• Title/Summary/Keyword: COD 오염부하량

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Characteristics of Stormwater Treatment in Construction Site (건설 현장 내 비점오염원 처리 특성 평가)

  • Choi, Younghoa;Kim, Changryong;Kim, Hyosang;Oh, Jihyun;Jeong, Soelhwa
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.6
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    • pp.69-75
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    • 2010
  • Total suspendid solid (TSS) of non point source pollutants in construction site are in higher concentration than others (BOD, COD etc). Also, the TSS concentration is very sensitive to the rainfall intensity in early stage of construction. There are two methods for treatment of non point source pollutants, which are temporary treatment facility and filtering one. But they have disadvantages. Temporary facility system has very low efficiency and filtering system consumes high energy and takes up large footprint. This study shows how prefabricated flocculation/coagulation system is developped to cover the above weakness and evaluation of the system performance in construction site. The prefabricated flocculation/coagulation system has very high treatment efficiency comparing with temporary and filtering system and takes small footprint. Therefore, it expects that the system leads to prevention of pollution near construction site and reduction of public grievance. Proper coagulant dosage and sludge circulation facility application, controlling the height of sludge interfacial are necessary to maximize the system efficiency.

The Study on the Amount and Major Compositions of Excreta from Swine (돼지의 분뇨 배설량 및 분뇨 성분 조사)

  • HwangBo, Jong;Hong, Eui-Chul;Park, Hee-Du;Kim, Dong-Woon;Cho, Sung-Back
    • Journal of Animal Science and Technology
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    • v.52 no.4
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    • pp.319-328
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    • 2010
  • This work was carried out to investigate the quantity of excreta and its composition in crossbred pigs (Yorkshire ${\times}$ Landrace ${\times}$ Duroc) at different stages of growth. Twelve young piglets (average BW weight of $19.0{\pm}0.33kg$) were used in this study. Pigs were divided into four phases during growing time and two phases during finishing time. The average excreta production for growing pig was 3.46 kg/head/day (feces: 1.07 kg, urine: 2.39 kg). The average moisture contents of feces and urine were 70.54% and 97.39%, respectively. Contents of Calcium, Magnesium, Copper, Plumbum, and Arsenic were 1.00%, 0.26%, 10.47 mg/kg, 2.43 mg/kg, and 1.02 mg/kg, respectively. The concentration of the water pollutants like Biochemical Oxygen Demand ($BOD_5$), Chemical Oxygen Demand (COD), Suspended Solid (SS), Total Nitrogen (TN) and Total Phosphorus (TP), excreted from pig were 96335, 61073, 207466, 8104 and 4209 mg/L in feces and 7364, 7149, 2715, 10110 and 613 mg/L in urine at the end of test, respectively. The daily loading amount of water pollutants ($BOD_5$, COD, SS, TN, and TP, respectively) in pig excreta were 102.1, 61.8, 221.6, 8.7, and 3.9 g/head/day in feces, and 19.3, 16.7, 8.0, 22.2, and 1.3 g/head/day in urine, respectively. The Nitrogen, $P_2O_5$, and $K_2O$ contents in the excreta of pigs were 0.96, 0.83 and 0.42% in feces, and 0.80, 0.09 and 0.53% in urine, respectively. Finally, this work was suggested to give basic information to swine farms.

A Program of Water Quality Management for Agricultural Reservoirs by Trophic State (농업용 저수지의 부영양화와 수질관리방안)

