and the stability of reaction was seriously impaired, when the influent COD was doubled. However, operation of the ASBR was quite stable, when the hydraulic loading rate was doubled and a cycle time was adjusted to 12 hour. It is essential to avoid rapid accumulation of VA during the fill period in order to maintain operational stability of the ASBR.

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모래와 굴패각을 이용한 인공습지 오수처리장치 개발 (Development of Constructed Wetland using Sand and Oyster shell for Sewage Treatment)

  • 박현건;이춘식;이홍재;서동철;허종수
    • 한국물환경학회지
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    • 제20권5호
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    • pp.437-446
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    • 2004
  • To develop sewage treatment apparatus by natural purification method, the sewage treatment plant that consisted of aerobic and anaerobic plot was constructed. And then, the effects of treatment conditions on the removal of pollutants in the relation to sewage loading, sewage injection method and season according to the pebble kind. Removal rate of BOD and COD according to the sewage loading in effluent were over 95 and 77%, respectively. Removal rate of nitrogen in treated water by aerobic plot and effluent using sand were about 22~40 and 49~75%, respectively. Those of effluent using sand 75%+ oyster shell 25% and sand 50%+ oyster shell 50% as filter media in comparison with using sand were about 7~25 and 16~23%, respectively. Removal rate of phosphorus in treated water by aerobic plot and effluent using sand as filter media were about 30~36 and 52~56%, respectively. Those of effluent using sand 75%+ oyster shell 25% and sand 50%+ oyster shell 50% in comparison with using sand as filter media were about 11~40 and 12~45%, respectively. Removal efficiency of BOD and COD according to the intermittent injection method of sewage were slightly decreased, but those of nitrogen and phosphorus were little varied in comparison with continuous injection method. Removal efficiency of BOD and COD in winter in comparison with the others were little varied, but those of nitrogen and phosphorus slightly decreased.

상향류 혐기성 블랭킷 반응조를 이용한 프로피온산의 혐기성 처리시 고농도 황산염의 영향 (Effect of High Concentration of Sulfate on Anaerobic Digestion of Propionic Acid Using an Upflow Anaerobic Sludge Blanket)

  • 이채영
    • 유기물자원화
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    • 제16권3호
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    • pp.75-82
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    • 2008
  • 상향류 혐기성 슬러지 블랭킷 반응조을 이용한 프로피온산의 처리시 고농도 황산염의 영향을 조사하였다. 반응조의 평균 유기물 부하와 수리학적 체류시간은 $1.2kg \;COD/m^3{\cdot}d$와 1.6일로 유지하였다. 황산염이 없는 조건에서 UASB 반응조의 경우 95%의 COD 제거율을 보였으며 황산염이 $2,000mgSO_4^{2-}/L$로 존재하는 경우 용존 황화물의 영향으로 COD 제거율이 83%로 감소하였다. 메탄 생성균과 황산염 환원균의 경쟁관계를 평가하기 위하여 미생물의 상호작용에 관해 조사하였다. $COD/SO_4^{2-}$ 비가 1인 경우 이용 가능한 전자 수용체의 평균 58%가 메탄 생성균에 의해 이용되며 나머지가 황산염 환원균에 의해 사용되었다. 초산과 프로피온산을 기질로 이용한 비메탄 활성도의 경우 미생물이 기질에 적응함에 따라 증가하였다.

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Microbial and Physicochemical Monitoring of Granular Sludge During Start-up of Thermophilic UASB Reactor

  • Ahn, Yeong-Hee;Park, Sung-Hoon
    • Journal of Microbiology and Biotechnology
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    • 제13권3호
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    • pp.378-384
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    • 2003
  • Mesophilically-grown granular sludge seeded in thermophilic UASB reactor was monitored to better understand the start-up process of the reactor. The reactor was fed with a synthetic wastewater containing glucose. As COD loading rate increased stepwise, methane production rate increased. Maximum values of COD removal efficiency (95%) and methane production rate (5.3 l/day) were achieved by approximately day-80 and remained constant afterward. However, physicochemical and microbial properties of granules kept changing even after day-80. Specific methanogenic activity (SMA) was initially negligible, and increased continuously until day-153 and remained constant afterward, showing the maximum value of $1.51{\pm}0.13\;g\;CH_4-COD/g$ VSS/day. Deteriorated settling ability of granules recovered the initial value by day-98 and was maintained afterward, as determined by sludge volume index. Initially reduced granule size increased until day-126, reaching a plateau of 1.1 mm. Combined use of fluorescence in situ hybridization and confocal laser scanning microscopy (CLSM) allowed to localize families of Methanosaetaceae and Merhanosarcinaceae in granules with time Quantitative analyses of CLSM images of granule sections showed abundance patterns of the methanogens and numerical dominance of Methanosaeta spp. throughout the start-up period. The trend of SMA agreed well with abundance patterns of the methanogens.

