• Title/Summary/Keyword: COD Test

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Development of a New Process for PVA Degradation in Desize Wastewater by lmmobilized Symbiotic Bacteria (고정화 공생 Bacteria를 이용한 호발폐수 중 PVA분해 신공정 개발)

  • 김정목;조무환조윤래정선용
    • KSBB Journal
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    • v.6 no.4
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    • pp.395-402
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    • 1991
  • A new process was developed to degrade PVA(polyvinyl alcohol) in desize wastewater. Two symbiotic bacteria of Pseudomonas strain G5Y and PW were immobilized on the media by adsorption. A natural zeolite was chosen as the best media considering cell adhesion capacity, sedimentation rate, and material cost. PVA and COD removal efficiencies of this system for synthetic wastewater were 84% and 85% at the retention time of 6 hr, when the volumetric loading rate was PVA 8g/L·day and COD 8g/L·day, and cell density was 19,775 mg/L. In case of desire wastewater, they were 78% and 72% at the retention time of 6 hr, respectively, when the volumetric loading rate was PVA 8g/L·day and COD 13.2g/L·day, and cell density was 32,899mg/L. In case of desize wastewater, PVA and COD removal efficiencies were lower than synthetic wastewater, but cell density of the desize wastewater was lower than that of the synthetic wastewater, because there were insufficiency of necessary nutrition and variety of desize materials in the desize wastewater. A pilot test was successfully performed showing 88% and 82%, PVA and COD removal efficiencies at the retention time of 24 hr, when volumetric loading rate were 4.7 PVA g/L·day and COD 6.9g/L·day, and cell density was 12,,324 mg/L.

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Statistical Analysis of Water Quality in the Downstream of the Han River (한강하류부 수질의 통계학적 해석)

  • 백경원;정용태;한건연;송재우
    • Water for future
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    • v.29 no.2
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    • pp.179-190
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    • 1996
  • The characteristics of water quality in the downstream of the Han River were analyzed by statistical techniques. Basic characteristics, areal and temporal variations, and correlations of water quality data were investigated. Monthly water quality data have been investigated systematically by exploring data analysis, including time series plot, summary statistics, distribution test, time dependence test, seasonality test and flow relatedness test. Results show that water quality data in this river have seasonality. And applicability of stochastic models such as Thomas-Fiering model and ARMA(1,1) model was identified. From the examination of water quality data related to discharge, it was found that DO and SS are sensitive to water temperature rather than discharge, while BOD and COD are sensitive to discharge at dry seasons. Seasonal periodicities were identified in all water quality variables from the cross correlation analysis.

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Characteristic evaluation of anaerobic co-digestion using desulfurization sludge and primary sludge (탈황슬러지 및 생슬러지를 이용한 혐기성 병합소화 특성평가)

  • Seulki Koo;Woojin Chung;Soonwoong Chang;Myoungsoo Park
    • Journal of the Korea Organic Resources Recycling Association
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    • v.31 no.4
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    • pp.51-58
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    • 2023
  • In this study, anaerobic co-digestion was carried out using desulfurization sludge and sewage sludge (primary sludge) to evaluate the effects of sulfur compounds in anaerobic digestion. The experiment was carried out in the form of a batch test using 500 mL duran bottle, and the mixing ratio of the feedstock was selected based on the ratio of COD/SO4. As a result of the experiment, it was confirmed that the amount of biogas generated and the yield decreased at the mixing ratio of COD/SO4 20 or less. In particular, below COD/SO4 10, it was lower than seed (283.5 mL) which was set without feedstock to correct biogas generated by itself from seed sludge. Methane yield tended to decrease from a ratio of COD/SO4 20 or less to 0.135 m3/kg VS compared to 0.396 m3/kg VS of COD/SO4 50. In addition, compared to 0.0097 m3/kg VS of hydrogen sulfide yield from COD/SO4 50, the ratio of COD/SO4 20 increased sharply to 0.0223 m3/kg VS, and in particular, the highest result was 0.0855 m3/kg VS in COD/SO4 10. Based on these results, it is judged that the effect of sulfide in anaerobic digestion can have an adverse effect if the COD/SO4 ratio decreases to less than 20.

