• Title/Summary/Keyword: COD 감소

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Optimum Conditions for the Removal of External Organic Carbon Sources in a Submerged Denitrification Biofilter (탈질 여과조에서 외부 탄소원 제거를 위한 적정 체류 시간과 외부 탄소원 종류 및 질산염 농도에 대한 외부 탄소원의 적정 비율)

  • 오승용;조재윤;윤길하
    • Journal of Aquaculture
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    • v.12 no.1
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    • pp.47-56
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    • 1999
  • Denitrification by anaerobic bacteria is one of the most common processes of removing nitrate from recirculating aquaculture systems. This process is affected by many factors such as external carbon sources, hydraulic retention time (HRT), and $COD/NO_3-N$ ratio. Although external organic carbon sources are essential for the denitrification process, these also contribute to increase dissolved organic carbon concentration in recirculating aquaculture systems. So these external organic carbons must be removed from the systems. This study was conducted to find out the optimum operating conditions for the removal of external organic carbons in a submerged denitrification biofilter. Combinations of two external carbon sources (glucose and methanol), two HRT (4- and 8-hour), and four different C:N ratios (3, 4, 5, and 6) were used in this experiment. The removal efficiencies of organic carbon sources at 8-hour HRT were always better than those at 4-hour's (P<0.05). Maximum removal efficiencies were achieved when C:N ratio was 5 in both glucose and methanol. The removal efficiencies of methanol were always better than those of glucose. The maximum removal efficiencies of glucose and methanol were 76.5% and 84.0%, respectively and the removal rates were 223.5 $g/m^2/day$ and 247.1$g/m^2/day$. The maximum removal rates of glucose (290.9 $g/m^2/day$) and methanol (355.6 $g/m^2/day$) were achieved at 4-hour HRT and 5 C:N ratio. But the concentrations of SCOD in the effluent of both glucose ($52.5 mg/\ell$) and methanol ($40.9 mg/\ell$) were too high for rearing fish. Therefore, the optimum operating conditions for the removal of external carbon in a submerged denitrification biofilter were 8-hour HRT and 5 C:N ratio. And methanol showed better efficiency as an external carbon sources.

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Fish Community Characteristics in Hwapocheon Wetland, Korea (화포천 습지의 어류군집 특성)

  • Ko, Myeong-Hun;Choi, Kwang-Seek;Lim, Jeong-Cheol
    • Korean Journal of Environment and Ecology
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    • v.36 no.2
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    • pp.165-176
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    • 2022
  • This study surveyed the characteristics of fish communities in Hwapocheon Wetland, Korea, from May to September 2020. The survey collected 735 objects in 21 species belonging to 7 families from 8 survey stations. The dominant and subdominant species were Hemiculter eigenmanni(23.8%) and Micropterus salmoides(10.3%), respectively. The next most abundant species were Zacco platypus(9.5%), Carassius auratus(9.4%), Pseudorasbora parva(9.0%), Squalidus chankaensis tsuchigae(6.7%), Acheilognathus macropterus(5.4%), Lepomis macrochirus(5.2%), Pseudogobio esocinus(4.1%), Opsariichthys uncirostris amurensis(3.7%), and Carassius cuvieri(3.3%). Among the fish species collected, one species, Culter brevicauda, was class II endangered wildlife designated by the Ministry of Environment, and one species,S. c. tsuchigae(4.8%), was endemic to Korea.Additionally, three exotic species (M. salmoides, L. macrochirus, and C. cuvieri) and one landlocked species (Rhinogobius brunneus) were collected. Compared to previous studies, the proportion of fish living in the running water area tended to decrease, the proportion of fish living in the water purification area tended to increase, and ecosystem-disturbing species (M. salmoides and L. macrochirus) tended to increase gradually. Results of fish community analysis showed that the mainstream stations (St. 1, 3, 4, 5, 6, and 8) had low dominance, but high diversity and richness, and other stations (St. 2 and 7) had high dominance but low diversity and richness. The river health (index of biological integrity) evaluated using fish was assessed as bad (6 stations), normal (1 station), and very bad (1 station). The water quality grade was assessed as slightly bad due to the chemical oxygen demand (COD), total organic content (TOC), suspended solid (SS), and total coliforms (TC). The annual water quality showed a gradually increasing trend of biological oxygen demand (BOD), COD, SS, and chlorophyll-a. The stable life of fish and the improvement of river health in Hwapocheon Wetland require water quality improvement and the systematic management of ecosystem-disturbing species (M. salmoidesand L. macrochirus).