생물학적 영양염류 제거를 위한 돈사폐수의 반응 특성 (Reaction Characteristics of Piggery Wastewater for Biological Nutrient Removal)

  • 한동준;류재근;임연택;임재명
    • 환경위생공학
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    • 제13권1호
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    • pp.44-56
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    • 1998
  • This study was performed to investigate the reaction characteristics of piggery wastewater for biological nutrient removal. The reaction characteristics were discussed the fraction of organics, the behavior of nitrogen, nitrification, denitrification, and the behavior of phosphorus. The fraction of readily biodegradable soluble COD was 11-12 percent. The ammonia nitrogen was removed via stripping, nitrification, autotrophic cell synthesis, and heterotrophic cell synthesis. The removal percents by each step were 12.1%, 68.9%, 15.0%, and 4.0%, respectively. Nitrification inhibition of piggery wastewater was found to occur at an influent volumetric loading rate over 0.2 NH$_{3}$-N kg/m$^{3}$/d. Denitrification rates were the highest in the raw wastewater and the lowest in the anaerobic effluent. The denitritation of piggery wastewater came out to be possible, and the rate of organic carbon consumption decreased about 10 percent. The phosphorus removed was released in the form of ortho-p in the aerobic fixed biofilm reactor, it was caused by autooxidation. The synthesis and release of phosphorus were related to the ORP and the boundary value for the phase change was about 170mV. In the synthesis phase, the phosphorus removal rate per COD removed was 0.023mgP$_{syn}$/mgCOD$_{rem}$. The phosphorus contents of the microorganism were 4.3-6.0% on a dry weight basis.

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Performance Evaluation of Anaerobic Bioreactors and Effects of Ammonia on Anaerobic Digestion in Treating Swine Wastewaters

  • Lee, Gook-Hee;Seo, Jun-Won;Kim, Jong-Soo
    • 한국환경농학회지
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    • 제25권3호
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    • pp.195-201
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    • 2006
  • The operational characteristics of anaerobic bioreactors in treating swine wastewater were evaluated upto hydraulic retention time (HRT) of 1 day and organic loading rate (OLR) of $5.1kg-COD/m^3{\cdot}d$ for 200 days. The bioreactors were effective in treating swine wastewaters with COD removal efficiency of $78.9{\sim}81.5%$ and biogas generation of $0.39{\sim}0.59m^3/kg-COD_r$ at OLR of $1.1{\sim}2.2kg-COD/m^3{\cdot}d$. The two-stage ASBF anaerobic bioreactors was effective in treating different characteristics of swine wastewaters since they showed high and stable COD removal efficiency at high OLR due to effective retention of biomass by media and staging. The effects of ammonia on anaerobic digestion were investigated by operating two-stage ASBF reactors using swine wastewaters as influent without and with ammonia removal at HRT of $1{\sim}2$ days and OLR of $2.2{\sim}9.6kg-COD/m^3{\cdot}d$ for 250 days. The COD removal efficiency and biogas generation of two-stage ASBF reactors was decreased by increasing influent ammonia concentrations to 1,580 mg (T-N)/L with increasing OLR to $6.3kg-COD/m^3{\cdot}d$, while those were increased by maintaining influent ammonia concentrations below 340 mg (T-N)/L by MAP precipitation with increasing OLR to $9.6kg-COD/m^3{\cdot}d$. Initial inhibition of ammonia on anaerobic processes was observed at a concentration of 760 mg (T-N)/L and the COD removal efficiency and biogas generation dropped to 1/2 at ammonia concentration ranges of $1,540{\sim}1,870mg$ (T-N)/L. It is essential to remove ammonia in swine wastewaters to an initial inhibition level before anaerobic processes for the effective removal of COD.

