• Title/Summary/Keyword: CO coverage

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A Theoretical Study of CO Molecules on Metal Surfaces: Coverage Dependent Properties

  • Sang -H. Park;Hojing Kim
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.574-582
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    • 1991
  • The CO molecules adsorbed on Ni(111) surface is studied in the cluster approximation employing EH method with self-consistent charge iteration. The effect of CO coverage is simulated by allowing the variation of valence state ionization potentials of each Ni atom in model cluster according to the self-consistent charge iteration method. The CO coverage dependent C-O stretching frequency shift, adsorption site conversion, and metal work function change are attributed to the charge transfer between metal surface and adsorbate. For CO/Ni(111) system, net charge transfer from Ni surface to chemisorbed CO molecules makes surface Ni atoms be more positive with increasing coverage, and lowers Ni surface valence band. This leads to a weaker interaction between metal surface valence band and Co $2{\pi}^{\ast}$ MO, less charge transfer to a single CO molecule, and the bule shift of C-O stretching frequency. Further increase of coverage induces the conversion of 3-fold site CO to lower coordination site CO as well as the blue shift of C-O stretching frequency. This whole process is accompanied by the continuous increase of metal work function.

Comparison of CO on Carbon-supported Pt Catalysts Prepared by CO Gas Bubbling and Methanol Dehydrogenation

  • Han, Kee-Sung;Hwang, Ki-Ju;Han, Oc-Hee
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2442-2444
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    • 2007
  • CO adsorbates on the surface of Pt supported on carbon catalysts (Pt/C) were investigated by CO stripping voltammetry. Three types of CO adsorbed samples were prepared: by methanol dehydrogenation only (COm), by CO gas bubbling only (COg), and by methanol dehydrogenation followed by CO gas bubbling (COm+g). Our coverage data show that CO gas can be adsorbed on Pt/C catalyst already saturated with CO adsorbates by methanol dehydrogenation. The COm+g sample showed the properties of both COm as well as COg samples in terms of the potential although the CO adsorbed by dehydrogenation was completely exchanged with CO in the electrolyte solution. Therefore, the oxidation pathways of CO on Pt/C were observed to depend on the initial adsorption conditions of CO more strongly than on the CO coverage. Our results imply that an initial CO poisoning condition in fuel cell operation is an important factor to determine the difficulty in removing the adsorbed CO and confirm that the properties of the adsorbed CO do not change even with chemical replacement with CO in different conditions. In addition, our results indicate a low CO surface mobility on the Pt in an electrolyte solution.

Analysis on Co-channel Interference Coverage of ATSC DTV (ATSC DTV에서 동일채널간섭 커버리지에 대한 분석)

  • Ryu, Kwanwoong;Park, Sung Ik;Kim, Heung Mook
    • Journal of Broadcast Engineering
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    • v.18 no.1
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    • pp.59-65
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    • 2013
  • Recently, the digital television transition from analog television to digital television has been progressing in terrestrial broadcasting. As a result of the DTV transition, additional reassignments and deployments of TV White spaces (TVWS) caused by co-channel interference (CCI) were needed. In this paper, we investigate the TVWS caused by CCI using Longley-Rice and ITU-R P.1546 propagation model, which are the most widely-used propagation model. In addition, we analyze the service coverage radius and CCI radius according to the height of transmitter antenna and transmitting power. The results show that the ratios of CCI radius to service coverage radius in Longley-Rice and ITU-R P.1546 propagation model are about 2.54 and 2.07, respectively.