A Study on the Treatment of Distillery Wastewater by Single-phase and Two-phase Anaerobic Digestion (단상(單相) 및 2상(相) 혐기성(嫌氣性) 소화(消化)에 의한 주정폐수(酒精廢水) 처리(處理)에 관한 연구(硏究))

  • Choung, Young Kyoo;Rah, Seung Woo;Park, Joon Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.7 no.1
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    • pp.5-12
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    • 1993
  • The objectives of this paper are to present data to illustrate how an advanced digestion process, two-phase digestion, can provide superior performance in terms of waste stabilization efficiency and net energy recovery. As the result, it is possible to separate enrichment cultures of acidogenic and methanogenic organisms in isolated environments by kinetic control involving manipulation of dilution rates. In single-phase digestion process, HRT and COD loading for effective operation were 14.29 days and 2.33kg $COD/m^3$ day, but two-phase digestion may be conducted efficiently at 7 days of HRT and 5.71kg $COD/m^3$ day of loading. Data from this studies showed that the two-phase process is better than single-phase digestion under all test conditions when compared on the bases of gas yield and production rate, reductions of COD and VS, buffer capacity, and unconverted volatile acids in the effluent.

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A Study on the Treatment of Landfill Leachate using Membrane and Evaporator (Lab Test) (분리막과 증발기를 이용한 매립지 침출수 처리에 관한 연구 (Lab test))

  • Kang, Shin-Gyung;Park, Yung-Kyu
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.12
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    • pp.2125-2134
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    • 2000
  • This research was to develope the economical treatment processes of the landfill leachate to meet the legal discharge standards. To achieve this purpose, experiments were conducted in laboratory to choose the optimum process and to obtain the design factors before a pi!ot-scale test. The concept of the process developing in this research was using the reverse osmosis system. The submerged membrane bio-reactor was used to achieve pre-treatment of reverse osmosis system and the concentrate was treated by evaporator with land fill gas as a fuel. The results of the research showed that SS, $BOD_5$, $COD_{cr}$, $NH_4{^+}-N$ and T-N were removed 99.0%, 43.0%, 12.9%, 48.5% and 18.7% respectively in the submerged membrane bio-reactor. The reverse osmosis system could remove $BOD_5$, $COD_{cr}$, $NH_4{^+}-N$ and T-N as an efficiency of97.5%, 97.6%, 79.7% and 85.4% respectively. The evaporator could remove $COD_{cr}$, $NH_4{^+}-N$ and T-N as an efficiency of 90.5%, 50.6% and 63.3% respectively. However the condensed water of the evaporator was not satisfied the legal standard and should be treated in reverse osmosis with the pre-treated leachate.

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Estimation of Ultimate Methane Yields and Biodegradability from Urban Stream Sediments Using BMP Test (BMP(Biochemical Methane Potential) test를 통한 도심하천 퇴적물의 최종메탄발생수율 및 생분해도 산정)

  • Song, Jaehong;Kim, Seogku;Lee, Junki;Koh, Taehoon;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.2
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    • pp.33-42
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    • 2010
  • The main objective of this study was to offer informations about the current conditions of stream sediments and to evaluate biochemical methane potentials of stream sediments from the urban streams in Busan city using conventional BMP tests. First we select total 5 urban streams and collect sediment samples. Then, COD, proximate analysis, volatile solid, organic carbon content and elemental analysis were conducted to determine characteristics of the sediments. Results show that COD, volatile solid and organic carbon content are determined in the range of $15.20{\sim}75.07mg\;g^{-1}$, 2.34~11.54% and 1.28~34.21%, respectively. Also, several biochemical methane potential tests were performed in a laboratory. As a result, pH values of the reactors generally increased and then stabilized at 7.11~7.35. In addition, C/N ratio, ultimate methane and carbon dioxide yield (mL/g VS) and biodegradability (%) were determined to 1.05~10.27, 10.1~179.4, 10.3~34.4 and 4.0~30.1, respectively. For the determination of the correlations between ultimate methane yield and ultimate carbon dioxide yield, C/N ratio, COD, volatile solid and organic carbon content, a linear model was fitted to the data using a least-squares algorithm. As a result, except for COD ($r^2=0.7586$) and volatile solid ($r^2=0.7876$), Linear model was well fitted to each data with good values of the correlation coefficient ($r^2=0.9795{\sim}0.9858$). Finally, we propose empirical equations, which contain C/N ratio or TOC, for the prediction of ultimate methane yield for the urban streams in Busan city.