  • Lee, Kwang-Sik;Yoon, Kyung-Sup;Kim, Ho-Il;Kim, Hyung-Joong
    • Korean Journal of Environmental Agriculture
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    • v.22 no.2
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    • pp.166-171
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    • 2003
  • A total of 498 agricultural reservoirs ranging from $164{\times}10^3\;m^3$ to $253{\times}10^6\;m^3$ in storage volume were investigated from 1990 to 2001 with respect to Chl-${\alpha}$, COD concentration and pollutant loading of BOD, TN, and TP. The lakes and reservoirs could be classified to 4 types using the relationships between the ratio of storage volume per water surface area(ST/WS) and Chl-${\alpha}$ concentration. It is recommended that the improvement of polluted lakes should be performed in the order of integrated consolidation type ${\rightarrow}$ watershed consolidation type ${\rightarrow}$ in-lake consolidation type ${\rightarrow}$ Management type and reservoir should be constructed to be over $5{\sim}6\;m$ in depth(ST/WS ratio) for preventing the eutrophication of agricultural reservoirs. We propose that water quality criteria for agricultural water is changed from less than 8 mg/L to less than 6 mg/L for safety value, $6{\sim}10\;mg/L$ for concern value, and more than 10 mg/L for countermeasure value in COD concentration, respectively.

Contamination of the Mushim-Cheon and its Countermeasure;II. The Status of the Seasonal and Hourly Contamination of the Water(1989${\sim}$1990)-Temperature, pH, DO, BOD, COD, SS, Turbidity, and BOD Load (무심천(無心川) 수질(水質) 오염(汚染) 실태(實態)와 그 방지책(防止策);II. 계절별(季節別) 및 시간별(時間別) 현황(現況) (1989-1990)-수온, pH, DO, BOD, COD, SS, 탁도 및 BOD 부하량(負荷量))

  • Lee, Jae-Koo;Kim, Hak-Nam;Kyung, Kee-Sung;Kwak, Hee-In
    • Korean Journal of Environmental Agriculture
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    • v.10 no.1
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    • pp.33-49
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    • 1991
  • In order to disclose the contamination of the Mushim-Cheon by pollutants and to establish the countermeasures, the water samples collected in November of 1989(lst sample), February(2nd), May(3rd) and August of 1990(4th) were analyzed to obtain the following results : 1. The water temperatures of the seasonal samples ranged from 8.6 to 16.2, 8.3 to 25.2, 18 to 26, and 24 to 32$^{\circ}C$, in the 1st, 2nd , 3rd, and 4th samples, respectively. 2. The pHs of all the samples ranged from 6.5 to 8.5. 3. In the 3rd sample, especially, DO was observed to fall down to 0.8 ppm at the downstream of St 13, which is not allowed even for agricultural use. 4. The BOD and COD values in sewers were much higher than those in the main stream, and especially the values of St 14-A reached 107-608 and 176-635 ppm, respectively, which far exceeded the limit of 40 ppm, the allowed value for the discharges from the disposal facilities. The SS value of St 14A ranged from 142 to 1, 900 ppm, which far exceeded the limit of 70 ppm, the allowed value for the discharges from the disposal facilities. 5. It turned out that the water quality of the Mushim-Cheon flowing through Cheong Ju was more worsened at sewers than the main stream, and at the downstream than the upstream of the surveyed area. Accordingly, the sewage disposal plant and the expansion of the disposal facilities are urgently needed.

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Analysis of Fish Ecology and Water Quality for Health Assessments of Geum - River Watershed (금강본류의 건강성 평가를 위한 어류생태 및 수질 특성분석)

  • Park, Yun-Jeong;Lee, Sang-Jae;An, Kwang Guk
    • Korean Journal of Environment and Ecology
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    • v.33 no.2
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    • pp.187-201
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    • 2019
  • This study examined the physicochemical water quality and evaluated the ecological health in 14 sites of Geum River (upstream, mid-stream, and downstream) using the fish community distribution and guilds and eight multi-variable matrices of FAI (Fish Assessment Index) during June 2008-May 2009. The analysis of the water quality variables showed no significant variation in the upstream and mid-stream but a sharp variation due to the accumulation of organic matter from the point where the treated water of Gap and Miho streams flew. The analysis of physicochemical water properties showed that BOD, COD, TN, TP, Cond, and Chl-a tended to increase while DO decreased to cause eutrophication and algae development from the downstream where Miho and Gap stream merged. The analysis of fish community showed that the species richness index and species diversity index increased in the mid-stream area but decreased in the downstream area, indicating the stable ecosystem in the upper stream and the relatively unstable ecosystem in the downstream. The analysis of the species distribution showed that the dominant species were Zacco platypus that accounted for 20.9% of all fish species and Zacco koreanus that accounted for 13.1%. The analysis of the fish tolerance and feeding guild characteristics showed that the sensitive species, the insectivore species, and the aquatic species were dominant in the mid-stream point. On the other hand, contaminants from the sewage water treatment plant of Miho stream had a profound effect in the downstream to show the dominance of tolerant species, omnivorous species, and lentic species. Therefore, it is necessary to improve water quality by reducing the load of urban pollutants and to pay attention to the conservation and restoration of aquatic ecosystems.

