• Clean Technology
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• v.10 no.2
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• pp.111-120
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• 2004

Manufacturing with a chemical for eco-friendly leather for nitrogen decrease of leather falling hair process waste water and the falling hair process that a number to decrease with sulfuration water decrease, a pollution load of COD, BOD. In this study manufactured lining agent and the unhairing assist product which did urea, mercaptan by basic matter. As a result of having dealt in hair saving process, compared, and was recalled by the existing hair burning process recovered hair, increased approximately 2times. Grain state to influence the yield that was quality of leather and an index of productivity evaluation, an improvement of contraction phenomenon (drawing) were possible. Is increased going seal, tear strength property of matter and softness and touch leather native nature in wet blue. Also, it is possible confirmation with decrease being more possible than about 50% COD, T-N density in a hair saving waste water.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.1094-1097
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• 2007

낙동강 유역의 가용한 최장기 수량 및 수질자료를 획득하여 자료의 적합성 및 QC과정을 통하여 분석 가능한 자료를 생산하고 자료의 분석에 적합한 통계기법을 선정 각 변수의 변동특성과 변동 상관성을 정밀 분석하였다. 본 연구에서는 낙동강 수질자료의 변동특성을 분석하고 수질개선 필요성을 파악하기 위하여 Mann-Kendall 검정을 사용하여 수질변화의 경향성을 분석하였다. 낙동강 수계의 수질변화 특성을 분석하기 위하여 수온$(^{\circ}C)$, $DO(mg/{\ell}),\;BOD(mg/{\ell}),\;COD(mg/{\ell}),\;SS(mg/{\ell}),\;TN(mg/{\ell}),\;TP(mg/{\ell})$ 이상 7가지의 가용자료를 선택하였다. 수질자료는 환경부에서 운영하는 물 환경 정보 시스템의 수질측정망 자료인 월 단위 자료를 대상으로 Mann-Kendall 검정을 수행하였다. 분석에 사용된 자료 기간은 강우량자료와 유출량자료의 동기간인 1989년${\sim}$2000년까지이다. BOD의 변화를 살펴보면 전반적으로 감소하는 것을 알 수 있다. 가장 큰 감소 경향을 보인 지점은 금호강6 지점으로 $-39.1mg/{\ell}/20yr$로 나타났다. 증가지점으로는 안동과, 구미, 달성, 반변천 등이고 증가량은 약 $1.1mg/{\ell}{\sim}0.03mg/{\ell}/20yr$ 정도이다. COD의 변화를 살펴보면 대부분 지점에서 증가하는 것을 알 수 있다. 감소하는 지역은 고령과 현동, 대암, 금호강3${\sim}$6등이다. 특이사항은 금호강6의 감소분이 $-30.2mg/{\ell}$로 타 지점에 비해 상당히 크다는 것이다. DO의 경우는 증가지점과 감소지점의 수가 비슷하였고 주로 상류쪽이 감소하고 하류로 오면서 증가함을 알 수 있다. DO 또한 금호강6 지점이 가장 큰 폭으로 증가하고 있는 것을 볼 수 있다. pH는 함양위천과 덕천강1을 제외한 모든 지역이 증가 하였다. SS 또한 금호강5, 6, 거창 위천2를 제외한 모든 지역에서 증가하였다. SS항목도 금호강6 지점이 가장 큰 폭으로 감소하였다. 샘플지점(금호강6)의 BOD/COD/DO/pH/SS/TEMP/TN/TP 시계열을 통해 자료분석기간 동안 수처리시설 등의 확장으로 인한 금호강유역의 급격한 수질개선을 알 수 있다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.1
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• pp.493-498
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• 2013

The production of synthetic polymer compounds and ethanolamine (ETA, a pH control agent used in nuclear power plants) generates effluent that pollutes water. This study focused on the development of chemicals for the treatment of effluent and processes to reduce the COD level due to the presence of organic materials via physicochemical treatment. It was found that a mixed coagulant of $FeCl_2$ and $MgCl_2$ (1:1) was the most effective in treating effluent and reducing the COD level. When the mixed coagulant was injected into effluent including organic materials, the COD level was reduced by more than 80%.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.2
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• pp.41-49
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• 2019

