• 상하수도학회지
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• 제24권4호
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• pp.387-394
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• 2010

The influent COD of municipal wastewater has been divided into 4 fractions; readily soluble biodegradable, slowly particulate biodegradable, soluble and particulate unbiodegradable COD. The mathematical modeling of biological wastewater treatment processes and the design and operation of nutrient removal plants require a reliable and accurate estimate of the composition of influent wastewater COD. COD utilization rate is proportional to the oxygen uptake rate(OUR), so a batch biodegradation test with OUR measurement has been effectively used for the determination of COD fractionation. But the mathematical model of COD utilization and heterotrophs synthesis is essential to interpret the OUR measurement. Mamais method is another method for determining readily biodegradable soluble COD. Like the OUR test method, batch biodegradation test is necessary but it does not require mathematical model. These two methods for determining COD fractionation are introduced here in detail. Experimental results showed that COD composition by Mamais method is not different to that by OUR test method so, either of them can be used.

• Journal of Advanced Marine Engineering and Technology
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• 제12권3호
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• pp.57-67
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• 1988

Although handicapped by the inability to bridge the size gap between small laboratory sample and large engineering component, the V charpy test sample method does possess certain advantages, such as each of preparation, simplicity of test method, speed, low cost in test machinery, and low cost per test. On the other hand, the COD test method does posses advantages, which reduce the size gap between the laboratory sample and actual engineering component. Consequently, the correlation between V charpy absorbed energy and the critical COD value is required for estimating critical COD value from the simple V charpy test results. In this paper, the high tensile strength steel AH36 plate specimens having a single edge cracked notch were investigated to find out the correlation between V charpy absorbed energy and critical COD value in the welded parts under such various welding methods as shielded metal arc welding, the submerged arc welding and the electro gas welding by means of V charpy impact test and static 3-point bending test. Main results obtained are as follow ; 1. The relationships between V charpy absorbed energy Wc' and critical COD value ($\delta_c$)show; $\delta_c$=0.0065 Wc'+0.1906. 2. Ductile- brittle transition behaviours can be estimated by means of fracture appearance and general yielding behaviours. 3. The V charpy absorbed energy of SMAW is higher than that of SAW, EGW and similar relationships are obtained in the COD tests.

• 한국환경보건학회지
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• 제15권2호
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• pp.33-40
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• 1989

Dichromate reflux method for COD analysis is one of the useful and precise way to solve the organic content of the wastewater. But the standard procedure for COD is not entirely satisfactory for sample containing appreciable amounts of inhibiting substance, especially chloride ion. Under the conditions of the established test, a big disadvantage of the method is that dichromate oxidizes chloride quantitatively to chlorine. When it is necessary to use silver sulfate as a catalyst in the COD procedure, chloride must be removed before the addition of the catalyst. Silver sulfate and mecuric sulfate forms a precipitate of AgCl and HgCl$_{2}$ separately which is not completely oxidized during the test and, therefore, cannot be corrected for. So, we evaluate and compensate the amount of chloride oxidation in the absence of chemicals during the experimental procedure. Calculation of COD is made using the following reviced formula: real COD = tested COD - 0.2277Cl.

• 환경영향평가
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• 제4권2호
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• pp.93-103
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• 1995

This study was carried out to suggest the best statistical test to analyze the trend in monthly water quality data. Traditional parametric tests such as t-test and regression analysis are based on the assumption that the underlying population has a normal distribution and regression analysis additionally assumes that residual errors are independent. Analyzing 9-years monthly COD data collected at Paldang in Han River, the underlying population was found to be neither normal nor independent. Therefore parametric tests are invalid for trend detection. Four Kinds of nonparametric statistical tests, such as Run Test, Daniel test, Mann-Kendall test, and Time Series Residual Analysis were applied to analyze the trend in the COD data, Daniel test and Mann-Kendall test indicated upward trend in COD data. The best nonparametric test was suggested to be Daniel test, which is simple in computation and easy to understand the intuitive meaning.

• Journal of Welding and Joining
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• 제1권2호
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• pp.53-60
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• 1983

COD test based on fracture mechanics concept was used in this study to evaluate the fracture toughness quantitatively. Effects of specimen sizes on critical COD value for ABS EH 36 steel and its submerged arc weldments, and the variation of critical COD value depending on metallurgical/mechanical heterogeneities caused by weld thermal cycles were investigated. Experiment was performed by using specimens made from base metal and submerged arc weldments according to BS 5762. Obtained results are summarized as follows; 1) Critical COD value for base metal decreases with increasing thickness of specimen. On hand, as the reduction ratio of critical COD decreases with increasing specimen thickness, critical COD value becomes constant above a thickness of specimen. 2) Critical COD value for weldment decreases with increasing thickness of specimen and was also affected by metallurgical states of base metal. 3) Size effects for weldment was greater at the hardened region. 4) Critical COD value was affected by microstructural change due to weld thermal cycles in weldments; that is, accicular ferrite formation is favorable for increasing of COD value.