Removal Velocities of Pollutants under Different Wastewater Injection Methods in Constructed Wetlands for Treating Livestock Wastewater (인공습지 축산폐수처리장에서 주입방법에 따른 오염물질의 제거속도 평가)

  • Kim, Seong-Heon;Seo, Dong-Cheol;Park, Jong-Hwan;Lee, Choong-Heon;Lee, Seong-Tea;Jeong, Tae-Uk;Kim, Hong-Chul;Ha, Yeong-Rae;Cho, Ju-Sik;Heo, Jong-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.2
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    • pp.272-279
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    • 2012
  • In order to effectively treat livestock wastewater in constructed wetlands by natural purification method, removal velocities of pollutants under different injection methods in constructed wetlands were investigated. The removal velocities of chemical oxygen demand (COD), suspended solid (SS), T-N and T-P by continuous injection method were slightly rapid than those by intermittent injection method in full-scale livestock wastewater treatment plant. The removal velocity (K; $day^{-1}$) of COD by continuous injection method was $0.38\;d^{-1}$ for $1^{st}$ bed, $0.13\;d^{-1}$ for $2^{nd}$ bed, $0.17\;d^{-1}$ for $3^{rd}$ bed, $0.05\;d^{-1}$ for $4^{th}$ bed and $0.17\;d^{-1}$ for $5^{th}$ bed. The removal velocities (K; $day^{-1}$) of COD in $1^{st}$, $2^{nd}$, $3^{rd}$, $4^{th}$ and $5^{th}$ beds by intermittent injection method were $0.210\;d^{-1}$, $0.086\;d^{-1}$, $0.222\;d^{-1}$, $0.053\;d^{-1}$ and $0.137\;d^{-1}$, respectively. The removal velocity (K; $day^{-1}$) of SS by continuous injection method was $0.750\;d^{-1}$ for $1^{st}$ bed, $0.108\;d^{-1}$ for $2^{nd}$ bed, $0.120\;d^{-1}$ for $3^{rd}$ bed, $0.086\;d^{-1}$ for $4^{th}$ bed and $0.292\;d^{-1}$ for $5^{th}$ bed. The removal velocities (K; $day^{-1}$) of SS in $1^{st}$, $2^{nd}$, $3^{rd}$, $4^{th}$ and $5^{th}$ beds by intermittent injection method were $0.485\;d^{-1}$, $0.056\;d^{-1}$, $0.174\;d^{-1}$, $0.081\;d^{-1}$ and $0.227\;d^{-1}$, respectively. The removal velocity (K; $day^{-1}$) of T-N by continuous injection method was $0.361\;d^{-1}$ for $1^{st}$ bed, $0.121\;d^{-1}$ for $2^{nd}$ bed, $109\;d^{-1}$ for $3^{rd}$ bed, $0.047\;d^{-1}$ for $4^{th}$ bed and $0.155\;d^{-1}$ for $5^{th}$ bed. The removal velocities (K; $day^{-1}$) of T-N in $1^{st}$, $2^{nd}$, $3^{rd}$, $4^{th}$ and $5^{th}$ beds by intermittent injection method were $0.235\;d^{-1}$, $0.071\;d^{-1}$, $0.171\;d^{-1}$, $0.058\;d^{-1}$ and $0.126\;d^{-1}$, respectively. The removal velocity (K; $day^{-1}$) of T-P by continuous injection method was $0.803\;d^{-1}$ for $1^{st}$ bed, $0.084\;d^{-1}$ for $2^{nd}$ bed, $0.076\;d^{-1}$ for $3^{rd}$ bed, $0.118\;d^{-1}$ for $4^{th}$ bed and $0.301\;d^{-1}$ for $5^{th}$ bed. The removal velocities (K; $day^{-1}$) of T-P in $1^{st}$, $2^{nd}$, $3^{rd}$, $4^{th}$ and $5^{th}$ beds by intermittent injection method were $0.572\;d^{-1}$, $0.049\;d^{-1}$, $0.090\;d^{-1}$, $0.112\;d^{-1}$ and $0.222\;d^{-1}$, respectively.

