• Title/Summary/Keyword: CO conversion

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ABSORBED INTERNAL DOSE CONVERSION COEFFICIENTS FOR DOMESTIC REFERENCE ANIMALS AND PLANT

  • Keum, Dong-Kwon;Jun, In;Lim, Kwang-Muk;Choi, Yong-Ho
    • Nuclear Engineering and Technology
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    • v.42 no.1
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    • pp.89-96
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    • 2010
  • This paper describes the methodology of calculating the internal dose conversion coefficient in order to assess the radiological impact on non-human species. This paper also presents the internal dose conversion coefficients of 25 radionuclides ($^3H,\;^7Be,\;^{14}C,\;^{40}K,\;^{51}Cr,\;^{54}Mn,\;^{59}Fe,\;^{58}Co,\;^{60}Co,\;^{65}Zn,\;^{90}Sr,\;^{95}Nb,\;^{99}Tc,\;^{106}Ru,\;^{129}I,\;^{131}I,\;^{136}Cs,\;^{137}Cs,\;^{140}Ba,\;^{140}La,\;^{144}Ce,\;^{238}U,\;^{239}Pu,\;^{240}Pu$) for domestic seven reference animals (roe deer, rat, frog, snake, Chinese minnow, bee, and earthworm) and one reference plant (pine tree). The uniform isotropic model was applied in order to calculate the internal dose conversion coefficients. The calculated internal dose conversion coefficient (${\mu}Gyd^{-1}$ per $Bqkg^{-1}$) ranged from $10^{-6}$ to $10^{-2}$ according to the type of radionuclides and organisms studied. It turns out that the internal does conversion coefficient was higher for alpha radionuclides, such as $^{238}U,\;^{239}Pu$, and $^{240}Pu$, and for large organisms, such as roe deer and pine tree. The internal dose conversion coefficients of $^{239}U,\;^{240}Pu,\;^{238}U,\;^{14}C,\;^3H$, and $^{99}Tc$ were independent of the organism.

The Study on Measurement of Relative Conversion Factor in X-ray Image Intensifier (X선영상증배관의 상대변환계수 측정에 관한 검토)

  • Kim, Sung-Chul;Shin, Sung-Ill;Lee, Sun-Sook;Huh, Joon;Kim, Sung-Soo
    • Journal of radiological science and technology
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    • v.20 no.2
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    • pp.28-33
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    • 1997
  • For the Evaluation of X-ray image intensifier, we measured radiation dose at input of I. I., brightness and fluorescence at output of I. I. by using X-ray exposure meter, optometer and fluorescence meter for the relative conversion factor. Especially, by using fluorescence meter, we could easily get relative conversion factor without having regulated machine by JIS. Since using, the quality of image intensifier is going down. Consequently, it needs continuous quality maintenance.

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Low Grade Coal-CO2 Catalytic Gasification Reaction for CO gas Synthesis (CO 합성을 위한 저급석탄-CO2 촉매 가스화 반응)

  • Lee, Ho Yong;Lee, Jong Dae
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.3
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    • pp.466-473
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    • 2016
  • In this study, the experiments on optimal CO gas synthesis were conducted using low grade coal-$CO_2$ catalyst gasification reaction. The characteristics of generated CO gas were investigated using the chemical activation method of KOH, $K_2CO_3$, $Na_2CO_3$ catalysts with Kideco and Shewha coal. The preparation process has been optimized through the analysis of experimental variables such as ratio between activating chemical agents and coal, the flow rate of gas and reaction temperature during $CO_2$ conversion reaction. The produced CO gas was analysed by Gas Chromatography (GC). The 98.6% $CO_2$ conversion for Kideco coal mixed with 20 wt% $Na_2CO_3$ and 98.9% $CO_2$ conversion for Shenhua coal mixed with 20 wt% KOH were obtained at the conditions of $T=950^{\circ}C$ and $CO_2$ flow rate of 100 cc/min. Also, the low grade coal-$CO_2$ catalytic gasification reaction showed the CO selectivities(97.8 and 98.8 %) at the same feed ratio and reaction conditions.

Effects of Temperature, Pressure, and Gas Residence Time on Methane Combustion Characteristics of Oxygen Carrier Particle in a Pressurized Fluidized Bed Reactor (가압 유동층 반응기에서 산소공여입자의 메탄 연소 특성에 미치는 온도, 압력 및 기체체류시간의 영향)

  • Ryu, Ho-Jung;Park, Sang-Soo;Moon, Jong-Ho;Choi, Won-Kil;Rhee, Young-Woo
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.2
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    • pp.173-182
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    • 2012
  • Effects of temperature, pressure, and gas residence time on methane combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using methane and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction condition and very low NO emission at oxidation condition. Moreover OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration. However, $CO_2$ selectivity increased as pressure increased and fuel conversion increased as gas residence time increased.