SOC Bus Transaction Verification Using AMBA Protocol Checker

  • Lee, Kab-Joo;Kim, Si-Hyun;Hwang, Hyo-Seon
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.2 no.2
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    • pp.132-140
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    • 2002
  • This paper presents an ARM-based SOC bus transaction verification IP and the usage experiences in SOC designs. The verification IP is an AMBA AHB protocol checker, which captures legal AHB transactions in FSM-style signal sequence checking routines. This checker can be considered as a reusable verification IP since it does not change unless the bus protocol changes. Our AHB protocol checker is designed to be scalable to any number of AHB masters and reusable for various AMBA-based SOC designs. The keys to the scalability and the reusability are Object-Oriented Programming (OOP), virtual port, and bind operation. This paper describes how OOP, virtual port, and bind features are used to implement AHB protocol checker. Using the AHB protocol checker, an AHB simulation monitor is constructed. The monitor checks the legal bus arbitration and detects the first cycle of an AHB transaction. Then it calls AHB protocol checker to check the expected AHB signal sequences. We integrate the AHB bus monitor into Verilog simulation environment to replace time-consuming visual waveform inspection, and it allows us to find design bugs quickly. This paper also discusses AMBA AHB bus transaction coverage metrics and AHB transaction coverage analysis. Test programs for five AHB masters of an SOC, four channel DMAs and a host interface unit are executed and transaction coverage for DMA verification is collected during simulation. These coverage results can be used to determine the weak point of test programs in terms of the number of bus transactions occurred and guide to improve the quality of the test programs. Also, the coverage results can be used to obtain bus utilization statistics since the bus cycles occupied by each AHB master can be obtained.

Built-In-Test Coverage Analysis Considering Failure Mode of Electronics Components (전자부품 고장모드를 고려한 Built-In-Test 성능분석)

  • Seo, Joon-Ho;Ko, Jin-Young;Park, Han-Joon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.43 no.5
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    • pp.449-455
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    • 2015
  • Built-In-Test(hereafter: BIT) is necessary functionality for aircraft flight safety and it requires a high failure detection capacity of more than 95 % in the case of avionics equipment. The BIT coverage analysis is needed to make sure that BIT meets its fault diagnosis capability. FMECA is used a lot of for the BIT coverage analysis. However, in this paper, the BIT coverage analysis based on electronic components is introduced to minimize the analytical error. Further, by applying the failure mode of the electronic components and excluding electronic components that do not affect flight safety, the BIT coverage analysis can be more accurate. Finally, BIT demo was performed and it was confirmed that the performance of the actual BIT matches the analysis of BIT performance.

Simulation analysis and evaluation of decontamination effect of different abrasive jet process parameters on radioactively contaminated metal

  • Lin Zhong;Jian Deng;Zhe-wen Zuo;Can-yu Huang;Bo Chen;Lin Lei;Ze-yong Lei;Jie-heng Lei;Mu Zhao;Yun-fei Hua
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.3940-3955
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    • 2023
  • A new method of numerical simulating prediction and decontamination effect evaluation for abrasive jet decontamination to radioactively contaminated metal is proposed. Based on the Computational Fluid Dynamics and Discrete Element Model (CFD-DEM) coupled simulation model, the motion patterns and distribution of abrasives can be predicted, and the decontamination effect can be evaluated by image processing and recognition technology. The impact of three key parameters (impact distance, inlet pressure, abrasive mass flow rate) on the decontamination effect is revealed. Moreover, here are experiments of reliability verification to decontamination effect and numerical simulation methods that has been conducted. The results show that: 60Co and other homogeneous solid solution radioactive pollutants can be removed by abrasive jet, and the average removal rate of Co exceeds 80%. It is reliable for the proposed numerical simulation and evaluation method because of the well goodness of fit between predicted value and actual values: The predicted values and actual values of the abrasive distribution diameter are Ф57 and Ф55; the total coverage rate is 26.42% and 23.50%; the average impact velocity is 81.73 m/s and 78.00 m/s. Further analysis shows that the impact distance has a significant impact on the distribution of abrasive particles on the target surface, the coverage rate of the core area increases at first, and then decreases with the increase of the impact distance of the nozzle, which reach a maximum of 14.44% at 300 mm. It is recommended to set the impact distance around 300 mm, because at this time the core area coverage of the abrasive is the largest and the impact velocity is stable at the highest speed of 81.94 m/s. The impact of the nozzle inlet pressure on the decontamination effect mainly affects the impact kinetic energy of the abrasive and has little impact on the distribution. The greater the inlet pressure, the greater the impact kinetic energy, and the stronger the decontamination ability of the abrasive. But in return, the energy consumption is higher, too. For the decontamination of radioactively contaminated metals, it is recommended to set the inlet pressure of the nozzle at around 0.6 MPa. Because most of the Co elements can be removed under this pressure. Increasing the mass and flow of abrasives appropriately can enhance the decontamination effectiveness. The total mass of abrasives per unit decontamination area is suggested to be 50 g because the core area coverage rate of the abrasive is relatively large under this condition; and the nozzle wear extent is acceptable.