Study on the Nanofiltration of Various Dye Solutions (NF막에 의한 다양한 염료용액의 막분리 특성)

  • Yang, Jeongmok;Kim, Tak-Hyun;Park, Cheolhwan;Kim, Jeehyeong;Kim, Sangyong
    • Clean Technology
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    • v.10 no.1
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    • pp.37-45
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    • 2004
  • This study examined the separation characteristics of some of the most commonly used disperse, reactive and acid dyes by nanofiltration membrane. The chemical characteristics of three major dye solutions such as chemical oxygen demand, total nitrogen, total organic carbon, color, suspended solids, total dissolved solids, conductivity were investigated in this work. Experiments showed that the types of dye had a significant effect on both permeate flux and rejection efficiencies mainly due to the differences among their chemical structures and natures. Especially, the nanofiltration of reactive dye solutions showed higher permeate flux, lower total dissolved solid rejection efficiency and higher organics rejection efficiency than those of disperse dye solutions.

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Effect of Wastewater Treatment of Partially Deacetylated Chitosan (부분 탈아세틸화된 키토산의 폐수처리 효과)

  • Cho, S.K.;Kim, S.J.;Jung, B.O.;Kim, J.J.;Choi, K.S.;Lee, Y.M.
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.899-903
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    • 1994
  • Chitin was extracted from crab shell by Hackman method and chitosan was prepared to chitin, that was deacetylated under various concentration of NaOH solution and reaction time at constant temperature, $100^{\circ}C$. Samples were A=19%, B=52%, C=70% and D=93% deacetylation's chitosan and they were tested. When deacetylation was increased, $\overline{Mw}$ was decreased and removal rate of suspended solid and removal rate of chemical oxygen demand were increased. Suspended solid and removal rate of chemical oxygen demand showed the better at pH 9 and pH 7 than any other pH range.

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Washoff Characteristics of NPS Pollutants from Artificial Grassland (강우시 인공 초지의 비점오염물질 유출특성 및 상관성)

  • Lee, Jeong-Young;Maniquiz, Marla C.;Choi, Ji-Yeon;Lee, Ja-Eun;Kim, Lee-Hyung
    • Journal of Wetlands Research
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    • v.11 no.3
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    • pp.145-151
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    • 2009
  • Recently the water quality management policy has been changed from managing the point source to controlling the nonpoint sources (NPSs) because of TMDL program. Most NPSs are accumulated on the surface during dry periods. These accumulated pollutants are washed-off during a storm event and highly impairing the water quality of the receiving water bodies. Usually NPS has high uncertainty and is hard to control because of the variability of the rainfall and watershed characteristics. Also, NPS is derived from various land uses. The Ministry of Environment (MOE) is studying and monitoring the pollutant loads from each land use since 2007 to determine the unit pollutant loads. This research was a part of long-term monitoring program conducted to characterize the washoff and provide the mean EMC of artificial grassland. The average EMCs result of BOD, COD, DOC, SS, TN, NH4-N, NO3-N, TP, and PO4-P of the artificial grassland were deterined to 8.2, 17.5, 11.3, 110.1, 3.07, 0.20, 0.75, 0.86 and 0.08 mg/L, respectively. The results of statistical analysis conducted showed a low correlation to the contaminants.

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Protozoa Structure of Anaerobic/Anoxic/Oxic Process. (혐기/무산소/호기공법의 원생동물 군집구조)

  • 이찬형;문경숙
    • Microbiology and Biotechnology Letters
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    • v.31 no.3
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    • pp.264-270
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    • 2003
  • A quantitative survey of the protozoa microfauna at bioreactor of advanced sewage treatment plant was carried out during a period of 11 months. In this study, 32 genera were identified, including 17 ciliates. The abundance of the important protozoa were compared with the operating parameters and water quality of the effluent of the plant using statistical procedure. Statistical analysis revealed a relationship between the abundance of some genera and removal rate. In particular, correlation analysis on the quality of effluent and protozoa indicated that Lepadella may be used as the bioindicator of TP removal and Trochilia, Entosiphon, Colepus may be used as the bioindicator of TN removal when water temperature was below $20^{\circ}C$.