• 한국농공학회논문집
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• 제47권2호
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• pp.99-110
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• 2005

Characteristics of concentrations of total nitrogen (TN), total phosphorus (TP), and chemical oxygen demand (COD) pollutant in percolated water at four paddy field sites (Soro, Odong, Munui, and Boeun) were investigated by a nonparametric test. Percolation rate measurement and percolated water sampling were taken during irrigation periods at $5{\sim}10$ day intervals. The normality of percolation rate and pollutant concentrations were examined using histogram, boxplot, and the Kolmogorov-Smirnov (K-S) test. Pollutant concentrations in percolated water showed positively skewed distribution. The median concentrations of pollutant were 1.91 mg/L for TN, 0.021 mg/L for TP, and 6.6 mg/L for COD, which were lower than its arithmetic mean concentrations by $35\%$ for TN, $36\%$ for TP, and $13\%$ for COD. The median concentrations of TN and TP differed significantly among sample sites according to the Kruskal-Wallis test. However, median concentrations were not significantly different among month except for TN and TP of Soro and COD of Odong. The percolation load of pollutants during irrigation periods in the study area were estimated at $3.12{\sim}7.75\;kg/ha$ for TN, $0.033{\sim}0.155\;kg/ha$ for TP, and 10.7 kg/ha for COD, which were much lower than respective values reported in Japan.

• 생태와환경
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• 제33권4호통권92호
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• pp.328-335
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• 2000

현재 우리나라에서 수중의 유기물양의 지표로 사용되고 있는 $COD_{Mn}$법이 지표로서 적합한지를 알아보기 위하여 소양호의 댐앞지점과 유입수를 대상으로 유기물양과 $COD_{Mn}$과의 상관관계를 알아보았다. 또한 소양호를 표충, 중층, 심층으로 나누어 $COD_{Mn}$ 법에 의한 각 충의 유기물산화정도를 비교하였다. 소양호의 유기물농도와 $COD_{Mn}$ 비는 계절에 따라 매우 상이하였고, 수층에 따라서도 차이를 보였다. 유입수에서도 홍수기를 전후로 하여 유기물농도와 $COD_{Mn}$ 비가 유의적인 차이를 보였다. $COD_{Mn}$ 법에 의한 소양호의 유기물의 산화는 평균 40% 정도로 낮은 값을 보였다. 특히 심층의 유기물은 $COD_{Mn}$ 법에 의해 산화되는 양이 30%이하로 매우 낮았다. 이러한 결과는 $COD_{Mn}$ 법이 호수와 하천의 유기물양을 제대로 대변하고 있지 못할 뿐 아니라 계절에 따라 유기물의 조성이 변할 때 $COD_{Mn}$ 법에 의한 유기물산화력이 변한다는 단점을 보여준다.

• 한국지반환경공학회 논문집
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• 제3권4호
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• pp.29-35
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• 2002

본 연구는 유기질토를 토공재로서 활용할 목적으로 시료A(모래+유기질토)와 시료B(풍화토+유기질토)의 두 가지 시료를 유기질토 혼합비를 5%, 10%, 20%, 30%, 40%, 50%로 혼합하여 각종 실내시험을 실시하였다. 시료A, B의 용출시험에 의한 COD값은 순수 유기질토에 비해 상당히 낮은 값을 보였으며, 초기 침출수의 COD 값은 침출수 수질기준을 약간 상회하였지만 용출시작 4시간후의 COD 값은 매우 적게 나타났다. 모래와 유기질토의 혼합토는 유기질토 혼합비 40%(유기물함유량 11.3%)내에서는 성토재로서의 활용이 가능한 것으로 나타났으며, 풍화토와 유기질토의 혼합토는 유기질토 혼합비 30%(유기물함유량 16.4%)이내에서 토공재로서 활용이 가능하다고 판단되어진다.

• 분석과학
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• 제8권3호
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• pp.281-284
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• 1995

개정된 공정 시험법의 세부 절차상의 변경이 시험 결과에 미치는 영향을 조사하였다. 가열 시간이 1/3로(60분${\rightarrow}$20분), 과망간산칼륨의 농도가 1/2.5(0.025N${\rightarrow}$0.010N)로 줄어든 결과로 글루코스의 경우 COD로서의 회수율이 평균적으로 약 30% 감소하였다. 즉, 개정된 절차에 따른 시험 결과는 개정 전의 절차에 의한 결과의 70%밖에 안 된다. 이 때 정밀성은 다소 향상되었다(CV가 4.6%${\rightarrow}$3.3%). 이러한 $KMnO_4$의 산화능 감소는 주로 농도의 묽어짐 때문이었다. 나머지 감소 효과의 1/3이 가열 시간 감소의 영향으로 드러났다. 이처럼 알칼리성 COD법에서는 산화제의 농도 변화가 가열 시간의 경우보다 결과에 미치는 영향이 훨씬 큼을 나타내었다. 실제 바닷물 시료에서도 같은 결과를 얻을 수 있었다.

• 한국농공학회논문집
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• 제57권6호
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• pp.153-162
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• 2015

In this study, we analyzed the trends of water quality along the main stream in Nakdong river basin using the recent data and seasonal Mann-Kendall test. Monthly averaged values of DO, BOD, SS, COD, TN, and TP from 1989 to 2014 for 14 stations (including 2 TMDLs stations) were used in the study. The trend analysis results showed that BOD and TP at most stations has decreasing temporal trend except a few stations while COD and SS showed increasing trend at most stations. Temporal trends in TN at 8 stations were found to be statistically significant and 5 of them showed increasing temporal trend. Temporally averaged BOD, COD, TN and TP were generally increasing as going downstream and the worst water quality were found at Goryeong and Hyunpung station. Overall, water quality of Nakdong river especially in COD, SS, and TN getting worse in time at most stations and as going downstream.