• Journal of Korean Society of Water and Wastewater
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• v.24 no.4
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• pp.387-394
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• 2010

The influent COD of municipal wastewater has been divided into 4 fractions; readily soluble biodegradable, slowly particulate biodegradable, soluble and particulate unbiodegradable COD. The mathematical modeling of biological wastewater treatment processes and the design and operation of nutrient removal plants require a reliable and accurate estimate of the composition of influent wastewater COD. COD utilization rate is proportional to the oxygen uptake rate(OUR), so a batch biodegradation test with OUR measurement has been effectively used for the determination of COD fractionation. But the mathematical model of COD utilization and heterotrophs synthesis is essential to interpret the OUR measurement. Mamais method is another method for determining readily biodegradable soluble COD. Like the OUR test method, batch biodegradation test is necessary but it does not require mathematical model. These two methods for determining COD fractionation are introduced here in detail. Experimental results showed that COD composition by Mamais method is not different to that by OUR test method so, either of them can be used.

• Journal of Advanced Marine Engineering and Technology
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• v.12 no.3
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• pp.57-67
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• 1988

Although handicapped by the inability to bridge the size gap between small laboratory sample and large engineering component, the V charpy test sample method does possess certain advantages, such as each of preparation, simplicity of test method, speed, low cost in test machinery, and low cost per test. On the other hand, the COD test method does posses advantages, which reduce the size gap between the laboratory sample and actual engineering component. Consequently, the correlation between V charpy absorbed energy and the critical COD value is required for estimating critical COD value from the simple V charpy test results. In this paper, the high tensile strength steel AH36 plate specimens having a single edge cracked notch were investigated to find out the correlation between V charpy absorbed energy and critical COD value in the welded parts under such various welding methods as shielded metal arc welding, the submerged arc welding and the electro gas welding by means of V charpy impact test and static 3-point bending test. Main results obtained are as follow ; 1. The relationships between V charpy absorbed energy Wc' and critical COD value ($\delta_c$)show; $\delta_c$=0.0065 Wc'+0.1906. 2. Ductile- brittle transition behaviours can be estimated by means of fracture appearance and general yielding behaviours. 3. The V charpy absorbed energy of SMAW is higher than that of SAW, EGW and similar relationships are obtained in the COD tests.

• Journal of Environmental Health Sciences
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• v.15 no.2
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• pp.33-40
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• 1989

Dichromate reflux method for COD analysis is one of the useful and precise way to solve the organic content of the wastewater. But the standard procedure for COD is not entirely satisfactory for sample containing appreciable amounts of inhibiting substance, especially chloride ion. Under the conditions of the established test, a big disadvantage of the method is that dichromate oxidizes chloride quantitatively to chlorine. When it is necessary to use silver sulfate as a catalyst in the COD procedure, chloride must be removed before the addition of the catalyst. Silver sulfate and mecuric sulfate forms a precipitate of AgCl and HgCl$_{2}$ separately which is not completely oxidized during the test and, therefore, cannot be corrected for. So, we evaluate and compensate the amount of chloride oxidation in the absence of chemicals during the experimental procedure. Calculation of COD is made using the following reviced formula: real COD = tested COD - 0.2277Cl.

• Journal of Environmental Impact Assessment
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• v.4 no.2
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• pp.93-103
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• 1995

This study was carried out to suggest the best statistical test to analyze the trend in monthly water quality data. Traditional parametric tests such as t-test and regression analysis are based on the assumption that the underlying population has a normal distribution and regression analysis additionally assumes that residual errors are independent. Analyzing 9-years monthly COD data collected at Paldang in Han River, the underlying population was found to be neither normal nor independent. Therefore parametric tests are invalid for trend detection. Four Kinds of nonparametric statistical tests, such as Run Test, Daniel test, Mann-Kendall test, and Time Series Residual Analysis were applied to analyze the trend in the COD data, Daniel test and Mann-Kendall test indicated upward trend in COD data. The best nonparametric test was suggested to be Daniel test, which is simple in computation and easy to understand the intuitive meaning.

• Journal of Welding and Joining
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• v.1 no.2
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• pp.53-60
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• 1983

COD test based on fracture mechanics concept was used in this study to evaluate the fracture toughness quantitatively. Effects of specimen sizes on critical COD value for ABS EH 36 steel and its submerged arc weldments, and the variation of critical COD value depending on metallurgical/mechanical heterogeneities caused by weld thermal cycles were investigated. Experiment was performed by using specimens made from base metal and submerged arc weldments according to BS 5762. Obtained results are summarized as follows; 1) Critical COD value for base metal decreases with increasing thickness of specimen. On hand, as the reduction ratio of critical COD decreases with increasing specimen thickness, critical COD value becomes constant above a thickness of specimen. 2) Critical COD value for weldment decreases with increasing thickness of specimen and was also affected by metallurgical states of base metal. 3) Size effects for weldment was greater at the hardened region. 4) Critical COD value was affected by microstructural change due to weld thermal cycles in weldments; that is, accicular ferrite formation is favorable for increasing of COD value.