Characterization of NAD-Dependent Formate Dehydrogenase from Trametes versicolor Using a Cell-Free Protein Expression System

  • LEE, Su-Yeon;JANG, Seokyoon;LEE, Soo-Min
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.3
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    • pp.159-166
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    • 2022
  • CO2 emissions are the primary reason for global warming; hence, biological and chemical technologies for converting CO2 into useful compounds are being actively studied. Biological methods using enzymes can convert CO2 under mild conditions. Formate dehydrogenase (FDH) is a representative CO2 conversion enzyme. Its function was revealed after isolation from bacteria, yeast, and plants. In this study, we evaluated the CO2 conversion potential of FDH isolated from wood-rotting fungi. After isolating the FDH gene (TvFDH) from Trametes versicolor, we cloned the full-length FDH from T. versicolor and expressed it in a cell-free expression system. The gene encoding TvFDH was identified as 1,200 bp open reading frame (ORF) and the expected molecular weight of the protein was approximately 42 kDa. Overexpression of the recombinant crude protein including TvFDH was confirmed by sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE). Enzyme activities and metabolite analyses confirmed the efficiency of TvFDH for CO2 reduction.

DEVELOPMENT OF A SUPERCRITICAL CO2 BRAYTON ENERGY CONVERSION SYSTEM COUPLED WITH A SODIUM COOLED FAST REACTOR

  • Cha, Jae-Eun;Lee, Tae-Ho;Eoh, Jae-Hyuk;Seong, Sung-Hwan;Kim, Seong-O;Kim, Dong-Eok;Kim, Moo-Hwan;Kim, Tae-Woo;Suh, Kyun-Yul
    • Nuclear Engineering and Technology
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    • v.41 no.8
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    • pp.1025-1044
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    • 2009
  • Systematic research has been conducted by KAERI to develop a supercritical carbon dioxide Brayton cycle energy conversion system coupled with a sodium cooled fast reactor. For the development of the supercritical $CO_2$ Brayton cycle ECS, KAERI researched four major fields, separately. For the system development, computer codes were developed to design and analyze the supercritical $CO_2$ Brayton cycle ECS coupled with the KALIMER-600. Computer codes were developed to design and analyze the performance of the major components such as the turbomachinery and the high compactness PCHE heat exchanger. Three dimensional flow analysis was conducted to evaluate their performance. A new configuration for a PCHE heat exchanger was developed by using flow analysis, which showed a very small pressure loss compared with a previous PCHE while maintaining its heat transfer rate. Transient characteristics for the supercritical $CO_2$ Brayton cycle coupled with KALIMER-600 were also analyzed using the developed computer codes. A Na-$CO_2$ pressure boundary failure accident was analyzed with a computer code that included a developed model for the Na-$CO_2$ chemical reaction phenomena. The MMS-LMR code was developed to analyze the system transient and control logic. On the basis of the code, the system behavior was analyzed when a turbine load was changed. This paper contains the current research overview of the supercritical $CO_2$ Brayton cycle coupled to the KALIMER-600 as an alternative energy conversion system.

A Theoretical Study of CO Molecules on Metal Surfaces: Coverage Dependent Properties

  • Sang -H. Park;Hojing Kim
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.574-582
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    • 1991
  • The CO molecules adsorbed on Ni(111) surface is studied in the cluster approximation employing EH method with self-consistent charge iteration. The effect of CO coverage is simulated by allowing the variation of valence state ionization potentials of each Ni atom in model cluster according to the self-consistent charge iteration method. The CO coverage dependent C-O stretching frequency shift, adsorption site conversion, and metal work function change are attributed to the charge transfer between metal surface and adsorbate. For CO/Ni(111) system, net charge transfer from Ni surface to chemisorbed CO molecules makes surface Ni atoms be more positive with increasing coverage, and lowers Ni surface valence band. This leads to a weaker interaction between metal surface valence band and Co $2{\pi}^{\ast}$ MO, less charge transfer to a single CO molecule, and the bule shift of C-O stretching frequency. Further increase of coverage induces the conversion of 3-fold site CO to lower coordination site CO as well as the blue shift of C-O stretching frequency. This whole process is accompanied by the continuous increase of metal work function.

Effect of Glass Composition on the Optical Properties of Color Conversion Glasses for White LED (유리조성에 따른 백색 LED용 색변환 유리의 광특성)

  • Huh, Cheolmin;Hwang, Jonghee;Lim, Tae-Young;Kim, Jin-Ho;Lee, MiJai;Yoo, Jong-Sung;Park, Tae-Ho;Moon, Jooho
    • Korean Journal of Materials Research
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    • v.22 no.12
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    • pp.669-674
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    • 2012
  • Yellow phosphor dispersed color conversion glasses are promising phosphor materials for white LED applications because of their good thermal durability, chemical stability, and anti-ultraviolet property. Six color conversion glasses were prepared with high Tg and low Tg specimens of glass. Luminous efficacy, luminance, CIE (Commission Internationale de l'Eclairage) chromaticity, CCT (Correlated Color Temperature), and CRI (Color Rendering Index) of the color conversion glasses were analyzed according to the PL spectrum. Color conversion glasses with high Tg glass frit, sintered at higher temperature, showed better luminous properties than did color conversion glasses with low Tg glass frit. The characteristics of the color conversion glass depended on the glass composition rather than on the sintering temperature. The XRD peaks of the YAG phosphor disappeared in the color conversion glass with major components of $B_2O_3$-ZnO-$SiO_2$-CaO and, in the XRD results, new crystalline peaks of $BaSi_2O_5$ appeared in the color conversion glass with major components of $Bi_2O_3$-ZnO-$B_2O_3$-MgO. The characteristics of CIE chromaticity, CCT, and the CRI of low Tg color conversion glasses showed worse color properties than those of high Tg color conversion glasses. However, these color characteristics of low Tg glasses were improved by thickness variation. So color conversion glasses with good characteristics of both luminous and color properties were attained.