Non-parametric Trend Analysis Using Long-term Monitoring Data of Water Quality in Paldang Lake (장기 모니터링 자료를 이용한 팔당호 수질변화의 비모수적 추세분석)

  • Cho, Hang-Soo;Son, Ju-Yeon;Kim, Guee-Da;Shin, Myoung-Chul;Cho, Yong-Chul;Shin, Ki-Sik;Noh, Hye-Ran
    • Journal of Environmental Impact Assessment
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    • v.28 no.2
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    • pp.83-100
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    • 2019
  • This study, we conducted a non-parametric trend test (Seasonal Kendall tests, LOWESS) and Cross Correlation. We aimed to identify water quality trends using the weekly data for 9 variables (Water Temperature, EC, DO, BOD, COD, T-N, T-P, TOC and Chl-a) collected from 4 sites in the Paldang Lake from 2004.01 to 2016.12. According to the Seasonal Kendall test, Water temperature increased but EC, T-N and T-P decreased trend. LOWESS showed that BOD was gradually decreased from 2013 to 2016. but COD gradually increased between 2012 and 2016. As a result, it was confirmed that the period between 2012 and 2013 was a turning point in the increase of COD along with the decrease of BOD at all sites in Paldang Lake. Results of Cross Correlation showed that there was no time difference between all of Water variables and Sites. In this study, it is necessary to analyze the cause of the transition period and to monitoring the water quality more precisely for better water quality management in Paldang Lake.

A Rapid COD Test Procedure for Alkaline Permanganate Value Determination (알칼리성 $100^{\circ}C$에서 화학적 산소요구량 신속정량법)

  • Czae, Myung-Zoon;Ly, Suw-Young;Kim, Mi-Kyung
    • Analytical Science and Technology
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    • v.8 no.2
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    • pp.167-170
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    • 1995
  • A simple and rapid permanganate value test procedure for the estimation of COD, based on the photometric measurement of the remained permanganate after the color bleaching by oxygen demand organics during digestion, has been described. Optimized conditions were 1% NaOH, 0.6mM $KMnO_4$, with a closed reflux in the boiling water bath for 90 sec using sample size of 5mL.

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Treatment of Corn Starch Wastewater Using an UASB Reactor (UASB 반응조를 이용한 옥수수 전분폐수의 처리)

  • Shin, Hang-Sik;Bae, Byung-Uk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.13 no.4
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    • pp.269-275
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    • 1993
  • The performance of Upflow Anaerobic Sludge Blanket(UASB) reactor for treatment of corn starch wastewater was investigated using continuous and batch experiment. Results showed that the corn starch wastewater had different characteristics in terms of biodegradability and methane potential, depending on the manufacturing precess. COD removal efficiencies were maintained over 70% up to the loading rate of 3.2 kg $COD/m^3{\cdot}day$ and the maximum gas production rate was about 55 l/day, equivalent to 3.5 l/day per liter of reactor volume, at the loading rate of 8.4 kg $COD/m^3{\cdot}day$. In the anaerobic serum bottle test(SBT) carried out along with continuous operation, the sludge activity was found to increase from 0.03 to 0.53 g $COD-CH_4/g\;VSS{\cdot}day$ as granular sludges were developed in 130 days operation. SBT gave valuable informations on the characteristics of wastewaters to be treated as well as on the sludge activity. The overall morphological characteristics of granular sludges cultivated on corn starch wastewaters were similar to those cultivated on various organic industrial wastewaters such as distillery and sugar.

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