• Journal of The Korean Society of Agricultural Engineers
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• v.47 no.2
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• pp.99-110
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• 2005

Characteristics of concentrations of total nitrogen (TN), total phosphorus (TP), and chemical oxygen demand (COD) pollutant in percolated water at four paddy field sites (Soro, Odong, Munui, and Boeun) were investigated by a nonparametric test. Percolation rate measurement and percolated water sampling were taken during irrigation periods at $5{\sim}10$ day intervals. The normality of percolation rate and pollutant concentrations were examined using histogram, boxplot, and the Kolmogorov-Smirnov (K-S) test. Pollutant concentrations in percolated water showed positively skewed distribution. The median concentrations of pollutant were 1.91 mg/L for TN, 0.021 mg/L for TP, and 6.6 mg/L for COD, which were lower than its arithmetic mean concentrations by $35\%$ for TN, $36\%$ for TP, and $13\%$ for COD. The median concentrations of TN and TP differed significantly among sample sites according to the Kruskal-Wallis test. However, median concentrations were not significantly different among month except for TN and TP of Soro and COD of Odong. The percolation load of pollutants during irrigation periods in the study area were estimated at $3.12{\sim}7.75\;kg/ha$ for TN, $0.033{\sim}0.155\;kg/ha$ for TP, and 10.7 kg/ha for COD, which were much lower than respective values reported in Japan.

• Korean Journal of Ecology and Environment
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• v.33 no.4 s.92
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• pp.328-335
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• 2000

Seasonal and vertical variations of organic carbon and chemical oxygen demand (COD$_{Mn}$ were investigated to estimate a suitability of COD$_{Mn}$ methods as an index of the quantity of organic matter in Lake Soyang. Organic matter in the lake may be composed matters resistant to oxidation by COD$_{Mn}$ method, especially in de데 layers. Rations of COD$_{Mn}$ to TOC varied with season and depth layer in Lake Soyang. In the inflowing river, the ratios after summer monsoon were very low and significantly different compared with other seasons (p<0.0001 between after summer monsoon and other seasons by unpaired sample t-test). At the dam site the ratio was low in the deep layer. The ratios in deep layer were significantly different compared with those of upper and middle layers (p<0.0001 by paired sample t-test). In Lake Soyang COD$_{Mn}$ yielded only 40$ of TOC and the oxidation rate of COD$_{Mn}$ varied largely with season and depth. These results implied that the COD$_{Mn}$ does not seem to be an index or organic matter in lakes.

• Journal of the Korean GEO-environmental Society
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• v.3 no.4
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• pp.29-35
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• 2002

In order to establish the applicability of organic soil as Earthwork Materials, this research conducts a battery of laboratory tests using two kinds of test materials. The test material A, a mixture of sand and organic soil, and the test material B, a mixture of granite soil and organic soil varying the proportion of organic soil through 5%, 10%, 20%, 30%, 40%, and 50% are used. Continuous column leaching tests of the test materials A and B indicate that their COD value is substantially smaller than that of pure organic soil, the COD value of the early leached water slightly exceeds the standard level for leached water. The COD value after 4 hours of leaching becomes very small. The mixed soil of sand and organic soil is considered usable as embankment materials when the proportion of organic soil is up to 40% with the corresponding concentration ratio of organic contents is less than 11.3%. Similarly, the mixed soil of granite soil and organic soil is considered usable as earthwork materials when the proportion of organic soil is less than 30% with the corresponding concentration ratio of organic contents is less than 16.4%.

• Analytical Science and Technology
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• v.8 no.3
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• pp.281-284
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• 1995

The effect of permanganate concentration and refluxing time on the test COD results were investigated, as a validation test of the revised procedure. The amended protocol involves the use of a more dilute(1/2.5) permanganate solution(0.010N) and a shorter(1/3) refluxing period(20 min). This revision resulted only 70% of the COD value determined by the old procedure with 8 somewhat improved precision(CV 4.6%${\rightarrow}$3.3%). The dominant factor that influences the decrease in the COD result is the oxidant concentration, being two thirds of the overall effect. The same results were obtained in the comparison test using seawater samples.

• Journal of The Korean Society of Agricultural Engineers
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• v.57 no.6
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• pp.153-162
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• 2015

In this study, we analyzed the trends of water quality along the main stream in Nakdong river basin using the recent data and seasonal Mann-Kendall test. Monthly averaged values of DO, BOD, SS, COD, TN, and TP from 1989 to 2014 for 14 stations (including 2 TMDLs stations) were used in the study. The trend analysis results showed that BOD and TP at most stations has decreasing temporal trend except a few stations while COD and SS showed increasing trend at most stations. Temporal trends in TN at 8 stations were found to be statistically significant and 5 of them showed increasing temporal trend. Temporally averaged BOD, COD, TN and TP were generally increasing as going downstream and the worst water quality were found at Goryeong and Hyunpung station. Overall, water quality of Nakdong river especially in COD, SS, and TN getting worse in time at most stations and as going downstream.