Synthesis of Water Soluble Chitosan Derivatives with Quaternary Ammonium Salt and Their Flocculating Behavior (4차 Ammonium 기를 가진 새로운 수용성 Chitosan 유도체의 제조 및 이들의 응집거동에 관한 연구)

  • Kim, Chun-Ho;Jung, Byung-Ok;Choi, Kyu-Suk;Kim, Jae-Jin
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.118-128
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    • 1996
  • N-methyl, N-butyl and N,N-dibutyl chitosan derivatives were prepared by Schiff's base formation and hydrogenation in aqueous media. Furthermore quaternization of the chitosan derivatives was performed in N-methyl-2-pyrrolidone using methyl iodide to obtain water soluble cationic polyelectrolytes. It was confirmed that O-alkylation was occured as well as selective N-alkylation in these reactions. Chitosan and chitosan derivatives with quaternary ammonium iodide showed high flocculation power as the cationic flocculant. When tested on paper mill waste water, they showed high flocculation power, independing of pH range. The flocculation power was increased as the N-alkyl chain length was increased. Among them, N-butyl dimethyl chitosan ammonium iodide showed better flocculation power than chitosan. But, N,N-dibutyl-N-methyl chitosan ammonium iodide showed less flocculation powre than chitosan itself.

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Effective Chemical Treatment of Biologically Treated Distillery Wastewater in Industrial Scale (생물학적으로 처리한 주정폐액의 효율적인 화학적 처리방법)

  • Nam, Ki-Du;Chung, In;Hur, Daniel;Park, Wan
    • Journal of Life Science
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    • v.9 no.6
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    • pp.692-697
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    • 1999
  • For further removal of non-biodegradable CODs and color in biologically treated distillery waster water, we selected a chemical treatment with Fe(III) and cationic polymers and then another chemical treatment with Fenton reagent. We developed Pregenerated Bubble Flotation(PBF) to effectively remove the chemical sludge from each chemical reaction process. The flotation unit was constructed with hydraulic loading rate, 7 ㎥/$m^2$.hr. The CODMn and suspended solids (SS) in biologically treated distillery waste water were reduced by the first PBF from 310-1096 mg/L to 141-303 mg/L and from 160-990 mg/L to 48-385 mg/L, respectively. Again, after the Fenton reaction process, floated SS was skimmed off at the top of the flotation unit and the final effluent was directly discharged without any tap water dilution. The quality of final effluent can be below 40 mg/L-CODMn but IISan Distilery has been maintained effluent quality of 73 mg/L-CODMn and 10-80 mg/L-SS. The chemical cost was saved by more than 30% as compared with that of prior process.

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Effects of the Application of Alternative Agricultural Materials on the Growth of Rice and Water Quality in Paddy Field (벼 생육 및 수질에 대한 대체농자재의 영향)

  • Moon, Young-Hun;Choi, Joung-Sik;Uhm, Mi-Jeong;Han, Seong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.22 no.4
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    • pp.273-277
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    • 2003
  • The aim of this study was to apply the new agricultural technique developed for three years($'96{\sim}'98$) by demonstration at an model farm of environmental agriculture located in Bangsan-ri, Dagang-myun, Namwon-city. Rice growth of environmental farming plot, which supplied with oil cake and compost fermented with chicken manure was reduced compared to that of conventional farming plot, which supplied with chemical fertilizers. Weed control by using of Ampullarius insularus in the rice paddy field was effective compared to that of control, which treated with chemical herbicide twice. The yield of rice was decreased of 35% in both environmental and eclectic farming polt compared to that of conventional farming plot. The water quality of environmental not and eclectic farming plot were good compared to conventional farming plot. Density of water flea was high in environmental and eclectic farming plot compared to that of the conventional farming plot.