Efficient Spent Sulfidic Caustic wastewater treatment using Adsorption Photocatalysis System (흡착광산화 시스템을 이용한 효과적인 SSC 페수처리)

  • Kim, Jong Kyu;Lee, Min Hee;Jung, Yong Wook;Joo, Jin Chul
    • Proceedings of the Korea Water Resources Association Conference
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    • 2016.05a
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    • pp.520-520
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    • 2016
  • 석유 화학공장에서 발생하는 spent sulfidic caustic (SSC) 폐수는 액화석유가스(LPG)나 천연가스(NG)의 정제과정에서 발생되는 것으로 고농도의 sulfide와 cresylic, phenolic 그리고 mercaptan 등이 포함된 독성과 냄새를 유발하는 물질이다. 이러한 물질들은 LPG나 NG의 정제과정에서 높은 산도를 가진 휘발성 황화합 물질들을 제거하기 위해 사용된 NaOH가 $H_2S$와 반응하여 발생하는 것이다. 진한 갈색 또는 검은색을 띄는 SSC 폐수는 12 이상의 높은 pH를 가지고 있으며 5~12 wt%의 높은 염분도를 가지고 있다. 또한 강한 부식성과 독성을 가진 황화합물의 농도가 1~4 wt%이며, 방향족 탄화수소 물질 (i.e. methanethiol, benzene, tolune and phenol)들도 다량 함유되어 있다. 따라서 이러한 유해 물질들은 기존의 하수처리 공정으로 방류하기 전에 완벽하게 처리해야만 하수처리 공정의 오염 부하량을 줄일 수 있다. 습식산화공정은 SSC 폐수를 처리하기 위해 흔히 사용되고 있는 물리-화학적 처리 공정이지만 고비용, 고에너지가 필요하며, 고온 및 고압에서만 작동되어 안전상의 문제점을 갖고 있다. 또한 습식산화공정을 거친 폐수는 배출허용기준을 만족하기 위해 생물학적 2차 처리가 반드시 필요하다. 철-과산화수소를 이용하는 펜톤산화 공정, 그리고 sulfide를 sulfate로 전환시키는 생물학적 처리 공정은 황화합물의 완전한 무기물화가 힘들며, 현장 적용 시 기술적 경제적 부담이 크다. 이러한 단점을 극복하고, SSC 폐수를 효과적으로 처리하기 위해 본 연구는, 높은 흡착력과 광산화력을 가진 흡착광산화 반응 시스템(Adsorption Photocatalysis System, APS)을 개발하였다. APS는 SSC 폐수를 시스템 내부로 유입하여 수중의 오염물질을 흡착광산화제로 구성된 반응구조체가 흡착하고, 흡착된 오염물질을 UV에너지와 이산화티타늄 광촉매의 광화학반응에 의해 최종적으로 무해한 물질로 환원시키는 폐수처리시스템이다. APS의 반응구조체는 태양에너지 및 인공에너지원에 의해 활용 가능하며, 난분해성 유기화합물질을 물과 이산화탄소로 분해할 수 있는 친환경적이고 경제적인 소재로서 널리 쓰이고 있는 이산화티타늄 광촉매와 화력발전소의 높은 소성온도에 의해 연소된 후 발생되는 bottom ash를 이산화티타늄의 지지체로 사용하여 높은 흡착력과 광촉매 산화력을 가진 복합물이다. 개발된 APS에 의해 SSC 폐수를 처리한 결과, COD 86.1%, 탁도 98.4%, sulfide 99.9%의 높은 처리효율을 보여주고 있다. 따라서 본 연구를 통해 개발된 APS는 강한 부식성과 독성 그리고 높은 농도를 가지고 있는 SSC 폐수를 효과적으로 처리할 수 있다.

