• Journal of Environmental Science International
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• v.23 no.2
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• pp.181-192
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• 2014

In Korea, the chemical oxygen demand($COD_{sed}$) in freshwater sediments has been measured by the potassium permanganate method used for marine sediment because of the absence of authorized analytical method. However, this method has not been fully verified for the freshwater sediment. Therefore, the use or modification of the potassium permanganate method or the development of the new $COD_{sed}$ analytical method may be necessary. In this study, two modified $COD_{sed}$ analytical methods such as the modified potassium permanganate method for $COD_{Mn}$ and the modified closed reflux method using potassium dichromate for $COD_{Cr}$ were compared. In the preliminary experiment to estimate the capability of the two oxidants for glucose oxidation, $COD_{Mn}$ and $COD_{Cr}$ were about 70% and 100% of theoretical oxygen demand(ThOD), respectively, indicating that $COD_{Cr}$ was very close to the ThOD. The effective titration ranges in $COD_{Mn}$ and $COD_{Cr}$ were 3.2 to 7.5 mL and 1.0 to 5.0 mL for glucose, 4.3 to 7.5 mL and 1.4 to 4.3 mL for lake sediment, and 2.5 to 5.8 mL and 3.6 to 4.5 mL for river sediment, respectively, within 10% errors. For estimating $COD_{sed}$ recovery(%) in glucose-spiked sediment after aging for 1 day, the mass balances of the $COD_{Mn}$ and $COD_{Cr}$ among glucose, sediments and glucose-spiked sediments were compared. The recoveries of $COD_{Mn}$ and $COD_{Cr}$ were 78% and 78% in glucose-spiked river sediments, 91% and 86% in glucose-spiked lake sediments, 97% and 104% in glucose-spiked sand, and 134% and 107% in glucose-spiked clay, respectively. In conclusion, both methods have high confidence levels in terms of analytical methodology but show significant different $COD_{sed}$ concentrations due to difference in the oxidation powers of the oxidants.

• Journal of Wetlands Research
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• v.20 no.2
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• pp.173-180
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• 2018

The utilization of TOC(Total organic carbon), a new environmental standard, was evaluated for 30 lakes in the Nakdong River Basin, which is used for drinking and agricultural usage. The active use of water resources begins with securing satisfactory water quality. Since this allows people and nature to maintain stability of quality, water quality standards are being tightened to ensure good water quality. In order to improve the pollution level of organic matter in lakes in the living environment, it is important to use the appropriate organic substance index. The relationship between the newly introduced TOC and the existing COD(Chemical oxygen demand) in the targeted lake was positively correlated with the possibility of replacing the TOC with COD. However, the environmental grade standard using TOC is better than the environmental grade standard using COD, so it has the same effect as that of the grade of water quality using TOC as an organic substance factor. This indicates the limitation of TOC to directly replace existing COD when trying to determine or improve the quality level using organic indicators of lakes. Therefore, in order to secure the qualitative safety of the lake, it is required to strengthen environmental standards of TOC in terms of water quality grade. In addition, the correlation between TOC and COD shows a great difference depending on the utilization characteristics of the lake. This requires clear scientific identification, and it requires continuous monitoring of COD that has been used to accumulate indicators of lake organic matter.

• Journal of Environmental Science International
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• v.5 no.6
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• pp.763-770
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• 1996

This study was performed to analyze the variation characteristics of writer qulity, correlation analysis of water quality data at each site and among the items of water Quality data. Water quality for analysis was monthly values of water temperature, pH, dissolved oxygen, biochemical oxygen demand, chemical oxygen demand, suspended solid, 7-N and T-P checked in Daecheong Lake from January to December, 1995. It was analyzed variation of monthly water qulity was well from February to April, water temperature and COD seemed to have high correlationships at all sites. Regression equation is COD = 0.07 Water temperature +1.23 ($R^2$: 0.7616) . Results of the correlation analysis of water quality data showed that DO had high correlationships between site 1 and site 2, BOD did site 1 and 3, COD did site 1 and 2, 55 did site 5 and 6, 7-N did 2 and 3, 7-P did site 4 and 6. Regression equations for estimate of water quality data are as follows. $DO_1$=4.46+0.59 DO, ($R^2$=0.8868), $BOD_1$ = 0, 52+0.63 BOD3 ($R^2$ = 0.6390) $COD_2$ = 0.44+0.71 $COD_1$ ($R^2$ = 0.9183), SS6 = 0.89+0.7055.($R^2$ = 0.9155) $TN_3$ = 0.151 +0.886 $TN_2$ ($R^2$ = 0.9415), $TP_4$ = 0.004+5.758 $TP_6$ ($R^2$ = 0.9669)

• The Journal of the Korea Contents Association
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• v.6 no.10
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• pp.1-8
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• 2006

The new system evaluating the pollution of the water quality for the branches of geum river using the fuzzy integral was proposed in this study. In this paper, the five individual factors, such as BOD(biochemical oxygen demand), COD(chemical oxygen demand), SS(suspended solids), T-N(total nitrogen), and T-P(total phosphorus) are selected. The measurement of fuzzy integral was determined depending on the degree of how they affect the pollution of water quality. The real values for the five factors measured and obtained from the branches of the geum river was normalized to ranging from 0 to 1. Finally, using the fuzzy integral, the degree of the pollution for the branches of geum river was expressed as the real numerical number. As a result, it appears that this approach can be proposed as the new system evaluating the pollution of the water quality for the branches of the geum river.