Livestock manure is a significant source for greenhouse gas (GHG) emission, and a huge amount of GHG emission is generated during its storage. In the present work, lowering temperature was attempted to mitigate methane ($CH_4$) emission from cattle manure (CM) with high solid content. CM was stored for 60 d at $15-35^{\circ}C$ ($5^{\circ}C$ interval). $CH_4$ emission reached $63.6{\pm}3.6kg\;CO_2\;eq./ton\;CM$ at $35^{\circ}C$, which was reduced to $51.6{\pm}1.8$, $24.1{\pm}4.4$, $14.9{\pm}0.5$, and $3.7{\pm}0.1kg\;CO_2\;eq./ton\;CM$ at 30, 25, 20, and $15^{\circ}C$, respectively. After storage, 30% of COD reduction was observed in the CM stored at $35^{\circ}C$, while the COD removal decreased to only 6% at $15^{\circ}C$. It was found that only 3-11% of COD removal was done by anaerobic process, while the rest of COD removal was done by aerobic biological process. Methanobrevibacter and Methanolobus were found to be the dominant species in the CM, and the dominance of Methanolobus psychrophilus increased at lower storage temperature. Specific methanogenic activity test results showed that the inhibition by low temperature was temporal.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.05a
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• pp.227-231
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• 2003

제주항을 대상으로 오염부하의 정량적인 관리를 위하여 물질순환모델을 이용하여 해수유동특성과 COD, DIN 그리고 DIP의 농도분포를 시뮬레이션 하였고, 이 결과를 통해 해역의 수질개선대책으로 하천오염부하 감소와 저질개선을 통한 용출부하 감소에 따른 COD, DIN 그리고 DIP의 농도를 정량적으로 평가한 결과는 다음과 같다. 외부부하인 하천유입 부하량의 감소에 의한 제주항 내 오염물질 농도의 저감효과는 만 중앙부에서 만 외로 갈수록 그 영향범위가 미비하나 하천 유입부에 한정되어 큰 효과를 나타내고 있어 제주항 내로 오염부하의 유입을 방지함으로서 제주항의 하천 유입부 수질개선에 큰 영향을 줄 수 있다. 내부부하인 저질 영양염 용출부하를 감소했을 경우의 제주항 내 영영염 농도의 저감 효과는 하천유입 부하량의 저감시와 상대적으로 비교하여 제주항의 하천 유입부보다는 만 중앙부나 만 유입부의 수질개선에 효율적인 영향을 보이는 것으로 사료되며 특히, DIP의 경우 그 양상이 잘 나타났다. 하천과 저질의 총 부하량을 100% 감소했을 경우, COD의 농도분포는 하천유입부인 정점 St. 1에서 약 44%정도의 저감효과를 나타내어 하천유입 부하량만을 감소했을 때보다는 저감효과가 증가하였다. DIN의 경우는 하천유입부하와 저질 용출부하를 각각 따로 저감했을 경우에 비해 전체적으로 저감효율이 상승하고 있으며, 만 중앙부에서 만 유입부로 갈수록 그 경향이 잘 나타나고 있으며 총 부하를 저감시켰을 때 제주항내의 DIN 농도는 정점 St. 3 다음 지점부터 해역수질기준 II등급을 유지되는 수질개선 효과를 나타내었다. DIP의 경우는 DIN과 유사한 경향을 보였으며 정점 St. 4 이후로 해역수질기준 II등급 이하로 유지되는 수질개선 효과를 나타내었다. 이상의 결과로 볼 때, 현재 해역수질기준 III등급인 제주항 내에서 수질을 향상시키기 위해서는 하천유입부하량의 저감뿐만 아니라 항내 저질개선 등을 통하면 전체적으로 II등급 이하를 유지할 수 있을 것으로 예상된다.

• KSBB Journal
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• v.17 no.3
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• pp.241-246
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• 2002

Today, many problems of dye-processing wastewaters were raised due to industry of dyeing and textiles. It is difficult to treat them perfectly because they contain many poorly degradable matters, such as surfactants, ethylene glycol, polyvinyl alcohol, and so on. To improve the performances of conventional physicochemical treatment and activated sludge process, new systems of combining jet-loop reactor (JLR) with physicochemical treatment were developed. Volumetric oxygen transfer coefficient ($k_{L}a$) of JLR was significantly larger than that of air-lift reactor. Also, for the effective treatment of dye-processing wastewater, JLR with active carbon supports (JLRAS) were investigated. Removal efficiency of BOD, $COD_{Mn}$, $COD_{Cr} and color were found as 99, 86, 84, 83%, respectively, when HRT was 8 hrs. And performance of JLRAS was rapidly restored after step change of $COD_{Mn}$ loading late. The optimal coagulant and dosage of second physicochemical treatment after JLRAS were polyferric sulfate and 130 mg/L, respectively, when removal efficiencies of $COD_{Mn} and color were 85 and 73%, respectively. In conclusion, this system enables the reduction of operation cost, and the effective removal of many organics.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.5
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• pp.981-987
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• 2000