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Distribution of Organic Matter and Heavy Metals in the Surface Sediments from Fishery Resources Protection Areas in the Southwestern Coast of Korea (남서해연안 수산자원보호구역 표층 퇴적물 중 유기물 및 중금속 농도분포)

  • Koo, Jun-Ho;Lee, Garam;Hwang, Hyunjin;Kim, Jeong-Bae;Kim, Sang-Su;Hwang, Dong-Woon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.6
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    • pp.666-677
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    • 2019
  • In order to understand the distribution of organic matter and heavy metal concentrations in the surface sediments of fishery resources protection areas (FRPAs), we measured the grain size, ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS), and concentrations of heavy metals (As, Cd, Cr, Cu, Fe, Hg, Pb, and Zn) in the surface sediments collected at 54 stations of 5 FRPAs (Gamak Bay, Yeoja Bay, Deukryang Bay, Wando coast, and Youngkwang coast) in the southwestern coast of Korea in February 2017. The surface sediments consisted of fine sediment such as mud, with 2.9~8.8Ø (7.4±0.1Ø) of mean grain size. The average concentrations of IL, COD, and AVS in the sediments were 4.63±0.96 %, 13.0±3.1 mgO2/g·dry, and 0.092±0.124 mgS/g·dry, respectively, and were lower for sediments from the Youngkwang coast than those from other FRPAs. The average concentrations of heavy metals in the sediment were 7.5±0.9 mg/kg for As, 0.04±0.02 mg/kg for Cd, 70.2±9.7 mg/kg for Cr, 15.3±2.8 mg/kg for Cu, 3.3±0.5 % for Fe, 0.014±0.003 mg/kg for Hg, 25.0±6.0 mg/kg for Pb, and 99±14 mg/kg for Zn, respectively, and were relatively higher for sediments in the inner bays than those from the outer bays and coasts. Based on the assessment of sediment samples using the sediment quality guidelines (SQGs), the pollutant load index (PLI), and the ecological risk index (ERI), the surface sediments of FRPAs in the southwestern coast of Korea do not appear to be polluted by heavy metals, suggesting that the heavy metal concentrations in the sediments would not adversely impact aquatic and benthic organisms.

Feasibility of Co-Digestion of Sewage Sludge, Swine Waste, and Food Waste Leachate (하수슬러지, 돈분뇨, 음식물쓰레기 탈리액 병합소화 타당성 평가)

  • Kim, Sang-Hyoun;Ju, Hyun-Jun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.1
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    • pp.61-70
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    • 2012
  • Feasibility of co-digestion was investigated by a series of anaerobic batch experiments using sewage sludge, swine waste, and food waste leachate as substrates. The organic solid wastes were collected from M city, where the daily productions of sewage sludge, swine waste, and food waste leachate were 178 ton/d, 150 ton/d, and 8 ton/d, respectively. Both swine waste and food waste leachate showed superior methane yields, methane productivities, and organic pollutant removal efficiencies compared to sewage sludge. Co-digestion of the total amounts of organic solid wastes would enhance methane production by 5.60 times $(530\;m^{3}\;CH_{4}/d\;{\rightarrow}\;2,968\;m^{3}\;CH_{4}/d)$. However, it also increase the amount of digestate by 1.88 times with 3.79 to 4.92 times higher pollutants (chemical oxygen demands total nitrogen, and total phosphorus) loading rates. Co-digestion of organic solid wastes is a valid strategy to enhance the performance of an anaerobic sludge digester and the energy independence of a wastewater treatment plant. Anyhow,the increment of digestate with higher pollutant loading would need a careful counterplan in the operation of the main stream of the treatment plant.