분뇨(糞尿)의 혐기성(嫌氣性) 소화시(消化時)의 암모니아의 독성(毒性)에 관한 연구(硏究) (Inhibitory Effects of Ammonium Nitrogen on the Nightsoil Digestion)

  • 최의소
    • 대한토목학회논문집
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    • 제5권2호
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    • pp.75-81
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    • 1985
  • 분뇨(糞尿) 내의 많은 암모니아의 독성여부(毒性與否)를 검토(檢討)하는 것이 본(本) 연구(硏究)의 목적(目的)이었는데 실험실(實驗室) 소화조(消化槽)가 이용(利用)되었다. 암모니아의 저해작용(沮害作用)은 1.5g/l 정도에서는 관측되었다. 따라서, 이러한 저해작용(沮害作用)을 감소시키기 위하여 분뇨(糞尿)를 희석하여 주입시키는 방법(方法)이 사용될 수 있는데, 희석에 의한 체류기간(滯留期間)의 단축으로 말미암아 소화조(消化槽) 내의 미생물(微生物)이 유실(流失)되므로 사용가능(使用可能)한 희석배수에는 제한(制限)이 있으며, 아울러 적용가능(適用可能)한 유기물질(有機物質) 부하율(負荷率)에도 제한(制限)이 있었다. 1 : 1로 희석시키는 것이 가장 효율적(效率的)인 것으로 나타났는데, 이 때에 적용가능(適用可能)한 최대(最大) 부하율(負荷率)은 $5kg\;COD/m^3/d$ 였다.

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Membrane Bioreactor를 이용한 폭발성 물질의 가수분해 부산물의 탈질과정에의 적용 (Application of a Membrane Bioreactor in Denitrification of Explosives Hydrolysates)

  • 조경덕
    • 한국물환경학회지
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    • 제18권2호
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    • pp.113-122
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    • 2002
  • A bench-scale anoxic membrane bioreactor (MBR) system, consisting of a bioreactor coupled to a ceramic crossflow ultrafiltration module, was evaluated to treat a synthetic wastewater containing alkaline hydrolysis byproducts (hydrolysates) of RDX, The wastewater was formulated the same as RDX hydrolysates, and consisted of acetate, formate, formaldehyde as carbon sources and nitrite, nitrate as electron accepters. The MBR system removed 80 to 90% of these carbon sources, and approximately 90% of the stoichiometric amount of nitrate, 60% of nitrite. The reactor was also operated over a range of transmembrane pressures, temperatures, suspended solids concentration, and organic loading rate in order to maximize treatment efficiency and permeate flux. Increasing transmembrane pressure and temperature did not improve membrane flux significantly. Increasing biomass concentration in the bioreactor decreased the permeate flux significantly. The maximum volumetric organic loading rate was $0.72kg\;COD/m^3/day$, and the maximum F/M ratio was 0.50 kg N/kg MLSS/day and 1.82 kg COD/kg MLSS/day. Membrane permeate was clear and essentially free of bacteria, as indicated by heterotrophic plate count. Permeate flux ranged between 0.15 and $2.0m^3/m^2/day$ and was maintained by routine backwashing every 3 to 4 day. Backwashing with 2% NaOCl solution every fourth or fifth backwashing cycle was able to restore membrane flux to its original value.

역 유동층 생물막 반응기에서 수리학적 부하가 생물막 성상에 미치는 영향 (Effect of Hydraulic Loading on Biofilm Characteristics in an Inverse Fluidized Bed Biofilm Reactor)

  • 김동석;최윤찬
    • 한국환경과학회지
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    • 제4권3호
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    • pp.221-228
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    • 1995
  • Stability of reactor and effect on biofilm characteristics were investigated by varying the hydraulic residence time in an inverse fluidized bed biofilm reactor(IFBBR). The SCOD removal efficiency was maintained above 90 % in the HRT range of 12hr to 2hr, but the TCOD removal efficiency was dropped down to 50% because of biomass detachment from overgrown bioparticles. The reactor was stably operated up to the conditions of HRT of 2hr and F/M ratio of 4.5kgCOD/$m^3$/day, but above the range there was an abrupt increase of filamentous microorganisms. The optimum biofilm thickness and the biofilm dry density in this experiment were shown as $200\mu\textrm{m}$ and $0.08 g/cm^3$, respectively. The substrate removal rate of this system was found as 1st order because the biofilm was maintained slightly thin by the increased hydraulic loading rate.

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