Upflow anaerobic sludge blanket(UASB) reactor was operated for treating swine wastewater containing high ammonia nitrogen to assess their performance and toxicity of free ammonia concentration. In the reactor, chemical oxygen demand(COD) removed about 70% at $2.6kgCOD/m^3.day$ of organic loading rate(OLR) and 3 days of hydraulic retention time (HRT), while it was decreased when OLR and HRT was maintained $7kg\;COD/m^3.day$ and 2 days, respectively. Also UASB reactor was evaluated the activity of methane producing bacteria(MPB) according to change of free ammonia concentrations, MPB activity of applied sludge in the 500 and $1000mg-N/{\ell}$ of free ammonia concentration was inhibited by 4% and 40%, respectively. This clearly showed that free ammonia concentration less than $500mg-N/{\ell}$ showed no inhibition to MPB in anaerobic treatment of organics, UASB reactor was stabilized easily less than $1000mgVSS/{\ell}$ due to degradation of organic solids by the high activities of anaerobes.

• Journal of the Korean Society of Marine Environment & Safety
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• v.12 no.3 s.26
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• pp.165-170
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• 2006

In this study, organic matters production was calculated with long term data in Wando costal area where was selected for non influent of fresh water. The objective of this study was to evaluate relationship between nutrients and phytoplankton and, between phytoplankton and organic matter. The result of DIN was the highest with 0.138 mg/L in winter season and the lowest with 0.052 mg/L in summer season. Similarly, DIP was shown to be 0. 017 mg/L in winter and 0.011 mg/L in summer. Limiting nutrient was revealed with nitrogen in Wando costal area. Specially in summer season, nitrogen limitation was the greatest with 10.5 of N/P ratio. Chl. -a was increased 80%, 108% in spring and summer compare with winter. COD was the lowest with 0.84 mg/L in winter and the highest with 1.10 mg/L in summer. The interrelation between nutrients and Chl. -a was high. Relationship $coefficient(r^2)$ were 0.93(P<0.05), 0.89(P <0.05) between DIN and Chi. -a, DIP and Chl. -a. This results suggest dissolved nutrients might be utilized at the production of phytoplankton. Also Relationship $coefficient(r^2)$ was 0.77(P<0.05) between Chl. -a and COD. COD production rate was calculated with regression equation. The COD production rate was 17% in winter and 36% in summer. It was revealed nutrients were decreased according to temperature increasing and then Phytoplankton and organic matter were increased. The Relationship of Nutrients, Chl. -a and COD was very high.

• Ecology and Resilient Infrastructure
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• v.4 no.4
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• pp.226-236
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• 2017

In this study, we aimed to analyze the characteristics of water quality variation at Kyeongan Stream for a decade and to investigate by the flow-loading equation. The correlation analysis of water quality parameters and the influence factors were examined by statistical analysis. The characteristics of water quality variation showed that the fluctuations in $BOD_5$, $COD_{Mn}$ and TOC were repeated from year to year. TN and TP were decreased by year. By the flow-loading equation, the concentrations of $BOD_5$, $COD_{Mn}$, TOC and TN were decreased when the flow rate was on the rise. However, the flow did not affect the concentration of TP. According to correlation analysis, $BOD_5$ was highly correlated with $COD_{Mn}$ and TOC with the correlation coefficients of 0.890 (p<0.01) and 0.721 (p<0.01). The result of factor analysis, we identified that the water quality in Kyeongan Stream has been highly influenced by the organic matter index, followed by nitrogenous substance depending on the seasonal variations and the influx of suspended solid in accordance with the increase of flow.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.6
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• pp.412-420
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• 2014

Water quality variations were investigated at 4 locations of Jungrang river (upper, middle and lower basins) during a period of 3 rainfall events. During the rainfall, concentrations of $COD_{Mn}$, SS and $BOD_5$ significantly increased, while the concentration of T-N decreased and that of T-P remained relatively constant. This pattern became more apparent as the level of accumulative precipitation and rainfall intensity increased. Simple regression analysis showed that the accumulative precipitation was positively correlated with all water quality pollutants except for T-N. With increasing accumulative precipitation, the concentration of T-N decreased, while the others increased. $R^2$ of simple regressions of hourly average rainfall intensity and water quality pollutants, showed wider range of variation ranged from 0.483 to 0.992, which indicated a strong correlation. The stronger the hourly average rainfall intensity, the more T-N and T-P in the upper basin, more $COD_{Mn}$ in the middle and lower basins, more SS with gradual increase from upper to lower areas, and more $BOD_5$ with gradual decrease from upper to lower region. Simple regression showed that water quality pollution in the upper basin was more sensitive to an increase of rainfall discharge than that in the middle and lower areas.