• Journal of Environmental Science International
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• v.14 no.9
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• pp.835-842
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• 2005

The three-dimensional eco-hydrodynamic model was applied to estimate the physical process in terms of COD (chemical oxygen demand) and net supply(or decomposition) rate of COD in Kamak Bay to find proper management plan for oxygen demanding organic matters. The estimation results of the physical process in terms of COD showed that transportation of COD is dominant in surface level while accumulation of COD is dominant in bottom level. In the case of surface level, the net supply rate of COD was 0 -0.50 mg/m2/day. The net decomposition rate of COD was 0 -0.04 mg/m2/day in middle level(3 -6m) and 0.05 -0.1 5 mg/m2/day in bottom level(6m -bottom). These results indicates that the biological decomposition and physical accumulation of COD are occurred predominantly at the northern part of bottom level. Therefore, it is important to consider both allochthonous and autochthonous oxygen demanding organic matters in the region.

• Journal of Environmental Science International
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• v.8 no.2
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• pp.189-195
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• 1999

Determining factors and temporal & spatial characteristics of COD(Chemical Oxygen Demand) at the sea surface in Jinhae bay have been examined by using seasonal data, taken at twenty six stations over the whole bay during 1989~1994 by NERDA. The data have been analyzed in terms of long term means, anomalously large values. Jinhae bay is divided into three regions based on the time mean : mouth of Jinhae bay, inner sea of Masan bay, western sea of Jinhae bay called region 1,2 and 3, respectively. The horizontal distribution of the long term mean of COD at each station is similar to those of nitrogen and phosphorus. Characteristics of whole mean variation in the year shows high range of variation in region 2. It was appear to decreases every year in whole trend. Factors determining seasonal variation in whole COD mean are relative to salinity and nutrient, affected by precipitation in summer. Spatial variation shows high range of fluctuation in region 2 compare to other region. Factors determining of spatial variation of COD was appear to nutrient, affected by pollutant load of land area and bottom sediment. The long term mean of COD at each station is closely related with thats of nutrients. The correlation coefficient between COD and nitrogen, phosphate phosphorus was found to be high as 0.75, 0.78, respectively. Anomalously large COD was observed 14 times at 6 stations. These stations are located in inner sea of Masan bay(Region 2) and Songjeong bay(Region 1). The seasonal frequency of the observed anomalous COD is large in April, and other seasons are much the same.

• Journal of the Korean Data and Information Science Society
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• v.18 no.4
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• pp.847-857
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• 2007

This paper provides a statistical algorithm which detects COD (chemical oxygen demand) measurement machine error on real-time. For this we propose to use regression model fitting and check its validity against the current observations. The main idea is that the normal regression relation between COD measurement and other parameters inside the machine will be violated when the machine is out of order.

• Journal of Environmental Science International
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• v.2 no.4
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• pp.291-297
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• 1993

The COD values and chloride ion concentrations of the Taewha river flowing through Ulsan area were determined along the main stream and the relationships between CODs and chloride ion concentrations were described. The results showed that the middle-upper stream and downstream of the Taewha river were polluted deeply with municipal sewage and self-purification occured in the middle-downstream of the river. When domestic sewage is a main source of pollutants, and is especially the only source of chloride in the stream water, the ratio of COD/[$\textrm{Cl}^{-}$] will be utilizable as a measure of self-purification of the stream.

• Journal of Korean Port Research
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• v.12 no.2
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• pp.313-322
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• 1998

The distributions of chemical oxygen demand (COD) and suspended solid (SS) in Ulsan Bay were simulated and reproduced by a numerical ecosystem model for the practical application to the management of marine water quality and the prediction of water quality change due to coastal developments or the constructions of breakwater and marine facilities. Comparing the computed with the observed data of COD and SS in Ulsan bay the results of simulation were found to be good enough to satisfy the practical applications.

• Journal of the Speleological Society of Korea
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• v.15 no.16
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• pp.38-60
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• 1987

There are BOD(Biochemical Oxygen Demand) and COD(Chemical Oxygen Demand) in the date of the water pollution in the pollution analysis, BOD and COD analysis the result of the analysis. The computer developed the program in the analysis. Went by BOD, the relation conversion equation type of COD, the control chart, the standard deviation, and the coefficient of correlation etc.. for the purpose of the development of the program. There is a purpose by which it is what coefficient of correlation in the development of this program or not if the value (X and Y) of unknow is understood. In the future, if this program is applied the utilization to not only the data is analyzed about the water pollution but also a lot of fields is proposed.