Application of Organic Fertilizer Preparation for Increasing of Coverage and Growth of Cool Season Turfgrasses (한지형 잔디의 피복 율과 생육 증진을 위한 유기질비료 제제의 살포)

  • Koo, Jun Hwak;Heo, Hyug Jae;Kim, Yang Sun;Yun, Jeong Ho;Chang, Seog Won;Jeon, Jong Yeob;Chang, Tae hyun
    • Weed & Turfgrass Science
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    • v.4 no.3
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    • pp.268-277
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    • 2015
  • Organic fertilizer preparation was developed with organic materials to improve growth and qualities of cool-season turfgrass species. Organic fertilizer preparation were contained with essential macronutrient elements and organic matter for growth of cool season turfgrass. Four preparations of organic fertilizers were tested on creeping bentgrass (Agrostis palustris Huds) cultivar Penn-A1 and Kentucky bluegrass (Poa pratensis L.) mixed cultivars (Midnight 33%, Moonlight 33%, and Prosperity 33%) by one time application on fifty days after sowing. Two species of cool season turfgrasses were evaluated on turfgrass coverage, growth on NDVI (Normalized Difference Vegetation Index) and qualities from fall season to spring season in sod producing farm. It were found significantly difference found on turfgrass coverage, turf color, chlorophyll contents and growth increase on two species of cool season turfgrasses. Turfgrass coverage, chlorophyll content, turf color and growth increase of organic fertilizer preparation were significantly increased on creeping bentgrass cultivar and Kentucky bluegrass mixed cultivar for six time investigation in spring season. These results may indicate that the use of some preparation is beneficial for sod producing sod and turfgrass management.

No Blind Spot: Network Coverage Enhancement Through Joint Cooperation and Frequency Reuse

  • Zhong, Yi;Qiao, Pengcheng;Zhang, Wenyi;Zheng, Fu-chun
    • Journal of Communications and Networks
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    • v.18 no.5
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    • pp.773-783
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    • 2016
  • Both coordinated multi-point transmission and frequency reuse are effective approaches to mitigate inter-cell interference and improve network coverage. The motivation of this work is to explore the manner to effectively utilize the spectrum resource by reasonably combining cooperation and frequency reuse. The $Mat{\acute{e}}rn$ cluster process, which is appropriate to model networks with hot spots, is used to model the spatial distribution of base stations. Two cooperative mechanisms, coherent and non-coherent joint transmission (JT), are analyzed and compared. We also evaluate the effect of multiple antennas and imperfect channel state information. The simulation reveals that the proposed approach to combine cooperation and frequency reuse is effective to improve the network coverage for users located at both the center and the boundary of the cooperative region.

Design of Regional Coverage Low Earth Orbit (LEO) Constellation with Optimal Inclination

  • Shin, Jinyoung;Park, Sang-Young;Son, Jihae;Song, Sung-Chan
    • Journal of Astronomy and Space Sciences
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    • v.38 no.4
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    • pp.217-227
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    • 2021
  • In this study, we describe an analytical process for designing a low Earth orbit constellation for discontinuous regional coverage, to be used for a surveillance and reconnaissance space mission. The objective of this study was to configure a satellite constellation that targeted multiple areas near the Korean Peninsula. The constellation design forms part of a discontinuous regional coverage problem with a minimum revisit time. We first introduced an optimal inclination search algorithm to calculate the orbital inclination that maximizes the geometrical coverage of single or multiple ground targets. The common ground track (CGT) constellation pattern with a repeating period of one nodal day was then used to construct the rest of the orbital elements of the constellation. Combining these results, we present an analytical design process that users can directly apply to their own situation. For Seoul, for example, 39.0° was determined as the optimal orbital inclination, and the maximum and average revisit times were 58.1 min and 27.9 min for a 20-satellite constellation, and 42.5 min and 19.7 min for a 30-satellite CGT constellation, respectively. This study also compares the revisit times of the proposed method with those of a traditional Walker-Delta constellation under three inclination conditions: optimal inclination, restricted inclination by launch trajectories from the Korean Peninsula, and inclination for the sun-synchronous orbit. A comparison showed that the CGT constellation had the shortest revisit times with a non-optimal inclination condition. The results of this analysis can serve as a reference for determining the appropriate constellation pattern for a given inclination condition.