Dredging Bottom Sediments of Seoha Weir at the Downstream of Kyongan Stream can be Used as a Feasible Pollutant Load Reduction Option in the Total Pollutant Load Management System of Kwangju City? (경안천 서하보 수저퇴적물 준설이 경기도 광주시 수질오염총량관리에 있어 추가적인 부하량 삭감수단으로써 타당한가?)

  • Yu, Seung-Hoon;Lee, Bum-Yeon;Lee, Kang-Hyun;Park, Shin Jung;Lee, Chang-Hee
    • Journal of Korean Society on Water Environment
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    • v.27 no.1
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    • pp.19-29
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    • 2011
  • In order to assess the influences of bottom sediment on water quality, following measurement were made. (1) Estimations of pollutant loads from the bottom sediment based on mass balance concept, (2) measurements of pollutant concentrations in the sediment to assess the pollution level and influence potential, (3) in situ and laboratory measurements of Sediment Oxygen Demants (SOD) and pollutant load (sediment release) from bottom sediment. Analyses of inflow and outflow loadings using simple mass balance show that there are some variations found according to the pollutants. However, there is no consistent evidence that the sediment can be a source of pollutants. Pollutant concentrations in the sediment range 16~724.8 mg/kg (COD), 1.68 ~12.64 mg/kg (T-P), 5.6~76.8 mg/kg (T-N), 0.32~21.6 mg/kg ($NH_3$-N), 0.092~0.544 mg/kg ($NO_2$-N), 4.8~18.4 mg/kg ($NO_3$-N), and 1.59~11.23 mg/kg ($PO_4$-P). Measured SOD ranges $0.190{\sim}0.802g{\cdot}m^{-2}{\cdot}d^{-1}$ and measured release rate ranges $-1618.42{\sim}10mg/m^2{\cdot}d$(COD), $-12{\sim}16mg/m^2{\cdot}d$(T-P), $-197.37{\sim}140mg/m^2{\cdot}d$(T-N), $0.4{\sim}74.32mg/m^2{\cdot}d$($NH_3$-N), $-2.04{\sim}0.8mg/m^2{\cdot}d$ ($NO_2$-N), $-70{\sim}40mg/m^2{\cdot}d$ ($NO_3$-N), and $-26.11{\sim}28.55mg/m^2{\cdot}d$($PO_4$-P). All study results indicate that bottom sediments in the Seoha weir show only limited effects on the water quality. It implies that sediment dredging is not an effective option or management measure to reduce pollutant loading.

Characteristics of Water Environment on Manun Reservoir (중산간 농업용 만운저수지의 수질환경특성)

  • Nam, Gui-Sook;Jang, Jeong-Ryeol;Lee, Gwang-Sik;Yoon, Keung-Sup;Lee, Sang-Joon
    • Korean Journal of Environmental Agriculture
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    • v.22 no.1
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    • pp.16-25
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    • 2003
  • Manun Reservoir, located in Andong district has the capacity of 2 million tons in irrigation water supply with the drainage area of $23.8\;km^2$. Manun Reservoir is over fifty year old, and shallow in depth. The ratio of drainage area (DA) to reservoir surface area (SA) as an effective physical parameter on water quality was 56.1 and was higher than those of other agricultural reservoirs. The ratio of reservoir storage (ST) to SA in Manun Reservoir was 4.79, and the mean depth was below 8m. Both ratios of DS/SA, total area (TA)/ST and ST/SA in Manun Reservoir were relatively higher than those in other agricultural reservoir and natural lakes in Korea. These physical parameters in Manun Reservoir, however, had a eutropic potential significance. Average of COD, IN, and TP in Manun Reservoir were 11.1 mg/L 1.426 mg/L, 0.093 mg/L, respectively. In the inflow stream of Manun Reservoir, the TN ($1.426{\sim}3.809\;mg/L$) was higher than those in reservoir. Only Lyngbya spp. was dominant in phytoplankton for this study period and Gymnodinium spp., Peridinium spp., and Cryptomonas spp. were dominant in zooplankton. According to the Carlson's trophic status index, Mnnun Reservoir was eutrophic in 1996, 1997, and 1999, and hypertrophic in 1998.